Home Blog Page 90

Tuff

Tuff rock, also simply known as “tuff,” is a type of sedimentary rock that forms from the consolidation of volcanic ash and other volcanic debris. It is a unique rock type that results from explosive volcanic eruptions, during which a mixture of hot ash, rock fragments, and gases is expelled into the atmosphere. As these materials settle and accumulate, they can eventually become compacted and cemented to form tuff rock.

Name origin: The name of Tuff driven from the Italian tufo, also known as volcanic tuff

Texture: Pyroclastic

Origin: Extrusive/Volcanic

Chemical Composition: Felsic

Color: Light to dark brown

Mineral Composition: Predominantly Glass

Miscellaneous: Light gray pumice fragments in white ash matrix

Tectonic Environment: Convergent Boundary – Andean-type subduction zones, intracontinental hot spots and rifts

Tuff Classification and Composition

Tuff is a type of sedimentary rock formed from the consolidation of volcanic ash and other volcanic debris. It can exhibit a wide range of characteristics based on its mineral composition, texture, and the processes involved in its formation. Tuff classification and composition can be described as follows:

  1. Classification based on Texture:
    • Lithic Tuff: Lithic tuffs are composed mainly of volcanic rock fragments and ash. They have a fragmental texture and often contain angular to rounded rock fragments of various sizes.
    • Vitric Tuff: Vitric tuffs are rich in volcanic glass fragments and have a glassy appearance. They may also contain smaller mineral crystals embedded in the glass matrix.
    • Crystal Tuff: Crystal tuffs have a significant amount of mineral crystals, such as feldspar, quartz, and mica, embedded in a finer matrix of volcanic ash. These crystals can be phenocrysts that originated from the magma before eruption.
    • Ash-Fall Tuff: Ash-fall tuffs result from the direct settling of fine volcanic ash particles from the atmosphere. They often have a fine-grained texture and can be widespread.
  2. Classification based on Composition:
    • Rhyolitic Tuff: Rhyolitic tuffs are composed of volcanic ash and debris from rhyolitic eruptions. They typically contain a high proportion of silica-rich minerals, such as quartz and feldspar.
    • Andesitic Tuff: Andesitic tuffs are derived from andesitic volcanic eruptions and have a composition intermediate between rhyolitic and basaltic tuffs. They may contain minerals like plagioclase feldspar and amphibole.
    • Basaltic Tuff: Basaltic tuffs originate from basaltic volcanic activity and contain minerals like pyroxene and olivine. They often have a darker color due to the presence of mafic minerals.
  3. Other Characteristics:
    • Pumiceous Tuff: Pumiceous tuffs are rich in pumice, which is a highly vesicular volcanic glass with a frothy texture. These tuffs are often lightweight and have excellent insulating properties.
    • Tuffaceous Sandstone: Tuffaceous sandstone is a rock that contains a significant amount of tuff fragments along with sand-sized grains. It represents a transition between tuff and sandstone.

Tuff composition can vary widely depending on the specific volcanic source, eruption style, and subsequent diagenetic processes. Major minerals found in tuff include quartz, feldspar (both plagioclase and potassium feldspar), mica, volcanic glass, and various accessory minerals. The presence of phenocrysts, mineral alteration, and weathering products can further influence the composition of tuff.

In summary, tuff classification and composition are influenced by factors such as volcanic source material, eruption dynamics, deposition conditions, and subsequent geological processes. These variations contribute to the diverse range of tuff types and their importance in understanding Earth’s history and geological processes.

Welded tuff

Welded tuff

Welded tuff is a pyroclastic rock that was sufficiently hot at the time of deposition to weld together. If the rock contains scattered, pea-sized fragments or fiamme in it, it is generally called a welded lapilli-tuff. During welding, the glass shards and pumice fragments stick together, deform and compact.

Rhyolitic tuff

Rhyolitic tuff

Tuff is generally classified according to nature of the volcanic rock of which it consists. Rhyolite tuffs contain pumiceus, glassy fragments and small scoriae with quartz, alkali feldspar, biotite, etc. The broken pumice is clear and isotropic, and very small particles commonly have crescentic, sickle-shaped, or biconcave outlines, showing that they are produced by the shattering of a vesicular glass, sometimes described as ash-structure.

Trachyte tuff

Trachyte tuffs contain little or no quartz, but much sanidine or anorthoclase and sometimes oligoclase feldspar, with occasional biotite, augite, and hornblende. In weathering, they often change to soft red or yellow clay-stones, rich in kaolin with secondary quartz.

Andesitic tuff

Andesitic tuff

In color, they are red or brown; their scoriae fragments are of all sizes from huge blocks down to minute granular dust. The cavities are filled with many secondary minerals, such as calcite, chlorite, quartz, epidote, or chalcedony; in microscopic sections, though, the nature of the original lava can nearly always be made out from the shapes and properties of the little crystals which occur in the decomposed glassy base.

Basaltic tuff

Basaltic tuff

Basaltic tuffs are also of widespread occurrence both in districts where volcanoes are now active and in lands where eruptions have long since ended. They are black, dark green, or red in colour; vary greatly in coarseness, some being full of round spongy bombs a foot or more in diameter; and being often submarine, may contain shale, sandstone, grit, and other sedimentary material, and are occasionally fossiliferous.

Ultramafic tuff

Ultramafic tuffs are extremely rare; their characteristic is the abundance of olivine or serpentine and the scarcity or absence of feldspar and quartz. Rare occurrences may include unusual surface deposits of maars of kimberlites of the diamond-fields of southern Africa and other regions. The principal rock of kimberlite is a dark bluish-green, serpentine-rich breccia (blue-ground) which when thoroughly oxidized and weathered becomes a friable brown or yellow mass (the “yellow-ground”).

Folding and metamorphism

In course of time, changes other than weathering may overtake tuff deposits. Sometimes, they are involved in folding and become sheared and cleaved. The green color is due to the large development of chlorite. Among the crystalline schists of many regions, green beds or green schists occur, which consist of quartz, hornblende, chlorite or biotite, iron oxides, feldspar, etc., and are probably recrystallized or metamorphosed tuffs. They often accompany masses of epidiorite and hornblende – schists which are the corresponding lavas and sills. Some chlorite-schists also are probably altered beds of volcanic tuff.

Formation Process of Tuff Rock

  1. Volcanic Eruptions and Ash Generation: Tuff rock forms as a result of explosive volcanic eruptions. During such eruptions, molten rock, ash, gas, and other volcanic materials are violently expelled from a volcanic vent. The erupted materials can include fine ash particles, larger rock fragments, pumice, and even molten lava. The explosiveness of the eruption is often influenced by the composition of the magma, with silica-rich magmas tending to produce more explosive eruptions.
  2. Deposition and Compaction of Volcanic Ash: Once ejected into the atmosphere, the volcanic ash and other debris are carried by winds and gravity. Over time, these materials settle back down to the Earth’s surface. The finer ash particles can travel great distances, forming layers of volcanic ash that cover a wide area. As these layers accumulate, they create stratigraphic sequences of ash deposits. The weight of the accumulating layers, combined with further sedimentation and water infiltration, leads to compaction of the volcanic ash.
  3. Diagenesis and Lithification of Tuff: Diagenesis refers to the physical and chemical changes that occur to sediments as they are buried and compacted over time. In the case of tuff, diagenesis plays a crucial role in transforming loose volcanic ash deposits into solid rock. Here are the steps involved:a. Compaction: As layers of volcanic ash accumulate, the weight of overlying sediments compacts the ash particles, reducing the pore spaces between them.b. Cementation: As groundwater percolates through the compacted ash layers, it carries dissolved minerals in solution. These minerals can precipitate and fill the pore spaces between the ash particles, acting as a natural cement that binds the particles together.c. Mineralization: Over time, the minerals within the groundwater may react with the volcanic ash, leading to the formation of new minerals or alteration of existing ones. This mineralization further strengthens the rock.d. Lithification: The combination of compaction, cementation, and mineralization leads to the lithification of the volcanic ash layers, transforming them into solid tuff rock. The once-loose ash becomes a coherent rock unit with defined layers and a consolidated structure.

The resulting tuff rock can exhibit a range of textures, from fine-grained to coarse-grained, depending on factors such as the size of the original volcanic particles, the degree of compaction, and the types of minerals that precipitate during diagenesis. Tuff rock is often characterized by its light color and porous nature, making it distinct from other types of sedimentary rocks. Over time, tuff rock can become an integral part of the geological record, providing insights into past volcanic activity and environmental conditions.

Geological Characteristics of Tuff Rock

  1. Texture, Grain Size, and Porosity:
    • Texture: Tuff rock can exhibit a variety of textures, depending on factors such as the size of volcanic particles and the degree of compaction. It can range from fine-grained to coarse-grained. Fine-grained tuff has smaller, closely packed particles, while coarse-grained tuff has larger, more loosely arranged particles.
    • Grain Size: The grain size of tuff is determined by the size of the volcanic ash and debris that make up the rock. This can vary from microscopic particles to visible rock fragments and pumice. Coarse-grained tuff may have distinct layers or bands of different-sized particles.
    • Porosity: Tuff is typically characterized by its porosity, which refers to the amount of open space or voids within the rock. The porosity of tuff is a result of the original spaces between volcanic particles and the subsequent compaction and cementation processes. High porosity can impact the rock’s strength, water-holding capacity, and other physical properties.
  2. Mineral Composition and Presence of Phenocrysts:
    • Mineral Composition: The mineral composition of tuff is primarily determined by the minerals present in the original volcanic ash and debris. Common minerals found in tuff include quartz, feldspar, mica, and various volcanic glass fragments. These minerals may undergo alteration and mineralization during diagenesis, leading to the formation of new minerals.
    • Phenocrysts: Phenocrysts are larger crystals that can be embedded within the fine-grained matrix of tuff. These crystals are often formed within the volcanic magma before eruption and are then incorporated into the ash and debris during the eruption. The presence of phenocrysts can provide clues about the composition and origin of the volcanic material.
  3. Color Variations and Geological Implications:
    • Color: Tuff rock can display a wide range of colors, including shades of white, gray, brown, red, and even green, depending on the mineral content and the presence of iron oxide and other pigments. The coloration can be influenced by the original composition of the volcanic material, as well as subsequent chemical changes and weathering processes.
    • Geological Implications: Color variations in tuff can provide valuable information about the depositional environment, the volcanic source, and the history of the rock. For example:
      • Light-colored tuff may indicate a higher proportion of silica-rich volcanic material.
      • Darker colors might suggest the presence of volcanic glass or mafic minerals.
      • Red or brown hues often result from the presence of iron oxides, which can indicate oxidizing conditions.
      • Greenish tuffs may be associated with volcanic activity rich in magnesium and iron.
      • Color changes within layers can reflect changes in volcanic activity over time.

Geologists use these geological characteristics, along with other field observations and laboratory analyses, to interpret the origin, depositional history, and potential environmental conditions during the formation of tuff rock. Studying tuff can provide insights into past volcanic eruptions, sedimentary processes, and changes in Earth’s surface through geologic time.

Distribution and Occurrence of Tuff Rock

  1. Global Distribution of Tuff Deposits: Tuff deposits are found in various parts of the world, often associated with regions of past or present volcanic activity. They can be located near active volcanoes, along volcanic arcs, within volcanic calderas, or in areas where ancient volcanic activity occurred. Tuff deposits are present on nearly every continent and can provide valuable insights into the history of volcanic activity and the geologic evolution of different regions.
  2. Tuff Rock Formations in Specific Volcanic Regions:
    • Mediterranean Region: The Mediterranean region is well-known for its tuff formations. The city of Rome, for instance, is built upon tuff deposits, and many historical sites, such as the Colosseum and the Roman Forum, feature tuff-based structures.
    • Yellowstone National Park, USA: The Yellowstone Caldera, a supervolcano, has produced massive tuff deposits over its history. The park is home to the famous Yellowstone tuff, a series of volcanic ash deposits resulting from past eruptions.
    • Cappadocia, Turkey: This region is famous for its unique tuff formations known as “fairy chimneys.” Tuff erosion has created stunning rock formations that have been used as dwellings, churches, and other structures.
    • Tuff Rings and Cones: Some volcanic regions, such as New Zealand and parts of the United States, feature tuff rings and cones formed by explosive phreatomagmatic eruptions. These eruptions involve the interaction of magma with water, resulting in the ejection of steam and ash.

Significance of Tuff Rock in Understanding Past Volcanic Activity:

  1. Eruption History: Tuff deposits provide a record of past volcanic eruptions, including information about eruption frequency, intensity, and style. Studying the layers and characteristics of tuff can help scientists reconstruct the history of volcanic activity in a region.
  2. Volcanic Hazards: Analyzing tuff formations can help assess the potential hazards posed by volcanoes. By understanding the types of eruptions that produced tuff deposits, scientists can better predict and prepare for future volcanic events.
  3. Depositional Processes: Tuff deposits offer insights into the processes of ash deposition, sedimentation, and erosion. They can help researchers understand how volcanic materials are transported by air and water, contributing to the overall understanding of sedimentary processes.
  4. Climate and Environmental Changes: The mineral composition and geochemical characteristics of tuff can provide information about the environmental conditions at the time of eruption. Tuff layers can serve as markers for specific geological time periods and can aid in studying past climate changes.
  5. Magmatic Evolution: The mineralogy and chemistry of tuff can reveal details about the composition and evolution of the magma source. Phenocrysts and mineral assemblages within tuff can offer insights into the nature of the volcanic plumbing system.
  6. Dating Techniques: Tuff deposits often contain minerals that can be dated using radiometric dating methods. These dates help establish a chronological framework for volcanic and geological events, aiding in the construction of geological timelines.

In summary, tuff rock deposits are valuable geological archives that provide information about past volcanic activity, depositional processes, and environmental conditions. They contribute to our understanding of Earth’s history, the dynamics of volcanic systems, and the interactions between the geosphere and the surrounding environment.

Petrological Analysis of Tuff Rock

Petrological analysis involves the detailed study of rocks, including tuff, at a microscopic and macroscopic level to understand their mineralogical composition, texture, and overall origin. Here’s how the process of petrological analysis for tuff samples typically unfolds:

  1. Sample Preparation:
    • Tuff samples are collected from field locations or drill cores.
    • Samples are cut into thin sections using specialized equipment, resulting in thin slices of rock that can be studied under a petrographic microscope.
  2. Microscopic Examination:
    • Thin sections of tuff are observed under a petrographic microscope, which allows for detailed examination of mineral composition, texture, and relationships between mineral grains.
    • Key features, such as mineral shapes, sizes, colors, and orientations, are noted.
  3. Identification of Minerals and Components:
    • Mineral identification involves using various optical properties, such as birefringence, color, and cleavage, to determine the minerals present.
    • Common minerals found in tuff include quartz, feldspar, mica, volcanic glass, and various accessory minerals.
    • Phenocrysts, if present, are identified and their mineralogy noted. Phenocrysts are larger crystals embedded within the finer matrix of the tuff.
  4. Texture and Structures:
    • Petrologists examine the texture of the tuff, which includes characteristics like grain size, grain arrangement, and presence of vesicles (gas bubbles).
    • Vesicles can provide insights into the degree of explosiveness of the eruption and the gas content of the magma.
  5. Geochemical Analysis and Insights into Volcanic History:
    • Geochemical analysis involves determining the chemical composition of the tuff, including major and trace elements.
    • X-ray fluorescence (XRF) and inductively coupled plasma mass spectrometry (ICP-MS) are common techniques for geochemical analysis.
    • Geochemical data can provide insights into the source of the volcanic material, the nature of the magma, and potential changes in volcanic activity over time.
    • Isotopic analyses (e.g., radiogenic isotopes) can help determine the age of the tuff and the underlying volcanic processes.
  6. Mineral Alteration and Weathering:
    • Petrologists assess any signs of mineral alteration or weathering, which can provide information about post-depositional changes in the tuff.
  7. Integration of Results:
    • The results from microscopic examination, mineral identification, texture analysis, and geochemical studies are integrated to build a comprehensive understanding of the tuff’s petrological characteristics and its geologic history.

Petrological analysis of tuff samples is crucial for unraveling the story of past volcanic events, understanding the conditions under which tuff deposits formed, and deciphering the broader geological context of a region. This analysis contributes to our knowledge of volcanic processes, magmatic evolution, and Earth’s dynamic history.

Engineering and Industrial Applications of Tuff Rock

  1. Use of Tuff Rock as Construction Material: Tuff rock has been used as a construction material for centuries due to its favorable properties, such as its lightweight nature, ease of quarrying, and workability. Some of its applications in construction include:
    • Building Facades: Tuff can be cut into blocks or carved to create decorative facades and architectural details for buildings.
    • Structural Components: Tuff blocks can be used as load-bearing walls and structural elements in construction projects.
    • Ornamental Elements: Tuff’s softness allows for intricate carving, making it suitable for ornamental features, sculptures, and reliefs.
    • Historical and Cultural Heritage: Many ancient structures and monuments around the world are constructed from tuff, contributing to their historical and cultural significance.
  2. Tuff as a Lightweight Aggregate in Concrete: Tuff can also be crushed and used as a lightweight aggregate in concrete production. Lightweight concrete made with tuff aggregates offers several advantages:
    • Reduced Weight: Lightweight concrete made with tuff aggregates is significantly lighter than traditional concrete, making it useful in applications where weight is a concern.
    • Thermal Insulation: The porous nature of tuff can contribute to improved thermal insulation properties in lightweight concrete.
    • Reduced Shrinkage: Tuff aggregates can help reduce the overall shrinkage of concrete, leading to improved durability.
    • Workability: Lightweight concrete made with tuff aggregates can have improved workability, making it easier to place and finish.
  3. Tuff’s Role in Geothermal Energy Production: Tuff rock has a significant role in geothermal energy production, particularly in areas with high-temperature geothermal resources. Geothermal power plants harness the heat from Earth’s interior to generate electricity. Tuff’s properties contribute to this process:
    • Reservoir Rock: Tuff can act as a reservoir rock that contains hot water or steam generated by subsurface heat. The porous nature of tuff allows for the storage and movement of geothermal fluids.
    • Permeability: Tuff’s permeability allows geothermal fluids to flow through fractures and pores, facilitating the circulation of hot fluids that can be used to generate energy.
    • Enhanced Geothermal Systems (EGS): Tuff formations can also be used in enhanced geothermal systems, where water is injected into hot rocks to create artificial geothermal reservoirs for energy production.

Tuff’s versatility, lightweight nature, and porous properties make it suitable for a range of engineering and industrial applications. Its use in construction, concrete production, and geothermal energy underscores its importance in contributing to sustainable development and resource utilization.

Archaeological and Paleontological Significance of Tuff Rock

  1. Tuff as a Preservation Medium for Fossils: Tuff rock can play a crucial role in the preservation of fossils due to its rapid burial and protective properties. When volcanic ash and debris cover organisms and other materials, they create a protective environment that can prevent or delay decay. This process, known as taphonomy, can lead to exceptional fossil preservation, capturing details that might otherwise be lost. Fossils preserved within tuff deposits provide valuable insights into ancient ecosystems, species, and evolutionary history.
  2. Role of Tuff in Archaeological Dating and Stratigraphy: Tuff deposits are important markers in archaeological and geological stratigraphy. They can be used for dating and correlating different layers of sedimentary and volcanic rocks:
    • Radiometric Dating: Some minerals within tuff deposits, such as zircon or feldspar, contain radioactive isotopes that decay over time. By analyzing the ratios of parent and daughter isotopes, scientists can determine the age of the tuff layer, providing a minimum age for the fossils or artifacts found within it.
    • Relative Dating: Tuff layers act as temporal markers, allowing archaeologists and geologists to establish the relative sequence of events in different locations. Tuff layers can be correlated across sites based on their unique mineralogy and composition.
  3. Famous Tuff Sites and Their Historical Importance:
    • Laetoli, Tanzania: Tuff layers at the Laetoli site contain footprints of early hominins, providing valuable information about their behavior and locomotion nearly 3.6 million years ago.
    • Pompeii and Herculaneum, Italy: The eruption of Mount Vesuvius in 79 AD covered the ancient Roman cities of Pompeii and Herculaneum in tuff and volcanic ash. This preserved these cities, including buildings, artwork, and even the remains of inhabitants, offering a unique snapshot of Roman life at the time.
    • Olduvai Gorge, Tanzania: Tuff layers at Olduvai Gorge have yielded important archaeological and paleontological finds, including stone tools and hominin remains, contributing to our understanding of human evolution.
    • Taung, South Africa: Tuff layers at Taung contained the fossilized skull of the “Taung Child,” an early hominin of the species Australopithecus africanus, discovered by Raymond Dart in 1924.

These tuff sites and many others have provided crucial insights into human history, evolution, and the ancient environments in which our ancestors lived. Tuff’s role in preserving fossils and establishing chronological frameworks has contributed significantly to our understanding of Earth’s past and the development of life on our planet.

Scoria

Scoria is a type of volcanic rock that forms from the solidification of molten lava. It is commonly found around and on the surface of active and dormant volcanoes. Scoria has distinctive characteristics that make it unique and recognizable among other types of volcanic rocks.

Definition: Scoria is an extrusive igneous rock, meaning it is formed from lava that has erupted from a volcano and cooled quickly on the Earth’s surface. It is often referred to as “lava rock” due to its origin from lava flows. Scoria is composed primarily of vesicles (small cavities) and solidified lava fragments. These vesicles are the result of gas bubbles escaping from the molten lava during its rapid cooling and solidification.

Name Origin: The word scoria comes from the Greek “skoria”= rust

Texture: aphanitic and vesicular (contains abundant large gas cavities)

Composition: intermediate (andesitic) to mafic (basaltic)

Color: black or dark brown

Cooling Rate: rapid, extrusive

Intrusive Equivalent: diorite or gabbro

Other Characteristics: vesicular like pumice, but denser and darker with larger vesicles

Origin: Extrusive/Volcanic

Mineral Composition: Predominantly Glass

Tectonic Environment: Divergent Boundary or Intra-oceanic hot spots

Comparisons: Scoria differs from pumice, another vesicular volcanic rock, in having larger vesicles and thicker vesicle walls, and hence is denser. The difference is probably the result of lower magma viscosity, allowing rapid volatile diffusion, bubble growth, coalescence, and bursting.

Formation and Composition

Formation and Composition of Scoria

Formation and Composition: Scoria forms as a result of volcanic activity and the solidification of molten lava. When magma (molten rock beneath the Earth’s surface) reaches the surface during a volcanic eruption, it is called lava. This lava often contains dissolved gases, such as water vapor and carbon dioxide. As the lava reaches the lower pressure of the Earth’s surface, these gases start to come out of solution and form bubbles within the lava.

The rapid cooling of the lava on the surface causes the bubbles to become trapped within the solidifying rock. This leads to the characteristic vesicles (cavities) that are a defining feature of scoria. The vesicles can vary in size and distribution, giving different scoria samples their unique appearances.

The composition of scoria is primarily determined by the composition of the magma from which it forms. Generally, scoria is rich in iron and magnesium, which gives it its dark color. It also contains other minerals that are common in volcanic rocks, such as feldspar and pyroxene. The specific mineral composition can vary widely based on the source magma and local geological conditions.

Geological Occurrence: Scoria is commonly found in regions with recent or past volcanic activity. It is often associated with basaltic or andesitic volcanic eruptions. Some of the key geological occurrences of scoria include:

  1. Volcanic Cones and Craters: Scoria is often found around the vent of a volcano and within its craters. During eruptions, scoria may accumulate in the immediate vicinity of the vent, forming cone-shaped hills or mounds known as volcanic cones.
  2. Lava Flows: Scoria is frequently observed on the surface of lava flows, where it can accumulate in layers. As the lava flows down the sides of a volcano and cools, scoria can solidify and form a rough and porous surface.
  3. Tephra Deposits: Tephra refers to any fragmented material that is ejected during a volcanic eruption, including ash, lapilli (small rock fragments), and scoria. Scoria can be found in tephra deposits that have settled over a wider area around a volcano.
  4. Cinder Cones: Cinder cones are small, steep-sided volcanoes that are often built up from the accumulation of volcanic ash, lapilli, and scoria ejected during relatively mild eruptions.
  5. Volcanic Plateaus: In some cases, large lava plateaus or flows can form extensive layers of scoria. These plateaus are the result of massive lava eruptions that cover large areas with thick layers of lava and scoria.
  6. Historical and Recent Eruptions: Scoria can also be found in regions with historical or recent volcanic eruptions. In areas with ongoing volcanic activity, such as the Pacific Ring of Fire, scoria can continue to accumulate on the surface over time.

Overall, scoria’s geological occurrence is closely tied to volcanic processes and can provide valuable insights into a region’s volcanic history and activity.

Physical Properties of Scoria

Scoria from Yellowstone, Wyoming.

Scoria, a type of volcanic rock, possesses distinct physical properties that stem from its unique formation process and composition. Here are some of the key physical properties of scoria:

  1. Texture: Scoria typically has a porous and vesicular texture, which means it contains numerous cavities or vesicles formed by trapped gas bubbles during the rapid cooling and solidification of lava. The vesicles give scoria a rough, sponge-like appearance.
  2. Color: Scoria comes in a range of colors, including black, reddish-brown, dark brown, and variations in between. The color is often influenced by the presence of minerals such as iron and magnesium.
  3. Density: Due to its high porosity, scoria is relatively lightweight compared to other rocks. Its density can vary, but it is generally less dense than denser volcanic rocks like basalt. This characteristic makes scoria useful for various applications, such as lightweight aggregates.
  4. Porosity: Scoria is characterized by its high porosity, which is a measure of the amount of open space (pores, voids, or vesicles) within the rock. The vesicles are irregularly shaped and can vary in size, contributing to the overall porous nature of the rock.
  5. Hardness: Scoria is not as hard as some other volcanic rocks like basalt. It can be relatively easy to break apart or crush, making it suitable for certain construction and decorative uses.
  6. Weight: As a lightweight rock, scoria is often used in applications where weight is a concern, such as in the production of lightweight concrete, garden landscaping, and as an aggregate in lightweight cinder blocks.
  7. Luster: Scoria typically has a dull to matte luster, which means it does not exhibit a reflective or shiny appearance when light is shone upon it.
  8. Fracture: Scoria generally exhibits a rough and irregular fracture pattern, consistent with its porous and vesicular nature.
  9. Heat Insulation: The porous structure of scoria makes it a good insulator of heat and sound. This property has led to its use in some construction and insulation applications.
  10. Water Absorption: Scoria’s porosity allows it to absorb and retain water, which can be advantageous in certain gardening and horticultural applications.
  11. Weathering: Over time, scoria can undergo weathering and erosion due to exposure to the elements, causing the rock to break down and the vesicles to become more rounded.
  12. Specific Uses: Because of its physical properties, scoria has been used in a variety of ways, including as a lightweight aggregate in concrete, for decorative landscaping purposes, and in the production of lightweight construction materials.

It’s important to note that the specific physical properties of scoria can vary depending on factors such as its mineral composition, cooling rate, and geological environment.

Uses of Scoria

Uses of Scoria

Scoria, with its unique properties, has been utilized for various practical and decorative purposes. Its lightweight and porous nature make it suitable for specific applications. Here are some common uses of scoria:

  1. Construction Aggregates: Scoria can be crushed and used as an aggregate material in construction projects such as concrete and asphalt. Its lightweight nature helps reduce the overall weight of the construction material, which can be advantageous in certain applications.
  2. Lightweight Concrete: Scoria aggregates are often used in the production of lightweight concrete. This type of concrete is suitable for situations where a reduced overall weight is desired, such as in the construction of buildings, bridges, and other structures.
  3. Cinder Blocks: Scoria can be incorporated into the production of lightweight cinder blocks, which are used in construction for their insulation properties and lower weight compared to traditional concrete blocks.
  4. Drainage and Filtration: The porous nature of scoria makes it useful for drainage and filtration applications. It can be used as a drainage layer in landscaping projects, including garden beds, to promote proper water drainage and prevent waterlogging.
  5. Landscaping and Gardening: Scoria is commonly used in landscaping for pathways, decorative mulching, and rock gardens. Its distinct appearance and texture can add visual interest to outdoor spaces.
  6. Heat and Sound Insulation: Scoria’s porous structure makes it a good insulator of both heat and sound. It has been used in the construction of walls and barriers to help manage temperature and noise.
  7. Horticulture: In gardening, scoria can be used as a growing medium in hydroponic systems or as a component of soil mixes for potted plants. Its water-retention properties can help maintain proper moisture levels for plant growth.
  8. Road and Rail Embankments: Scoria has been used in the construction of road and rail embankments due to its lightweight nature and good drainage properties.
  9. Erosion Control: Scoria can be used to stabilize slopes and prevent erosion in certain landscapes.
  10. Art and Decorative Purposes: Scoria’s unique texture and color make it suitable for artistic and decorative applications, such as sculpture, mosaics, and architectural embellishments.
  11. Geological and Educational Displays: Scoria samples are often used in geological displays and educational settings to showcase volcanic processes and rock types.
  12. Lava Rock Jewelry: Polished and shaped scoria pieces can be used to create jewelry and ornaments.

It’s important to note that while scoria has various practical uses, its lightweight and porous nature may limit its suitability for certain high-strength and load-bearing applications. Additionally, its usage can vary based on regional availability and specific project requirements.

Volcanic Processes and Scoria Formation

Scoria formation is closely tied to volcanic processes and the behavior of magma during volcanic eruptions. Understanding the volcanic processes involved in scoria formation can provide insights into how this unique volcanic rock is created. Here’s an overview of the key volcanic processes that lead to scoria formation:

  1. Magma Generation and Ascent: Volcanic activity begins deep within the Earth’s mantle, where molten rock, known as magma, is generated. This magma is less dense than the surrounding rock, allowing it to rise toward the surface. As magma ascends, it can collect in chambers beneath a volcano.
  2. Gas Dissolution: Magma often contains dissolved gases, including water vapor, carbon dioxide, sulfur dioxide, and others. These gases are under high pressure within the magma due to the depth and confinement of the magma chamber.
  3. Eruption Initiation: When pressure within the magma chamber becomes too great, it can overcome the confining rock and trigger a volcanic eruption. As magma rises, it encounters decreasing pressure, causing the dissolved gases to come out of solution and form bubbles or gas pockets.
  4. Eruption and Lava Flow: During an eruption, magma is expelled from the volcano’s vent. If the magma is relatively viscous (thick and sticky), gas bubbles have difficulty escaping. This can result in a buildup of pressure and explosive eruptions. If the magma is less viscous, it can flow more easily and lead to effusive eruptions with relatively gentle lava flows.
  5. Rapid Cooling and Solidification: As the magma is expelled from the vent and comes into contact with the cooler ambient air or water, it cools rapidly and solidifies. This rapid cooling prevents the gas bubbles from escaping completely, and they become trapped within the solidifying lava.
  6. Formation of Vesicles: The trapped gas bubbles, or vesicles, create voids or cavities within the solid rock. These vesicles give scoria its characteristic porous texture. The size and distribution of the vesicles can vary based on factors such as the magma’s gas content and cooling rate.
  7. Accumulation and Fragmentation: As scoria-rich lava is erupted and flows on the surface, it can accumulate in various ways, forming features like volcanic cones, cinder cones, and lava plateaus. In some cases, the lava can fragment into small pieces, known as lapilli, which contribute to the scoria accumulation.
  8. Cooling and Weathering: Over time, scoria continues to cool and may undergo weathering processes, which can round the edges of vesicles and alter its appearance.

It’s important to note that scoria formation can vary based on the specific characteristics of the magma, the style of volcanic eruption, and the geological environment. Different types of volcanic eruptions, such as explosive eruptions or effusive eruptions, can produce scoria with distinct textures and vesicle distributions. Studying scoria can provide valuable insights into the conditions and processes that occur within volcanic systems.

Comparison with Other Volcanic Rocks

To better understand scoria, it’s helpful to compare it with other types of volcanic rocks. Here’s a comparison between scoria, basalt, and pumice, three common volcanic rocks:

  1. Scoria:
    • Formation: Forms from rapidly cooled and solidified lava with trapped gas bubbles, creating vesicles.
    • Texture: Porous and vesicular texture due to vesicle formation. Rough and sponge-like appearance.
    • Color: Can vary but often black, reddish-brown, or dark brown.
    • Density: Relatively lightweight due to high porosity.
    • Uses: Used in construction as lightweight aggregate, in lightweight concrete, cinder blocks, landscaping, and decorative applications.
  2. Basalt:
    • Formation: Forms from slower cooling of lava on the Earth’s surface or underwater.
    • Texture: Aphanitic (fine-grained) to porphyritic (larger crystals embedded in fine matrix) texture. May have vesicles but generally fewer than scoria.
    • Color: Dark gray to black.
    • Density: Denser than scoria, less porous.
    • Uses: Used in construction, road building, and as a dimension stone. Also found in natural formations like columns or pillars.
  3. Pumice:
    • Formation: Forms from highly frothy lava with abundant gas bubbles, leading to rapid vesicle formation.
    • Texture: Extremely porous and vesicular, often with a frothy appearance. Lightweight and can float in water.
    • Color: Light gray to white.
    • Density: Highly porous and very lightweight due to extensive vesicles.
    • Uses: Used as a lightweight abrasive material, in horticulture (as a soil amendment), and for making lightweight concrete and cinder blocks.

Comparing these volcanic rocks highlights their differences in terms of formation, texture, color, density, and uses. Scoria is distinct for its highly vesicular texture and is valued for its lightweight properties in construction and landscaping. Basalt is known for its fine-grained texture and wide range of applications, while pumice is unique in its extreme porosity and use in abrasive and horticultural applications. Understanding these differences helps geologists and scientists classify and study volcanic rocks and their origins.

Distribution of Scoria

Scoria is found in various volcanic regions around the world, often associated with both active and dormant volcanoes. It is commonly found in areas with recent or historical volcanic activity. Here are some notable volcanic regions and specific volcanoes where scoria deposits can be found:

1. Pacific Ring of Fire: The Pacific Ring of Fire is a horseshoe-shaped zone that encircles the Pacific Ocean and is known for its high levels of volcanic and seismic activity. Many of the world’s most well-known and active volcanoes are located in this region, including those with significant scoria deposits.

  • Mount St. Helens, USA: The 1980 eruption of Mount St. Helens produced vast amounts of scoria. The eruption caused the north face of the mountain to collapse, resulting in the largest landslide in recorded history.
  • Sakurajima, Japan: This stratovolcano frequently produces scoria during explosive eruptions. Its ash clouds and volcanic activity have been a recurring feature of the region.

2. East African Rift Valley: This geological rift system in East Africa is known for its active volcanic activity, which has resulted in the formation of various volcanoes and scoria deposits.

  • Mount Nyiragongo, Democratic Republic of Congo: The volcano’s lava lake is a source of continuous volcanic activity, leading to the formation of scoria deposits.

3. Central Andes, South America: The Andes Mountains are home to many volcanoes and volcanic features, including those that produce scoria.

  • Villarrica, Chile: Villarrica is one of Chile’s most active volcanoes and has erupted scoria in its explosive eruptions.

4. Italian Volcanoes: Italy has several active volcanoes, including Mount Vesuvius and Stromboli, known for their eruptions and scoria deposits.

  • Stromboli, Italy: Stromboli is famous for its nearly continuous volcanic activity, producing frequent small eruptions and scoria deposits.

5. Iceland: Iceland’s volcanic activity is linked to its location on the Mid-Atlantic Ridge, a divergent tectonic boundary.

  • Eyjafjallajökull: The 2010 eruption of Eyjafjallajökull produced scoria and disrupted air travel across Europe due to ash clouds.

These examples showcase the global distribution of scoria and its association with various volcanic regions. Scoria deposits are not limited to these regions, as they can be found in many other areas with volcanic activity. The specific characteristics of scoria and its distribution vary based on the local geological conditions, eruption styles, and other factors.

Geological Significance

Geological Significance of Scoria

Scoria holds significant geological importance as it provides valuable insights into volcanic processes, Earth’s internal dynamics, and the history of volcanic activity. Its study contributes to our understanding of various geological phenomena and processes. Here are some key aspects of the geological significance of scoria:

  1. Volcanic Activity and Eruptions: Scoria is a direct product of volcanic eruptions. Studying scoria deposits and their characteristics can help scientists reconstruct past volcanic events, understand eruption mechanisms, and predict potential future volcanic activity.
  2. Magma Properties: The formation of scoria is influenced by the properties of magma, including its composition, gas content, and viscosity. Analyzing scoria can provide information about the source magma and its behavior during eruption.
  3. Volcanic Hazards: The presence of scoria can indicate areas prone to volcanic hazards. Studying scoria deposits helps identify regions that have experienced volcanic eruptions in the past and can assist in assessing potential risks to human settlements and infrastructure.
  4. Evolution of Volcanic Systems: Scoria deposits from different eruptions can reveal the evolving nature of a volcanic system over time. The size, composition, and distribution of scoria can provide insights into the history of magma chambers, eruption styles, and changes in volcanic activity.
  5. Formation of Cones and Craters: Scoria is a key component in the formation of volcanic cones, cinder cones, and craters. Studying the accumulation and distribution of scoria around these features helps geologists understand the building processes of volcanoes.
  6. Volcanic Geomorphology: Scoria deposits contribute to the overall geomorphology of volcanic landscapes. They can create unique landforms, such as lava plateaus, volcanic cones, and lava flows, which shape the surface of the Earth.
  7. Magma Degassing: The vesicles in scoria provide insights into the degassing process of magma during eruption. The size, shape, and distribution of vesicles can reveal the rate of gas escape from magma and the conditions under which it occurred.
  8. Paleoenvironmental Reconstructions: Scoria deposits can sometimes be found interbedded with other sedimentary rocks. These deposits can be used to reconstruct past environmental conditions and changes, providing information about ancient climates and ecosystems.
  9. Geological Dating: Scoria deposits can be dated using various radiometric dating techniques, helping establish the timing of volcanic events and contributing to the development of geological timelines.
  10. Education and Outreach: Scoria is a visually distinctive rock that is often used in educational displays and public outreach programs to help explain volcanic processes and geological concepts to the general public.

In summary, scoria is more than just a volcanic rock; it is a window into Earth’s dynamic geological history, offering valuable information about volcanic activity, magma behavior, and the shaping of landscapes over time. Its study contributes to our broader understanding of Earth’s geological processes and the interactions between the planet’s surface and its internal processes.

Summary of Scoria’s Importance and Utility

Scoria’s Importance and Utility

Scoria is a volcanic rock with distinctive characteristics that hold both practical and scientific significance. Its unique properties and formation processes contribute to its importance and utility in various fields:

  1. Geological Understanding: Scoria provides valuable insights into volcanic processes, eruption dynamics, and Earth’s internal activity. Its study helps geologists reconstruct past volcanic events, predict potential future eruptions, and understand the behavior of magma.
  2. Volcanic Hazard Assessment: The presence of scoria deposits can indicate areas prone to volcanic activity and hazards. Studying scoria aids in assessing risks to human settlements and infrastructure, contributing to better volcanic hazard management.
  3. Environmental Reconstruction: Scoria deposits offer information about past climates and ecosystems when interbedded with other sediments. They help scientists reconstruct ancient environmental conditions and changes over time.
  4. Educational Outreach: Scoria’s unique appearance makes it an effective tool for educational displays and public outreach. It helps explain volcanic processes, geological concepts, and Earth’s dynamic nature to a broader audience.
  5. Volcanic Landform Formation: Scoria is a fundamental component in the formation of volcanic cones, craters, and other volcanic landforms. Its accumulation contributes to the shaping of landscapes and the development of distinct geological features.
  6. Construction Materials: Scoria’s lightweight and porous nature make it suitable for various construction applications. It is used as an aggregate in lightweight concrete, cinder blocks, and road embankments, reducing overall weight and cost.
  7. Landscaping and Horticulture: Scoria’s use in landscaping adds visual interest to outdoor spaces. Its water-retaining properties make it beneficial for drainage and water management in gardens, while also serving as a decorative element.
  8. Heat and Sound Insulation: The porosity of scoria lends itself to insulation applications, such as in construction materials and sound barriers, contributing to energy efficiency and noise reduction.
  9. Art and Aesthetics: Scoria’s texture and color make it suitable for artistic and decorative purposes, including sculptures, mosaics, and architectural embellishments.
  10. Scientific Research: The study of scoria aids in advancing our understanding of magma behavior, volcanic systems, and Earth’s geological history. Its analysis contributes to the broader field of geology and earth sciences.

In essence, scoria’s importance and utility extend beyond its appearance as a volcanic rock. It serves as a valuable tool for scientific research, a practical resource in construction and landscaping, and a means to educate and engage the public in the wonders of Earth’s geological processes.

Pumice

Pumice is a volcanic rock that consists of highly vesicular rough textural rock glass. It generally light colored. It is created when gas-saturated liquid magma erupts like a carbonated drink and cools so rapidly that the resulting foam solidifies into a glass full of gas bubbles. Pumices from silica-rich lavas are white, those from lavas with intermediate silica content are often yellow or brown, and rarer silica-poor that are black. The hollows in the froth can be rounded, elongated, or tubular, depending on the flow of the solidifying lava. The glassy material that forms it can be in threads, fibers, or thin partitions between the hollows. Although pumice is mainly composed of glass, small crystals of various minerals occur. Pumice has a low density due to its numerous air-filled pores. For this reason, it can easily float in water

Name origin: The names derived from the Latin word “pumex” which means foam and through history has been given many names because its formation was unclear.

Texture: Aphanitic and vesicular (contains abundant small gas cavities)

Composition: felsic (rhyolitic)

Color: white to light-gray or light-tan

Cooling Rate: rapid, extrusive

Intrusive Equivalent: granite

Other Characteristics: very light and will float on water

Minerals: Feldspar, augite, hornblende, zircon

Pumice Composition

Pumice is primarily Silicon Dioxide, some Aluminum Oxide and trace amounts pf other oxide. Mall crystals of various minerals occur in many pumices; the most common are feldspar, augite, hornblende, and zircon. The cavities (vesicles) of pumice are sometimes rounded and may also be elongated or tubular, depending on the flow of the solidifying lava. The occurring among old volcanic rocks, the cavities are usually filled with deposits of secondary minerals introduced by percolating water. The glass itself forms threads, fibres, and thin partitions between the vesicles. Rhyolite and trachyte pumices are white, andesite pumices often yellow or brown, and pumiceous basalts (such as occur in the Hawaiian Islands) pitch black.

It forms so quickly that its atoms often don’t have time to organize into crystals. Sometimes there are crystals present in pumice, but most of the structure is amorphous, producing a volcanic glass called a mineraloid.

Pumice Formation

The pumice is formed by contact with the lava water. This occurs most commonly near water or underwater volcanoes. When the hot magma comes into contact with water, rapid cooling and rapid pressure loss reduce bubble by forming lava. The cooling of the rock below the melting point of the rock means that the bubbles are trapped inside when the rock changes into a solid immediately after contact with water. Since the pumice is irreversible, it is sometimes like glass and the bubbles are held between the thin translucent bubble walls of the rock.

Volcanic Gases and Density

If volcanic gases coming from the lava before it cools rapidly, that process can be created to scoria and pumice  It is light colored, has a porosity of about 90 percent and is less dense; scoria is more dense with larger bubbles and thicker bubble walls and is quickly dipped in contrast to the floating boom. If there is too much gas, pumice is formed; When less gas is associated with less viscous magma, the scoria is formed. During the volcanic activity near Tonga, pumice swings from underwater volcanic eruptions were produced, and the pumice can be created quickly and in the past.

Shipping around the World

The actual shipping method depends on the end user. For example, a dentist buys his pumice in a small 2-ounce jar. A manufacturer of hand soap or a computer circuit board manufacturer will receive pumice shipments as shrink-wrapped pallets of 44 lb. bags (20 KG) that arrive via truck or ocean-going container. A public works department using pumice for water filtration may take delivery of their pumice in bulk rail cars. A concrete batch plant will accept a load of pumice (used as a natural pozzolan) in a pneumatic truck. The bottom line is that a company with a pumice deposit in demand world-wide, such as Hess Pumice, necessarily develops the expertise and ability to package pumice however the customer needs it packaged and to ship that pumice efficiently where it’s needed, anywhere in the world.

Where is it located

They are most abundant and most typically developed from felsic (silica-rich) igneous rocks; accordingly, they commonly accompany obsidian. It can be found all around the globe deriving from continental volcanic occurrence and submarine volcanic occurrence. Floating stones can also be distributed by ocean currents.As described earlier it is produced by the eruption of explosive volcanoes under certain conditions, therefore, natural sources occur in volcanically active regions. It is mined and transported from these regions. In 2011, Italy and Turkey led pumice mining production at 4 and 3 million tonnes respectively; other large producers at or exceeding a million tonnes were Greece, Iran, Chile and Syria.

Asia

There are large reserves of pumice in Asian countries including Afghanistan, Indonesia, Japan, Syria, Iran and eastern Russia. Considerable amounts of pumice can be found at the Kamchatka Peninsula on the eastern flank of Russia. This area contains 19 active volcanoes and it lies in close proximity with the Pacific volcanic belt.

Europe

Europe is the largest producer of pumice with deposits in Italy, Turkey, Greece, Hungary and Iceland. Italy is the largest producer of pumice because of its numerous eruptive volcanoes. On the Aeolian Islands of Italy, the island of Lipari is entirely made up of volcanic rock, including pumice.

North America

It can be found all across North America including on the Caribbean Islands. In the United States, This rock is mined in Nevada, Oregon, Idaho, Arizona, California, New Mexico and Kansas. U.S. production of pumice and pumicite in 2011 was estimated at 380,000 tonnes, valued at $7.7 million with approximately 46% coming from Nevada and Oregon. Idaho is also known as a large producer of pumice because of the quality and brightness of the rock found in local reserves.

South America

Chile is one of the leading producers of Pumice in the world.[The Puyehue-Cordón Caulle are two coalesced volcanoes in the Andes mountains that ejected ash and pumice across Chile and Argentina. A recent eruption in 2011 wreaked havoc on the region by covering all surfaces and lakes in ash and pumice.

Africa

Kenya, Ethiopia and Tanzania have some deposits of pumice.

Australia

The Havre Seamount volcano produced the largest-known deep ocean volcanic eruption on Earth. The volcano erupted in July 2012 but remained unnoticed until enormous pieces of pumice were seen to be floating on the Pacific Ocean. Blankets of rock reached a thickness of 5 meters. Most of this floating rock is deposited on the North-West coast of New Zealand and the Polynesia islands action in 2011 was estimated at 17 million tones.

Characteristics and Properties

Pumice is composed of highly microvesicular glass pyroclastic with very thin, translucent bubble walls of extrusive igneous rock. It is commonly,but not exclusively of silicic or felsic to intermediate in composition (e.g., rhyolitic, dacitic, andesite, pantellerite, phonolite, trachyte), but basaltic and other compositions are known. It is commonly pale in color, ranging from white, cream, blue or grey, to green-brown or black. It forms when volcanic gases exsolving from viscous magma form bubbles that remain within the viscous magma as it cools to glass. It is a common product of explosive eruptions (plinian and ignimbrite-forming) and commonly forms zones in upper parts of silicic lavas. It has a porosity of 64–85% by volume and it floats on water, possibly for years, until it is eventually waterlogged and sink.

There are two main forms of vesicles. Most of this rock contains tubular microvesicles that can impart a silky or fibrous fabric. The elongation of the microvesicles occurs due to ductile elongation in the volcanic conduit or, in the case of pumiceous lavas, during flow. The other form of vesicles are subspherical to spherical and result from high vapor pressure during eruption.

Physical Properties

Chemical Name: Amorphous Aluminum Silicate
Hardness (MOHS): 6
pH: 7.2
Radioactivity: none
Loss on Ignition (LOI): 5%
Softening Point: 900 degrees C
Water Soluble Substances: 0.15%
Acid Soluble Substances: 2.9%
Reactivity: Inert
Appearance: white powder (GE brightness of 84)

Chemical Analysis (typical averages)

Silicon Dioxide: 76.2%
Aluminum Oxide: 13.5%
Ferric Oxide: 1.1%
Ferrous Oxide: 0.1%
Sodium Oxide: 1.6%
Potassium Oxide: 1.8%
Calcium Oxide: 0.8%
Titanium Oxide: 0.2%
Magnesium Oxide: 0.05%
Water: <1.0%

Pumice Uses

It is a unique rock, noted for its light weight and low density (dry pumice can float in water). It is commonly used in cement, concrete and breeze blocks and as an abrasive in polishes, pencil erasers, exfoliates and to produce stone-washed jeans. It is also used to remove dry skin from the bottom of the foot during the pedicure process at some beauty salons.

It is a very light weight, porous and abrasive material and it has been used for centuries in the construction and beauty industry as well as in early medicine.

It is also used as an abrasive, especially in polishes, pencil erasers, and the production of stone-washed jeans.

It was also used in the early book making industry to prepare parchment paper and leather bindings. There is high demand for pumice, particularly for water filtration, chemical spill containment, cement manufacturing, horticulture and increasingly for the pet industry.

References

  • Bonewitz, R. (2012). Rocks and minerals. 2nd ed. London: DK Publishing.
  • Atlas-hornin.sk. (2019). Atlas of magmatic rocks. [online] Available at: http://www.atlas-hornin.sk/en/home [Accessed 13 Mar. 2019].
  • Helmenstine, Anne Marie, Ph.D. (2019, March 10). What Is Pumice Rock? Geology and Uses. Retrieved from https://www.thoughtco.com/pumice-rock-4588534

Lamprophyre

Lamprophyre is ultrapotassic igneous rock that is occurring as dikes, lopoliths, loccoliths, stocks and small intrussion. It is alkaline silica-undersaturated mafic or ultramafic rocks with high magnesium oxide, >3% potassium oxide, high sodium oxide and high nickel and chromium. Four minerals dominate these rocks: orthoclase, plagioclase, biotite, and hornblende. Amphibole and biotite tend to occur in a matrix of various combinations of plagioclase and other sodium- and potassium-rich feldspars, pyroxene, and feldspathoids.

In general, they form at great depth and are enriched in sodium, cesium, rubidium, nickel, and chromium, as well as potassium, iron, and magnesium. Some are also source rocks for diamonds. The exact origin of lamprophyres is still debated. They form along the margins of some granites and are often associated with large bodies of intrusive granodiorite.

Name origin: Lamprophyres (Greek λαµπρός (lamprós) = “bright” and φύρω (phýro) = to mix)

Color: Dark brown to black

Group: Extrusive igneous rock

Minerals: Amphibole and biotite tend to occur in a matrix of various combinations of plagioclase and other sodium- and potassium-rich feldspars, pyroxene, and feldspathoids

Dominant Minerals: Orthoclase, plagioclase, biotite, and hornblende

Lamprophyre Classification

Classification of lamprophyres has had several revisions and so much argument within the geology. Modern naming has been derived from an attempt some genetic parameters of lamprphyre genesis.This has, by and large, dispensed with the previous provincial names of lamprophyre species, in favor of a mineralogical name. The old names are still used for convenience.

Streckeisen recognized three main type of lamprophyres:

  • Calc-alkaline lamprophyres
  • Melilitic lamprophyres
  • Alkaline lamprophyres

Calc-Alkaline Lamprophyres

The calc-alkaline lamprophyres are also known as ordinary lamprophyres and they consist of Minettes, Vosegites, Kersantites and Spessartites. This lamprophyres are, in term of average chemical composition, virtually indistinguishable.

Vogesite: Vogesite was first described from the Vosges mountains, France, where rocks of this type (actually, minette) were described in the early 20th century.

Minette: A dike of minette near Shiprock, Navajo Volcanic Field. A historical view of minette was provided by Johannsen (1937). He wrote that the name was ” … used by the miners in the Vosges apparently for oolitic or granular iron ore, and possibly derived from the valley of Minkette.

Spessartites: From Spessart mountains east of Aschaffenburg in Germany. A spessartite is a porphyritic alkaline igneous rock dominated by essential amphibole, usually hornblende, and plagioclase feldspar, often with augite present as an accessory. Plagioclase occurs in the groundmass and potassic feldspar is absent or present in low abundance.

Kersantites: From Kersanton, a village in France, are Plagioclase, Honrblende, Augite lamprophyres.

Alkaline Lamprophyres And Melilitic Lamprophyres

The Alkaline and melilitic lamprophyres will be considered together, because both groups contain alkaline rocks and are usually associated with alkaline complexes and the rocks of the Carbonatite-nepheline-ijolite association. The common alkaline lamprophyres are comptonites, Sannaites and monchiquites and they are chemically akin to the alkaline basalt, basanites and Nephelinites.

Comptonites: From Campton in the New Hampshire (USA). A camptonite is a porphyritic alkaline igneous rock dominated by essential plagioclase and brown amphibole, usually hornblende, often with titanaugite. Plagioclase occurs in the groundmass.

Sannaites: From Sannavand, Fen complex, Sweden. Sannaites are broadly to Comptonites, except that they contain alkali feldspar in place of plagioclase.

Monchiquites: From Sierra de Monchique in Southern Portugal. A monchiquite is a porphyritic alkaline igneous rock dominated by essential olivine, titanaugite and brown hornblende.

Alnöite: From Alno island, Sweden. A alnöite is a porphyritic alkaline igneous rock dominated by essential olivine, biotite and pyroxene, in a groundmass containing melilite. It can contain monticellite.

Polenzite: From Polzen area of the Bohemian massif, Czechoslovakia. Is a melilitic lamprophyre that usually contain between 10-30% of feldspathoids (Nepheline and Hauyne) and it normally contains the same minerals as occur in alnöite.

Lamprophyre Composition

Lamprophres is all term for ultrapotassic mafic igneous rocks which have primary mineralogy consisting of amphibole or biotite, and with feldspar in the groundmass. Four minerals dominate these rocks: orthoclase, plagioclase, biotite, and hornblende. Amphibole and biotite tend to occur in a matrix of various combinations of plagioclase and other sodium- and potassium-rich feldspars, pyroxene, and feldspathoids. Because of their relative rarity and varied composition, lamprophyres do not fit into standard geological classifications. In general, they form at great depth and are enriched in sodium, cesium, rubidium, nickel, and chromium, as well as potassium, iron, and magnesium. Some are also source rocks for diamonds.

Lamprophyre Formation

In all geological periods, lamprophy occurs. Archaic examples are usually associated with gold reserves. Among the Cenozoic examples, the magnesian rocks in Mexico and South America and the young ultramafic lamp lamps from Gympie in Australia are 18.5% MgO at ~ 250 Ma.

Rock lamps thought to be rock are part of a “clan” of rocks with similar mineralogy, textures and formations. Lamprofiller, lamproite and kimberlites. While modern concepts see orange, lampogens and kimberlites separately, the vast majority of the lamprophytes have similar origins to these other rock species.

Mitchell considers the lamprophytes as a “facies” of magmatic rocks created by a number of conditions (usually; late, high volatile differences of other rock species). Both schemes can be applied to all and some of the large rock group known as lamprophyres and melilitic rocks.

Leaving aside the complex petrogenetic arguments, the basic components in the formation of lamprophyre;

  • high depth of melting, which yields more mafic magmas;
  • low degrees of partial melting, which yields magmas rich in the alkalis (particularly potassium);
  • lithophile element (K, Ba, Cs, Rb) enrichment, high Ni and Cr,
  • high potassium and sodium concentrations (silica undersaturation is common)
  • some form of volatile enrichment, to provide the biotite (phlogopite) and amphibole (pargasite) mineralogy
  • lack of fractional crystallisation (generally; there are exceptions)
  • high Mg# ( MgO/(FeO + MgO) )
  • Individual examples thus may have a wide variety of mineralogy and mechanisms for formation. Rock considered lamprophyres to be derived from deep, volatile-driven melting in a subduction zone setting. Others such as Mitchell consider them to be late offshoots of plutons, etc., though this can be difficult to reconcile with their primitive melt chemistry and mineralogy.

Where is the Lamprophyre Rock

Lamprophyres are usually associated with voluminous granodiorite intrusive episodes. They occur as marginal facies to some granites, though usually as dikes and sills marginal to and crosscutting the granites and diorites. In other districts where granites are abundant no rocks of this class are known. It is rare to find only one member of the group present, but minettes, vogesites, kersantites, etc., all appear and there are usually transitional forms.

Non-melilitic lamprophyres are found in many districts where granites and diorites occur, such as the Scottish Highlands and Southern Uplands of Scotland; the Lake District of northwest England; Ireland; the Vosges Mountains of France; the Black Forest and Harz mountain regions of Germany; Mascota, Mexico; Jamaica[8] and in certain locations of British Columbia, Canada.

Economic Importance

The economic importance of ultrapotassic rocks is wide and varied. Kimberlites, lamproites and perhaps even lamprophyres are known to contain diamond. These rocks are all produced at depths in excess of 120 km and thus can bring diamond to the surface as xenocrysts. Ultrapotassic granites are a known hos for much granite-hosted gold mineralisation. Significant porphyry-style mineralisation is won from highly potassic to ultrapotassic granites. Ultrapotassic A-type intracontinental granites may be associated with fluorite and columbite-tantalite mineralization.

Conclusion

  • Lamprophyres are melanocratic, porphyritic, hypabyssal rocks
  • The lamprophyres commonly consists of alkali rich calc-alkali to ultramafic minerals
  • The economic importance of ultrapotassic rocks are wide and varied.

References

  • Bonewitz, R. (2012). Rocks and minerals. 2nd ed. London: DK Publishing.
  • Wikipedia contributors. (2019, March 14). Lamprophyre. In Wikipedia, The Free Encyclopedia. Retrieved 19:30, May 11, 2019, from https://en.wikipedia.org/w/index.php?title=Lamprophyre&oldid=887734669
  • Vale, L. (2019). ALEX STREKEISEN-Sannaite-. Alexstrekeisen.it. Available at: http://www.alexstrekeisen.it/english/vulc/sannaite.php [Accessed 11 May 2019].

Kimberlite

Kimberlite is an igneous rock that major source of diamonds. Kimberlite is a variety of peridotite.  It is rich in mica minerals content and often in form of crystals of phlogopite. Other containt abundant minerals are chrome-diopside, olivine, and chromium- and pyrope-rich garnet.  Kimberlite is typically found in pipes – structures with vertical edges that are roughly circular in cross-section. The rock may have been injected into the areas of weakness in the mantle. Parts of the mantle rocks are often brought to the surface in kimberlites, making them a valuable source of information about the inner world.

Despite its relative rarity, kimberlite has attracted attention because it serves as a carrier of diamonds and garnet peridotite mantle xenoliths to the Earth’s surface. Its probable derivation from depths greater than any other igneous rock type, and the extreme magma composition that it reflects in terms of low silica content and high levels of incompatible trace-element enrichment make an understanding of kimberlite petrogenesis important. In this regard, the study of kimberlite has the potential to provide information about the composition of the deep mantle and melting processes occurring at or near the interface between the cratonic continental lithosphere and the underlying convecting asthenospheric mantle.

Name origin: The rock kimberlite was named after Kimberley, South Africa, where it was first recognized. Kimberley diamonds were originally found in weathered kimberlite, which was colored yellow by limonite, and was therefore called yellow ground. Deeper workings produced less altered rock, serpentinized kimberlite, which miners call blue ground.

Kimberlite Classification

Based on studies on a large number of kimberlite deposits, geologists divided the kimberlites into 3 separate units based on their morphology and petrology.

These units are:

  1. Crater Facies Kimberlite
  2. Diatreme Facies Kimberlite
  3. Hypabyssal Facies Kimberlite

1) Crater Facies Kimberlite

The surface morphology of an unweathered kimberlite is characterised by a crater, up to 2 kilometers in diameter, whose floor may be several hundred meters below ground level. The crater is generally deepest in the middle. Around the crater is a tuff ring which is relatively small, generally less than 30 meters, when compared to the diameter of the crater. Two main categories of rocks are found in crater facies kimberlite: pyroclastic, those deposited by eruptive forces; and epiclastic, which are rocks reworked by water.

2) Diatreme Facies Kimberlite

Kimberlite diatremes are 1-2 kilometer deep, generally carrot-shaped bodies which are circular to elliptical at surface and taper with depth. The dip contact with the host rocks is usually 80-85 degrees. The zone is characterized by fragmented volcanoclastic kimberlitic material and xenoliths plucked from various levels in the Earth’s crust during the kimberlites journey to surface. Some Textural features of Diatreme Facies Kimberlite:

3) Hypabyssal Facies Kimberlite

These rocks are formed by the crystallization of hot, volatile-rich kimberlite magma. Generally, they lack fragmentation features and appear igneous. Some Textural features: Calcite-serpentine segregations in matrix; Globular segregations of kimberlite in a carbonate-rich matrix; Rock fragments have been metamorphosed or exhibit concentric zoning; Inequigranular texture creates a pseudoporphyritic texture.

Carbon and Kimberlite

Carbon is one of the most common elements in the world and is one of the four essentials for the existence of life. Humans are more than 18 percent carbon. The air we breathe contains traces of carbon. When occurring in nature, carbon exists in three basic forms:

Diamond – an extremely hard, clear crystal

Diamonds form about 100 miles (161 km) below the Earth’s surface, in the molten rock of the Earth’s mantle, which provides the right amounts of pressure and heat to transform carbon into diamond. In order for a diamond to be created, carbon must be placed under at least 435,113 pounds per square inch (psi or 30 kilobars) of pressure at a temperature of at least 752 degrees Fahrenheit (400 Celsius). If conditions drop below either of these two points, graphite will be created. At depths of 93 miles (150 km) or more, pressure builds to about 725,189 psi (50 kilobars) and heat can exceed 2,192 F (1,200 C). Most diamonds that we see today were formed millions (if not billions) of years ago. Powerful magma eruptions brought the diamonds to the surface, creating kimberlite pipes.

Kimberlite pipes are created as magma flows through deep fractures in the Earth. The magma inside the kimberlite pipes acts like an elevator, pushing the diamonds and other rocks and minerals through the mantle and crust in just a few hours. These eruptions were short, but many times more powerful than volcanic eruptions that happen today. The magma in these eruptions originated at depths three times deeper than the magma source for volcanoes like Mount St. Helens, according to the American Museum of Natural History.

The magma eventually cooled inside these kimberlite pipes, leaving behind conical veins of kimberlite rock that contain diamonds. Kimberlite is a bluish rock that diamond miners look for when seeking out new diamond deposits. The surface area of diamond-bearing kimberlite pipes ranges from 2 to 146 hectares (5 to 361 acres).

Diamonds may also be found in river beds, which are called alluvial diamond sites. These are diamonds that originate in kimberlite pipes, but get moved by geological activity. Glaciers and water can also move diamonds thousands of miles from their original location. Today, most diamonds are found in Australia, Borneo, Brazil, Russia and several African countries, including South Africa and Zaire.

Kimberlite Emplacement Models

Mitchell (1986) consider several theories and presents a more comprehensive critique of each emplacement theory.

  1. Explosive volcanism theory
  2. Magmatic (fluidization) theory
  3. Hydrovolcanic theory

1. Explosive Volcanism Theory

This theory involves the pooling of kimberlite magma at shallow depths and the subsequent build-ıp of volatiles. When the pressure within this pocket, termed an intermediate chamber, is sufficient to overcome the load of rocks above, an eruption follows. The epicenter of the eruption was believed to be at the diatreme facies contact.

Through extensive mining it is clear that this theory is untenable. No intermediate chamber has been found at depth.

2. Magmatic Theory

This original proponent of this theory was Dowson (1971). It was subsequntly built upon by Clement (1982) and is pushed by Field and Scott Smith (1999)

Kimberlite magma rises from depth with different pulses building termed as “embryonic pipes”. The surface is not breached and the volatiles do not escape  At some point the embryonic pipes reach a shallow enough depth. Whereby the pressure of the volatiles is able to overcome the load of the overlying rocks. As the volatiles are escaping, a brief period of fluidization ensures. Fluidization is believed to be short lived as fragments are commonly angular.

3. Hydrovolcanic Theory

The main proponent of this theory is Lorenz (1999). Kimberlites magmas rise from depth thorough narrow 1m thick fissures. The kimberlite magma is focused along structural faults which act as focuses for waters or resultant brecciation due to volatile exsolution from the rising kimberlites may act as a focus for water. The brecciated rock becomes recharged with groundwater. Another pulse of kimberlite magma follows the some structural weakness in the rock to surface and again comes in contact with water producing another explosion.

Kimberlite Geochemistry

The geochemistry of Kimberlites is defined by the following parameters:

ultramafic, MgO >12% and generally >15%;

ultrapotassic, molar K2O/Al2O3 >3;

near-primitive Ni (>400 ppm), Cr (>1000 ppm), Co (>150 ppm);

REE-enrichment;[14]

moderate to high large-ion lithophile element (LILE)[15] enrichment, ΣLILE = >1,000 ppm;

high H2O and CO2.

Kimberlite Composition

Both the location and origin of kimberlitic magmas are subjects of contention. Their extreme enrichment and geochemistry have led to a large amount of speculation about their origin, with models placing their source within the sub-continental lithospheric mantle (SCLM) or even as deep as the transition zone. The mechanism of enrichment has also been the topic of interest with models including partial melting, assimilation of subducted sediment or derivation from a primary magma source.

Historically, kimberlites have been classified in two different varieties called basaltic” and “micaceous” based on petrographic observations. This was later revised by CB Smith, which renamed “group I” and “group II” of these groups based on the isotopic affinities of these rocks using Nd, Sr and Pb systems. Roger Mitchell later suggested the display of these group I and II kimberlites. These obvious differences may not be as closely related as they once thought. II. The group showed that the kimberlites showed more tendency towards the lampolines than the group I. Therefore, group II reclassified the kimberlites as orange to prevent confusion.

Group I kimberlites

Group-I kimberlites are of CO2-rich ultramafic potassic igneous rocks dominated by primary forsteritic olivine and carbonate minerals, with a trace-mineral assemblage of magnesian ilmenite, chromium pyrope, almandine-pyrope, chromium diopside (in some cases subcalcic), phlogopite, enstatite and of Ti-poor chromite. Group I kimberlites exhibit a distinctive inequigranular texture caused by macrocrystic (0.5–10 mm or 0.020–0.394 in) to megacrystic (10–200 mm or 0.39–7.87 in) phenocrysts of olivine, pyrope, chromian diopside, magnesian ilmenite, and phlogopite, in a fine- to medium-grained groundmass.

Olivine lamproites

Olivine lamproites were previously called group II kimberlite or orangeite in response to the mistaken belief that they only occurred in South Africa. Their occurrence and petrology, however, are identical globally and should not be erroneously referred to as kimberlite.Olivine lamproites are ultrapotassic, peralkaline rocks rich in volatiles (dominantly H2O). The distinctive characteristic of olivine lamproites is phlogopite macrocrysts and microphenocrysts, together with groundmass micas that vary in composition from phlogopite to “tetraferriphlogopite” (anomalously Al-poor phlogopite requiring Fe to enter the tetrahedral site). Resorbed olivine macrocrysts and euhedral primary crystals of groundmass olivine are common but not essential constituents.

Kimberlitic indicator minerals

Kimberlites are peculiar igneous rocks because they contain a variety of mineral species with chemical compositions that indicate they formed under high pressure and temperature within the mantle. These minerals, such as chromium diopside (a pyroxene), chromium spinels, magnesian ilmenite, and pyrope garnets rich in chromium, are generally absent from most other igneous rocks, making them particularly useful as indicators for kimberlites.

Economic importance of Kimberlite

Kimberlites are the most important source of diamonds in the world. About 6,400 kimberlite pipes have been discovered in the world, of those about 900 have been classified as diamondiferous, and of those just over 30 have been economic enough to diamond mine.

The deposits occurring at Kimberley, South Africa, were the first recognized and the source of the name. The Kimberley diamonds were originally found in weathered kimberlite, which was colored yellow by limonite, and so was called “yellow ground”. Deeper workings encountered less altered rock, serpentinized kimberlite, which miners call “blue ground”.

The blue and yellow ground were both prolific producers of diamonds. After the yellow ground had been exhausted, miners in the late 19th century accidentally cut into the blue ground and found gem-quality diamonds in quantity. The economic importance of the time was such that, with a flood of diamonds being found, the miners undercut each other’s prices and eventually decreased the diamonds’ value down to cost in a short time.

Kimberlite Formation

The general consensus is that kimberlites are formed deep within the mantle, at depths between 150 and 450 kilometers, from anomalously enriched exotic mantle compositions. They are erupted rapidly and violently, often with the release of considerable amounts of carbon dioxide (CO2) and volatile components. The violent explosions produce vertical columns of rock—volcanic pipes or kimberlite pipes—that rise from the magma reservoirs. The depth of melting and the process of generation makes kimberlites prone to hosting diamond xenocrysts.

The morphology of kimberlite pipes is varied, but it generally includes a sheeted dike complex of vertically dipping feeder dikes in the root of the pipe, extending down to the mantle. Within 1.5-2 kilometers (km) of the surface, as the magma explodes upward, it expands to form a conical to cylindrical zone called the diatreme, which erupts to the surface.

The surface expression is rarely preserved, but it is usually similar to a maar volcano. The diameter of a kimberlite pipe at the surface is typically a few hundred meters to a kilometer.

Many kimberlite pipes are believed to have formed about 70 to 150 million years ago, but in Southern Africa, there are several that formed between 60 to 1,600 million years ago (Mitchell, 1995, p. 16).

Conclusion

  • Kimberlite magmas are rich in carbondioxide and water which brings the magma quickly and violently to the mantle.
  • Kimberlite is a gas rich potassic ultramafic igneous rock.
  • Auistralia is currently the world’s largest producer of diamonds are low quality and used for industrial purposes.
  • The crater facies kimnerlite is recognized by sedimentary features.
  • The diatreme facies are recognized by pelletal lapilli.
  • The hypabyssal facşes şs commonly recognized by segregationary texture and the presence of abundant cancite.

References

  • Bonewitz, R. (2012). Rocks and minerals. 2nd ed. London: DK Publishing.
  • Kurszlaukis, S., & Fulop, A. (2013). Factors controlling the internal facies architecture of maar-diatreme volcanoes. Bulletin of Volcanology, 75(11), 761.
  • Wikipedia contributors. (2019, February 14). Kimberlite. In Wikipedia, The Free Encyclopedia. Retrieved 16:10, May 11, 2019, from https://en.wikipedia.org/w/index.php?title=Kimberlite&oldid=883239063

Pyroxenite

Pyroxenite is an ultramafic igneous rock that contain pyroxene group minerals such as augite, diopside, hypersthene, bronzite or enstatite. This is a coarse-grained rock and that contains at least 90 percent pyroxene minerals. Also Pyroxenite contain olivine and oxide minerals, when it occurs in layered intrusions or nepheline. It is hard and heavy rock and color is light green. Single crystals may be 3 inc or more in lenght. Pyroxenites are usually found with gabbros and peridotites. There are three type of pyroxenite rock that areclinopyroxenites, orthopyroxenites, and the websterites.

Color: Light green, dark green, or black

Protolith or Parent Rock:

Hardness: 5 to 7

Grain size: Coarse-grained texture

Group: Ultramafic igneous rock

Alterations: Crystallization of a silica-poor magma in a major intrusion

Minerals: Pyroxene, Biotite, hornblende, olivine, plagioclase, nepheline

Dominant Minerals: Pyroxene

Pyroxenite Classification

There are three type of pyroxenite rock that areclinopyroxenites, orthopyroxenites, and the websterites.

Orthopyroxene

Orthopyroxene partitions nickel, cobalt, and manganese less than olivine and there are no clear correlations amongst these elements. Although low in abundance, orthopyroxene can be a significant reservoir for the trivalent cations vanadium, scandium plus tetravalent titanium, due to its high modal abundance, especially in depleted xenoliths with little or no clinopyroxene. The abundances of strontium, niobium, zirconium, and yttrium in orthopyroxenes are near or below the ppm-level and show no clear correlations. A general feature is enrichment of titanium, zirconium, and niobium relative to coexisting clinopyroxene. The few measurements of the REE patterns in orthopyroxene are typically LREE-depleted, with all REE one to two orders of magnitude below clinopyroxene. There is far more scatter and far less coherent variation amongst many incompatible trace elements in orthopyroxene, likely reflecting more heterogeneity on the micro-scale as well as temperature effects that are not well understood with the paucity of data available (D.G.Pearson.,D.Canil.,S.B.Shirey, 2003 )

Clinopyroxene

Clinopyroxene is a major host for sodium, calcium, chromium, and titanium in mantle xenoliths and shows extensive solid solution toward orthopyroxene and/or garnet at high P and T in the mantle (Boyd, 1969, 1970; Brey and Köhler, 1990). The Mg# of clinopyroxene is usually slightly greater than that of coexisting olivine, due to a KD greater than 1. The calcium content of clinopyroxene is strongly T-dependent and is between 40 mol.% and 50 mol.% wollastonite component. Subcalcic clinopyroxenes (Wo<35%) occur in cratonic suites as megacrysts or discrete nodules, and indicate very high T of equilibration, perhaps in equilibrium with melt
D.G.Pearson.,D.Canil.,S.B.Shirey (2003) .

Websterite

Websterite is ultramafic igneous rock that consists of roughly equal proportions of orthopyroxene and clinopyroxene. It is a type of pyroxenite.

Triangle diagram for peridotites. Axis are olivine-clinopyroxene-orthopyroxene. Fields include peridotite, pyroxenite, dunite, lherzolite, harzburgite, wehrlite, olivine-websterite, websterite, orthopyroxenite, clinopyroxenite.
Triangle diagram for peridotites. Axis are olivine-clinopyroxene-orthopyroxene. Fields include peridotite, pyroxenite, dunite, lherzolite, harzburgite, wehrlite, olivine-websterite, websterite, orthopyroxenite, clinopyroxenite. 

Pyroxenite Composition

Pyroxenite composition is contain at least 90 percent pyroxene group minerals, such as as augite, diopside, hypersthene, bronzite or enstatite.Pyroxenite also contain olivine and oxide minerals. Pyroxenite has less olivine than peridotites. The principal minerals usually found accompanying pyroxenites, in addition to olivine and feldspar, are chromite and other spinels, garnet, rutile, and magnetite. It has been proposed that large volumes of pyroxenite form in the upper mantle. Rare metamorphic pyroxenites are known and are described as pyroxene hornfels.

Where is the Pyroxenite Located

They frequently occur in the form of dikes or segregations in gabbro and peridotite: in Shetland, Cortland on the Hudson River, North Carolina (websterite), Baltimore, New Zealand, and in Saxony. They are also found in the Bushveld Igneous Complex in South Africa and Zimbabwe.

Classification diagram for peridotite and pyroxenite, based on proportions of olivine and pyroxene. The pale green area encompasses the most common compositions of peridotite in the upper part of the Earth’s mantle

The pyroxenites are often subject serpentinization under low temperature retrograde metamorphism and weathering. The rocks are often completely replaced by serpentines, which sometimes preserve the original structures of the primary minerals, such as the lamination of hypersthene and the rectangular cleavage of augite. Under pressure-metamorphism hornblende is developed and various types of amphibolite and hornblende-schist are produced. Occasionally rocks rich in pyroxene are found as basic facies of nepheline syenite; a good example is provided by the melanite pyroxenites associated with the borolanite variety found in the Loch Borralan igneous complex of Scotland.

Pyroxenite Uses

  • Countertops, Decorative Aggregates, Interior Decoration, Kitchens
  • As Building Stone, As Facing Stone
  • Curbing
  • As Dimension Stone, Building houses or walls, Cement Manufacture, Construction Aggregate, for Road Aggregate
  • Cemetery Markers, Commemorative Tablets, Laboratory bench tops, Jewelry, Sea Defence, Tombstones

References

  • Bonewitz, R. (2012). Rocks and minerals. 2nd ed. London: DK Publishing.
  • D.G.Pearson.,D.Canil.,S.B.Shirey (2003) Mantle Samples Included in Volcanic Rocks: Xenoliths and Diamonds, Available online 7 June 2004, https://doi.org/10.1016/B0-08-043751-6/02005-3

Marl

Marl or the other name Marlstone is a calcium carbonate non-clastic sedimentary rock. It has containt variable of clays and silt. The dominant carbonate mineral in the most of the marls calcite, aragonite, dolomite and siderite.  Iı belongs to the family of pelitic rocks (clays <0.02 mm, the fine particles in water sales) and a carbonate is a variety of mudstone. The rocks can be both chemical-biogenic and clastic orgin.The carbonate can be washed as detritus, usually to the carbonate skeleton of plankton or biochemically deposited calcite. In order to collect layers of calcite and clay sediments, which have become stronger over time in the seabed and compressed according to the weight of thrusting of younger sediments. In addition, the reaction of the sediment in the pore solution with mineral matter and sediment is gradually transformed into rock. Junk residual marble (also called landscape marble) means limestone and marl (as calcitic overprint mud stones).

Marls are whitish gray or brownish in color but can also be gray, green, red, or variegated. Greensand marls contain the green mineral glauconite, and red marls, iron oxides. Marl is much less easily split than shale and tends to break in blocks. Specimens are often nodular, and the nodules are usually better cemented than the surrounding rock.

Color: Green, brown, beige and gray – grayish white

Grain size: Very fine-grained

Texture: Conchoidal fracture

Minerals Composition: Calcite, Clay, Dolomite, Gypsum, Micas, Pyrite, Quartz

Marl Formation

It is a rock containing clay and calcium carbonate. It is formed from the erosion of other rocks during weathering; as rocks erode, small sedimentary particles–sand, silt, and clay–pile up on top of each other. Eventually, these sedimentary particles become compacted together to form a new rock. The type of new rock that is formed depends on the original rock that was eroded and on the nature of the erosion. If the new rock contains predominantly clay and calcium carbonate, it is called marl.

The most common use for marl is as a fertilizer for soils that are deficient in calcium carbonate (lime).

Where is Marl Located

Marl as lacustrine sediment is common in post-glacial lake-bed sediments, often found underlying peat bogs. It has been used as a soil conditioner and acid soil neutralizing agent.

Marl Uses

  • Decorative Aggregates, Floor Tiles
  • As Building Stone, Roof Tiles
  • Curbing
  • Cement Manufacture, Construction Aggregate, for Road Aggregate, Making natural cement, Raw material for the manufacture of mortar
  • Artifacts, Jewellery, Sculpture, Small Figurines
  • Creating Artwork, Soil Conditioner

References

Bonewitz, R. (2012). Rocks and minerals. 2nd ed. London: DK Publishing.

Chalk

Chalk is a soft, white, porous, sedimentary rock composed primarily of the mineral calcite (calcium carbonate). It is often associated with marine environments and is characterized by its distinctive white color and powdery texture. Chalk has been used for various purposes throughout history, including as a writing surface, a construction material, and in agriculture.

Chalk rock, often referred to simply as chalk, is a specific type of sedimentary rock that is primarily composed of the remains of microscopic marine organisms known as coccolithophores. These organisms secrete calcium carbonate shells or plates, and when they die, their remains accumulate on the ocean floor. Over time, these accumulated remains can form thick layers of chalk rock. Chalk is distinguishable from other types of limestone by its very fine-grained texture and its distinctive white color. Chalk rock is generally soft and friable, making it easy to crumble into a powdery substance.

Significance of Chalk Rock: Chalk rock holds several significant aspects:

  1. Educational Use: Chalk has a long history as a writing and drawing tool, particularly on chalkboards. Teachers and educators have used chalk for centuries to convey information and instruct students, making it an important part of classroom settings.
  2. Geological History: Chalk rock provides valuable insights into Earth’s geological history. The layers of chalk contain a record of past environments and the evolution of marine life, helping scientists and geologists understand the Earth’s past climate and ecosystem changes.
  3. Agricultural Use: Chalk is sometimes used in agriculture to amend soil acidity. It can be applied to soil to neutralize acidity, improve soil structure, and provide essential calcium to plants, promoting healthy crop growth.
  4. Construction and Industry: Chalk has been used as a construction material in the past, especially in areas where it is abundant. While it is relatively soft and porous, it can be used in certain construction applications. Chalk-based materials have also found use in some industrial processes.
  5. Cultural and Historical Significance: Chalk has cultural and historical significance in various regions, often associated with traditional crafts, artwork, and historical writing instruments.
  6. Coastal Landforms: Coastal regions with chalk cliffs and formations, like the White Cliffs of Dover in the United Kingdom, are famous for their striking visual appeal. Chalk cliffs also play a role in coastal erosion and the formation of distinctive landscapes.

Overall, chalk rock is a notable geological formation with diverse uses and significance, ranging from education to agriculture, geology, culture, and industry. Its unique properties and historical relevance make it a valuable resource and subject of study.

Origin: Biochemical

Texture: Nonclastic; Fine-grained

Miscellaneous: Massive, Earthy; Reacts with HCl; Hardness < Glass

Depositional Environment: Deep Marine

Formation and Composition of Chalk Rock

Upper Cretaceous deposits of pure and bright white sedimentary chalk along the coast of central southern Cyprus.

Chalk rock is a distinctive type of sedimentary rock that forms through a specific process and is primarily composed of the mineral calcite (calcium carbonate). Here’s a breakdown of its formation and composition:

Formation of Chalk Rock:

  1. Marine Origin: Chalk rock is primarily associated with marine environments. It forms in areas where there is an abundance of microscopic marine organisms, particularly coccolithophores.
  2. Accumulation of Microscopic Organisms: The key process behind chalk rock formation involves the gradual accumulation of the remains of coccolithophores. These are tiny, single-celled algae that secrete calcium carbonate plates, known as coccoliths, around their cell membranes. These coccoliths are extremely small, usually less than 1/100th of a millimeter in size.
  3. Sedimentation: As these coccolithophores live and die, their coccoliths sink to the ocean floor. Over time, these accumulated remains build up in thick layers.
  4. Compaction and Cementation: As more and more layers of coccolith-rich sediments accumulate, they undergo compaction due to the weight of overlying sediments. Additionally, the calcium carbonate in the coccoliths can dissolve and recrystallize, acting as a natural cement that binds the sediments together.
  5. Lithification: The compaction and cementation processes eventually lead to the lithification of these sediments, turning them into solid rock. This is how chalk rock is formed.

Composition of Chalk Rock: Chalk rock is primarily composed of calcium carbonate (CaCO3), in the form of calcite. The primary components of chalk rock include:

  1. Coccoliths: Chalk rock is made up predominantly of the microscopic calcium carbonate plates, or coccoliths, of coccolithophores. These tiny structures are what give chalk its characteristic white color and fine-grained texture.
  2. Calcite Matrix: In addition to the coccoliths, chalk rock often contains a calcite matrix that binds the coccoliths together. This matrix forms as the calcium carbonate from the coccoliths dissolves and recrystallizes between the coccoliths, creating a cohesive rock.
  3. Minor Impurities: Chalk may contain minor impurities, such as clay minerals, silica, and organic matter, but these are typically present in small quantities compared to the dominant calcite content.

The high calcium carbonate content and fine-grained texture of chalk make it soft and relatively porous compared to many other types of sedimentary rocks. It is also characterized by its white or light gray color, and its soft nature allows it to be easily scratched or crumbled into a powder, making it distinct from other types of limestone and sedimentary rocks.

Chalk Classification

Chalk is a type of sedimentary rock primarily composed of calcium carbonate (calcite) and formed from the accumulation of microscopic marine organisms’ remains, primarily coccolithophores. While chalk is a distinct type of sedimentary rock, it can be classified in various ways based on different criteria:

  1. Chemical Classification:
    • Calcium Carbonate: Chalk is primarily composed of calcium carbonate (CaCO3). This chemical composition distinguishes it from other types of sedimentary rocks.
  2. Texture Classification:
    • Fine-Grained: Chalk rock is known for its extremely fine-grained texture, which gives it a smooth, powdery feel. This texture is a defining characteristic of chalk.
  3. Color Classification:
    • White Chalk: Chalk is typically white or very pale gray in color. This color is due to the high purity of calcium carbonate and the absence of significant impurities.
  4. Mineralogical Classification:
    • Calcite-Dominant: Chalk is predominantly composed of the mineral calcite. While other minerals may be present in trace amounts, calcite is the dominant mineral.
  5. Sedimentary Rock Classification:
    • Biogenic Sedimentary Rock: Chalk is classified as a biogenic sedimentary rock because it is formed from the remains of living organisms (coccolithophores). It falls under the broader category of chemical sedimentary rocks.
  6. Geological Age Classification:
    • Cretaceous Chalk: Some chalk deposits are specific to the Cretaceous period, and they are often referred to as Cretaceous chalk. The famous White Cliffs of Dover in England are examples of Cretaceous chalk.
  7. Geographical Classification:
    • Chalk can also be classified based on its geographical location or region of origin. Different regions may have variations in the chalk’s composition, color, and specific geological history.
  8. Historical Classification:
    • Chalk can be classified historically based on its various uses throughout time, such as classroom chalk, artist’s chalk, or geological chalk used for scientific research.

It’s important to note that while chalk has these various classification criteria, it remains distinct due to its unique combination of characteristics, including its fine texture, white color, and the specific process of formation from coccolithophore remains. Chalk’s classification can vary depending on the context in which it is being described, such as in geology, education, or industry.

Chalk Characteristics and Properties

Chalk has several distinctive characteristics and properties that make it unique among sedimentary rocks. These properties are a result of its composition and the specific processes involved in its formation. Here are the key characteristics and properties of chalk:

  1. Color: Chalk is known for its white or very pale gray color. This is a defining characteristic and is due to its high calcium carbonate content and the absence of significant impurities.
  2. Texture: Chalk has an extremely fine-grained texture, making it feel smooth and somewhat powdery to the touch. This fine texture allows it to be easily scratched or crumbled into a powder.
  3. Composition: Chalk is primarily composed of calcium carbonate (CaCO3), with the mineral calcite being the dominant form. The calcium carbonate in chalk is derived from the remains of microscopic marine organisms called coccolithophores.
  4. Porosity: Chalk is relatively porous, meaning it contains numerous small pores and voids within its structure. This porosity can vary but is generally higher compared to many other sedimentary rocks.
  5. Friability: Chalk is quite friable, meaning it is easily broken or crumbled. Its soft and brittle nature makes it less durable than harder rocks.
  6. Formation from Microorganisms: Chalk is formed through the accumulation of the microscopic remains of coccolithophores. These marine organisms secrete calcium carbonate plates, which settle to the ocean floor and eventually become compacted and lithified to form chalk rock.
  7. Low Compaction and Hardness: Chalk has a low degree of compaction, which contributes to its softness and low hardness. It can be easily scratched with a fingernail or a knife.
  8. Lithification: Over time, the accumulated remains of coccolithophores undergo compaction and cementation, turning them into solid rock. This process is known as lithification.
  9. Chemical Reactivity: Chalk is chemically reactive and can effervesce (fizz) when it comes into contact with acids due to its high calcium carbonate content. This property is often used to identify and distinguish chalk from other rocks.
  10. Historical and Cultural Significance: Chalk has been historically used as a writing and drawing tool, particularly on chalkboards. It has also been employed in art and has cultural significance in various regions.
  11. Versatile Uses: Chalk has been used in a range of applications, from education to agriculture (as a soil conditioner), geology (for stratigraphy studies), and industry (in various processes).
  12. Coastal Features: Chalk formations in coastal regions often create visually striking landscapes, such as cliffs and sea stacks. The White Cliffs of Dover in England are an iconic example of this.

Chalk’s unique combination of characteristics, including its color, texture, composition, and historical uses, makes it a distinct and valuable rock type with significance in various fields, from geology and education to culture and industry.

Distribution and Occurrence

Monument Rock, Large Chalk Formation

Chalk rock is primarily associated with marine environments and is found in various regions around the world. Its distribution and occurrence are influenced by the geological history of the Earth and the presence of specific conditions required for its formation. Here are some key points regarding the distribution and occurrence of chalk:

  1. Geographical Distribution:
    • Chalk deposits can be found on every continent, although they are more prevalent in certain regions, especially in areas with a history of marine sedimentation.
  2. Europe:
    • Chalk is famously associated with Europe, particularly the southeastern coast of England, where the iconic White Cliffs of Dover are composed of Cretaceous chalk. Chalk deposits can also be found in other parts of the United Kingdom, France, and parts of Scandinavia.
  3. North America:
    • Chalk is present in various parts of North America, with notable occurrences in the central and southern United States. In the United States, states like Texas, Kansas, and Nebraska have chalk formations.
  4. Australia:
    • Australia has chalk deposits in certain regions, such as South Australia and Western Australia.
  5. Africa:
    • Chalk can be found in some regions of Africa, including Morocco and Egypt.
  6. Asia:
    • Chalk is less common in Asia but can be found in countries like Turkey and the Middle East.
  7. South America:
    • Chalk deposits are less widespread in South America, but they are known to exist in parts of Argentina and Brazil.
  8. Other Regions:
    • Chalk deposits can also be found in smaller quantities in various other locations worldwide.
  9. Geological History:
    • Chalk is often associated with the Cretaceous period, and many chalk deposits date back to this era. However, chalk formations can span a broader geological range, depending on the region.
  10. Marine Environments:
  • Chalk primarily forms in marine environments, especially in areas where conditions are conducive to the growth of coccolithophores. These conditions typically include clear, well-oxygenated, and nutrient-rich waters.
  1. Fossil Content:
  • Chalk often contains a rich fossil record of the microscopic coccolithophores, which provides valuable insights into past marine ecosystems and environmental conditions.
  1. Coastal Features:
  • Chalk formations, particularly chalk cliffs, can create distinctive coastal features and are known for their striking appearance.

It’s important to note that chalk’s distribution is not uniform, and its occurrence can vary significantly from one region to another. Chalk is often associated with specific geological formations and time periods, and its presence in an area is influenced by the complex interplay of geological, environmental, and historical factors. Scientists and geologists study these chalk deposits to gain insights into Earth’s history and past marine environments.

Uses of Chalk Rock

Chalk rock has a variety of practical and historical uses across different fields and industries. Its unique properties, including its softness, chemical composition, and white color, make it suitable for numerous applications. Here are some common uses of chalk rock:

  1. Writing and Drawing: Historically, chalk has been widely used as a writing and drawing tool. Chalkboards, or blackboards, were once common in classrooms, and teachers used chalk to write and draw. Chalkboards are still used in some educational settings today.
  2. Art: Chalk is used as a medium in art and drawing. Artists use chalk pastels, which are sticks of compressed chalk, to create colorful and textured artworks.
  3. Education: Chalk is essential for teaching and demonstrating concepts in classrooms, particularly in mathematics, science, and other subjects. It provides a visible and erasable medium for educators.
  4. Gymnastics and Climbing: Chalk is used in gymnastics and rock climbing to improve grip and reduce hand sweat. Athletes and climbers apply chalk to their hands to enhance friction and prevent slipping.
  5. Agriculture: Chalk can be ground into a fine powder and used as agricultural lime or agricultural chalk. It is added to soil to reduce acidity and increase pH levels, making the soil more suitable for plant growth. Chalk also provides essential calcium to plants.
  6. Construction: While not as common as other construction materials, chalk has been used in construction, particularly in regions where it is abundant. It may be used in the construction of walls, buildings, and mortar.
  7. Geology and Research: Chalk is a valuable resource for geologists and researchers. It contains a record of past marine environments and can be studied to understand the Earth’s geological history, climate change, and the evolution of marine life.
  8. Industry: Chalk is used in various industrial processes. It can be employed in the manufacture of materials like rubber, plastics, and ceramics. It can also serve as a filler or extender in paint and coatings.
  9. Cultural and Traditional Practices: In some cultures, chalk is used for traditional practices, rituals, or ceremonies.
  10. Coastal Erosion and Landmarks: Coastal regions with chalk cliffs and formations, like the White Cliffs of Dover in the United Kingdom, are renowned for their striking visual appeal. Chalk formations contribute to the formation of coastal landmarks and features.
  11. Archaeology: Chalk has been used as a material for ancient carvings and inscriptions, contributing to archaeological discoveries and the preservation of historical records.
  12. Medicine: In the past, chalk was used for medicinal purposes, particularly as an antacid due to its high calcium carbonate content. However, modern antacids have largely replaced it in this role.

Chalk’s applications span a wide range of fields, from education to agriculture, art, sports, geology, and industry. Its softness, erasability, and unique properties have made it a valuable and versatile material throughout history.

Summary of Key Points

  • Chalk is a sedimentary rock primarily composed of calcium carbonate (calcite).
  • It is formed from the accumulation of microscopic marine organisms’ remains, especially coccolithophores.
  • Chalk is known for its distinctive white color, fine-grained texture, and softness.
  • It is commonly associated with marine environments.
  • Chalk forms as the remains of coccolithophores settle and accumulate on the ocean floor.
  • Over time, compaction and cementation transform these sediments into solid rock.
  • Chalk consists mainly of calcium carbonate, primarily as the mineral calcite, with some minor impurities.
  • Chalk has been used for various purposes, including writing and drawing, education, agriculture, and art.
  • It has historical, cultural, and geological significance.
  • Chalk deposits offer insights into Earth’s geological history and past marine environments.
  • Chalk can be classified based on various criteria, such as its chemical composition, texture, color, and historical uses.
  • It is categorized as a biogenic sedimentary rock, as it forms from the remains of living organisms.
  • Chalk is white or pale gray, fine-grained, and soft, with a powdery texture.
  • It has a high calcium carbonate content, is chemically reactive, and can effervesce in contact with acids.
  • Chalk is historically used in education and art, and its softness makes it ideal for rock climbing and gymnastics.
  • Chalk deposits can be found on every continent, with notable occurrences in Europe, North America, Australia, and other regions.
  • Chalk forms in marine environments, especially in areas with clear, well-oxygenated, nutrient-rich waters.
  • Chalk is used in writing, drawing, education, and art.
  • It serves as a soil conditioner in agriculture and has applications in construction and industry.
  • Chalk is valuable for geological research, as it contains a record of past marine environments.
  • Coastal regions with chalk cliffs create distinctive landscapes, and chalk formations have cultural and historical significance.

References

  • Bonewitz, R. (2012). Rocks and minerals. 2nd ed. London: DK Publishing.
  • Wikipedia contributors. (2019, April 12). Chalk. In Wikipedia, The Free Encyclopedia. Retrieved 20:32, May 9, 2019, from https://en.wikipedia.org/w/index.php?title=Chalk&oldid=892176455

Siltstone

Siltstone is a clastic sedimentary rock that formed from grains whose sized between that of sandstone and mudstone. It can found different environmental conditions different color and textures. Siltstone generally are red and gray color with flat bedding planes. Darker colored siltstone have plant fossils and other carbon-rich matter. It is hard and durable and do not easily split into thin particles or layer. Although often mistaken as a shale, siltstone lacks the fissility and laminations which are typical of shale. Siltstones may contain concretions. Unless the siltstone is fairly shaly, stratification is likely to be obscure and it tends to weather at oblique angles unrelated to bedding. Mudstone or shale are rocks that contain mud, which is material that has a range of silt and clay. Siltstone is differentiated by having a majority silt, not clay.

Origin: Detrital/Clastic

Texture: Clastic; Fine-grained (0.004 – 0.06 mm)

Composition: Quartz, clay minerals

Color: Reddish brown

Miscellaneous: Massive; Feels slightly gritty

Depositional Environment: Flood plain, Delta, or Mid-continental Shelf

Grain size: Fine- grained

Siltstone Composition

Clastic sedimentary rocks are deposited in three ways. They are water glaciers and wind. Identifying siltstone and shale requires distinguishing between silt and clay particles.Silt and clay are both tiny particles that have weathered away from rocks and minerals. Silt is intermediate in size between the larger grains of sand and the smaller clay particles. To be classified as silt, the particles must be smaller than .06 millimeters in diameter, (.002 inches) and larger than clay-size particles, which are smaller than .004 millimeters in diameter (.0002 inches). Clay, unlike silt, also refers to several types of minerals, including montmorillonite and kaolinite

Siltstone Formation

Semi-quiet depositional environments. Coarse silt is capable of forming cross laminations in a current, while the finer-end particles generally deposit from suspension.

Thus, any depositional environment with these conditions may form silt deposits, and they range from river systems, to deltas, to shelves, to submarine fans and basins. In other words, just about anywhere.

Silt is a common component with other deposits, or is interbedded with other deposits. For example, silt beds are common in flood plain deposits above the point bar sands, and they form the TD unit in a Bouma sequence.

Where is It Found?

Siltstone is deposited in a similar environment with shale, but is usually located near the old delta, lake or sea shore, where calm currents cause less particle suspension. Siltstone is generally formed adjacent to sandstone deposits – ie close to beaches and delta edges where sand is deposited. It consists of silt, hence siltstone, sandy beaches and water adjacent to deltas. Declining currents filter sand from smaller silt particles. Siltstone rises to the shale level in deep water; where the suspended clay particles are stored further as the currents continue to lose energy. In both cases, calm water is needed to suspend and separate silt and clay. Thus, sandstone, siltstone and shale are interrelated rocks which are distinguished by particle size.

Siltstone Characteristics and Properties

  • Generally uniform, moderately consolidated to semi-lithified, silty sediment.
  • Typically blue-grey to olive green and brown; fracture surfaces are stained orangebrown to black.
  • Local intervals of colluvium.
  • No macroscopic shell, plant or fossil material.
  • Little or no evidence of bedding or other sedimentary structures.
  • Found beneath the coarse alluvium/colluvium sequence and above ‘basement’ lithologies such as granite, rhyolite and metasedimentary rocks.

Siltstone Uses

  • It is rarely mining for use as a construction material or manufacturing feedstock.
  • The pore spaces of siltstone serve as good aquifer. It is rarely porous enough or extensive enough to serve as an oil or gas reservoir.
  • Its main use is as a low-quality fill when better materials are not locally available.

Shale, Siltstone, and Mudstone

Resistance to weathering: Shale, siltstone, and mudstone units are valley formers, producing gentle slopes and subdued landforms, including broad “V”-shaped gullies having long, gentle stream gradients.

Drainage: Shale, siltstone, and mudstone units have relatively low permeability, resulting in significant surface flow. This produces a high drainage density. The low permeability of shale and clay keeps water in the vicinity of plant roots, so, in general, shale and clay will support dense vegetation. This often obscures the surface of shale and further lowers the reflectance.

Color: Shale is commonly dark because of the lithic content, dark clay minerals, and carbonaceous matter, which is frequently a constituent of shale. The dark color of shale is usually indicative of marine origin. Marine shale dominates in frequency, areal distribution, and thickness. Fluvial and lacustrine shale have higher reflectances and often contain more silt. Siltstone, an abundant sedimentary rock type that is probably more prevalent on the landscape than shale, is often misidentified and labeled as shale by engineers. The mechanical properties of siltstone make siltstone an important class from an engineering/rock strength standpoint as well.

Structure: Shale can form thick, dense deposits, but shale response to tectonic forces is quite different from sandstone. Shale responds to deformation by forming numerous lenticular shear planes having separations measured in millimeters to centimeters. Hence, shale tends to be weak, requiring support for bearing loads. In addition, depending upon the type of clay minerals present, shale may present shrink/swell problems (smectite and chlorite minerals), or squeeze/deformation problems (kaolinite and chlorite minerals).

Siltstone Key Point

  • Silt does not have a precise composition. It usually has a mix of micas, feldspar, quartz and clay minerals. The small part of the silt is mostly clay. The rough size fraction is mostly quartz and feldspar grains.
  • It is mudstone and shale, mud-containing, clay and silt. Siltstone is different because it is mostly clay and not clayy.
  • Silt stone is much less common than shale and sandstone. Rocks are generally thinner and less common.
  • Silt accumulates in sedimentary basins all over the world. A current between the sludge and the place where the sand is deposited represents the level of wind or wave energy. These include aeolian, fluvial, tidal, lakrin, coastal, glacier, paludal, deltaic and shelf environments. Sedimentary structures such as stratification, fluctuation traces, erosion, cross bed and fossils provide evidence of these environments.
  • Silt-sized particles range from 0.00015 to 0.0025 inches in diameter or in the range of 0.0039 to 0.063 millimeters in diameter. They are of medium size between the coarse clay on the small sides and the fine sand on the large side.
  • Coarse silt grains are large enough for most people to see without using a magnifying glass.
  • It can be difficult to identify without close inspection and requires a small piece to be broken to observe grain size. Scratch the surface with a knife blade or a nail, instead of changing the grains of sand, small silt grains emerge.
  • Although this test is not recommended, it is known that experienced geologists and soil scientists can detect a few female silt fragments by gently inserting them between their front teeth.
  • Siltstone has little use. If used for building, it is only due to availability, not quality. When there are no better local materials, the main use is a low quality filler.

References

  • Bonewitz, R. (2012). Rocks and minerals. 2nd ed. London: DK Publishing.
  • Wikipedia contributors. (2019, March 20). Siltstone. In Wikipedia, The Free Encyclopedia. Retrieved 17:04, May 9, 2019, from https://en.wikipedia.org/w/index.php?title=Siltstone&oldid=888677754

Oil Shale

Oil Shale is organic-rich sedimentary rocks that have contain kerogen (insoluble organic matter in sedimentary rock. When subjected to intense heat, these shales yield oil. Oil shales range from brown to black in color. They are flammable and burn with a sooty flame. Some oil shales are true shales in which clay minerals are predominant. Others are actually limestones and dolomites. Much of the original organic material in oil shales is unrecognizable, but it is believed to be derived from plankton, algae, and microorganisms that live in fresh sediment. In previous centuries, small amounts of oil have been successfully recovered from oil shales. During the past century, oil shales have been mined with rock types varying from shale to marl and other carbonate rocks. Various pilot plants have been built to extract oil from shales, but the commercial results have been modest so far.

Oil Shale Classification

Classification are generally classified by their mineral content and depositional history. Depositional history of a sedimentary rocks is type of enbironment in which rock developed.The depositional history of an oil shale includes the organisms and sediments that were deposited, as well as how those deposits interacted with pressure and heat.

The van Krevelen Diagram

The van Krevelen Diagram is a method of classifying oil shales based on their depositional history. The diagram divides oil shales according to where they were deposited: in lakes (lacustrine), in the ocean (marine), or on land (terrestrial).  

Oil shales from lacustrine environments formed mostly from algae living in freshwater, saltwater, or brackish water. Lamosite and torbanite are types of oil shales associated with lacustrine environments. Lamosite deposits make up some of the largest oil shale formations in the world. Torbanite deposits are found mainly in Scotland, Australia, Canada, and South Africa.

 Oil shales from marine environments formed mostly from deposits of algae and plankton. Kukersite, tasmanite, and marinite are types of marine shales. Kukersite is found in the Baltic Oil Shale Basin in Estonia and Russia. Tasmanite is named after the region in which it was discovered, the island of Tasmania, Australia. Marinite, the most abundant of all oil shales, is found in environments that once held wide, shallow seas. Although marinite is abundant, it is often a thin layer and not economically practical to extract. The largest marinite deposits in the world are in the United States, stretching from the states of Indiana and Ohio through Kentucky and Tennessee.

 Oil shales from terrestrial environments formed in shallow bogs and swamps with low amounts of oxygen. The deposits were mostly the waxy or corky stems of hardy plants. Cannel shale, also called cannel coal or “candle coal,” is probably the most familiar type of terrestrial oil shale. Cannel coal was used primarily as fuel for streetlights and other illumination in the 19th century.

Classifying Oil Shales by Mineral Content

Thye are classified in three main types based on their mineral content: carbonate-rich shale, siliceous shale, and cannel shale.

 Carbonate-rich shale deposits have high amounts of carbonate minerals. Carbonate minerals are made of various forms of the carbonate ion (a unique compound of carbon and oxygen). Calcite, for instance, is a carbonate mineral common in carbonate-rich shales. Calcite is a primary component of many marine organisms. Calcite helps form the shells and hard exteriors of oysters, sea stars, and sand dollars. Plankton, red algae, and sponges are also important sources of calcite.

 Siliceous shale is rich in the mineral silica, or silicon dioxide. Siliceous shale formed from organisms such as algae, sponges, and microoganisms called radiolarians. Algae have a cell wall made of silica, while sponges and radiolarians have skeletons or spicules made of silica. Siliceous oil shale is sometimes not as hard as carbonate-rich shale, and can more easily be mined.

 Cannel shale has terrestrial origins, and is often classified as coal. It is made up from the remains of resin, spores, and corky materials from woody plants. It can contain the minerals inertinite and vitrinite. Cannel shale is rich in hydrogen, and burns easily.

Oil Shale Composition

The composition of oil shale may vary according to the depositional mechanism and setting. The composition of the original organic matter may impact the chemical composition of the embedded kerogen.

Quality Factors

The quality of oil shale is important in determining its suitability for production. Some of the important determinants of quality include:

  • Richness/Grade (litres per ton l/t))
  • Organic material content (as a percentage of weight)
  • Hydrogen content,
  • Moisture content, and
  • Concentrations of contaminants including:
  • Nitrogen and
  • Sulfur and metals.

Richness/Grade

The commercial desirability of any oil shale deposit is dependent on the richness of the shale. Commercially attractive grades of oil shale contain 100 l/t or more. There are some deposits of oil shale that contain 300 l/t (4). The richness may in fact result in greater yields than determined by Fischer Assay due to efficiencies in processing. Oilshales vary considerably in terms of richness or grade, which is determined by the percentage of organic carbon in the ore. Yield is an expression of the volume of shale oil that can be extracted from the oil shale. Richness of oil shale may be assessed by methodologies including Fischer Assay which is the traditional method but may not provide the total potential volume of oil that can be produced from the shale. A newer method, known as Rock-Evaluation, may provide a better measure of true potential yield (5).

Recoverability

The volume of oil shale is often expressed as the oil shale in place. This is an estimate of the total volume of oil shale contained in the ore taking into account the quality of the resource. Some deposits also have estimates of the recoverable resource which takes into consideration additional factors to determine the volume ofshale that may actually be extracted from the ore. There is variation in the degree that individual deposits around the world have been evaluated or characterized; thus, the volume of shale oil is not fully known.

Oil Shale Formation

Oil shale is formed from organic material which may have several different origins. It is often categorized according to the origin of the organic material into three major categories: terrestrial, lacustrine, and marine (2).

  • Terrestrial oil shale is formed from organic material, plant and animal matter that once lived on land, similar to the material that produces coal.
  • Lacustrine oil shale descends from fresh or brackish water algae remains.
  •  Marine oil shale deposits are the result of salt water algae, acritarchs, and dinoflagellates.

The origin of the oil shale may impact its quality and/or the other minerals that are found within the deposit

Distribution

Deposits of oil shale may be found at varying depths below the surface. Oil shale occurs in nearly 100 major deposits in 27 countries worldwide (3). It is generally found atshallow depths of lessthan 900 meters, whereas deeper, warmer geologic zones are required to form conventional oil. Some deposits are close to the surface in relatively thin beds of shale. Other deposits may be found deeper beneath the surface (greater than 300 meters) in very thick beds (300 meters or more in thickness).

Characteristics and Properties

Thye are found in different host rock types, but most deposits are either carbonate or silica based. The type of rock that comprises the shale body affects the mining and heating approaches, moisture content, and air and carbon emissions released during processing. Silica and clay based oil shales tend to have higher moisture contents. Carbonate rock may crumble in mining, crushing, and handling creating small particles called fines. Fines require different retorting approaches than lump shale. Fines can also contaminate shale oil with particulates that are difficult to remove. Carbonate rock also decomposes when subjected to high temperatures causing the creation and release of carbon dioxide emissions.

World Oil Shale Resources

World oil shale resources are characterized to varying degrees. The largest resource, the United States deposits, contain approximately 75 percent of the world’s oil shale resources and a great deal is known about the quality and extent of these resources. However, there are many deposits around the world in which little is known about the quality and extent of the resource.

Oil Shale Uses

People have been using oil shale for thousands of years. Ancient Mesopotamians used shale oil to pave roads and caulk ships. Ancient Mongolians dipped the tips of their arrows in shale oil during battles, sending flaming arrows at their enemies. In the Middle East, sticky shale oil was even a component of decorative mosaics.

 The modern shale industry began in the 19th century. This industry used industrial processes to heat shale in order to extract oil. Shale oil was used for a variety of products, including paraffin wax.

 European countries, and later the United States, began extracting oil shale and shale oil and burning them as sources of fuel. The first U.S. shale mining facilities were established in the Ohio River Valley in the states of Pennsylvania, Ohio, West Virginia, and Kentucky.

 Extracting and processing shale oil is an expensive and difficult process. Coal, petroleum, and natural gas are less expensive to extract. Australia, Brazil, Switzerland, Sweden, Spain, and South Africa began mining oil shale in the 19th and 20th centuries, but they all stopped production by the 1960s. The U.S. ceased production in the early 1980s.

 Many nations, including Estonia, China, and Brazil, continue to rely on oil shale for fuel. It is burned to generate electricity, is a component in chemical industries, and byproducts are used in cement production.

References

  • Bonewitz, R. (2012). Rocks and minerals. 2nd ed. London: DK Publishing.
  • Knaus, E., Killen, J., Biglarbigi, K., & Crawford, P. (2010). An overview of oil shale resources. In ACS symposium series (Vol. 1032, pp. 3-20). Oxford University Press.
  • Society, N. (2019). oil shale. [online] National Geographic Society. Available at: https://www.nationalgeographic.org/encyclopedia/oil-shale/ [Accessed 9 May 2019].

Shale

Shale is a laminated or fissile clastic sedimentary rock that composed of predominance of silt and clay other minerals , especially quartz and calcite. Characteristic properties of shale is breaks along thin laminae or parallel layering or bedding called fissility. It is most abundant sedimentary rock. The composition (silt and clay) of shale in a category of sedimentary rocks known  as mudstone. Difference between shale to mudstone, It is fissile and laminated seen. Shale rock readily into thin pieces along the laminations.

Origin: Detrital/Clastic

Colour: Black, Grey

Group: Clastic Sedimentary Rock

Texture:     Clastic; Very fine-grained (< 0.004 mm) Silty shale . Clay shale . Sandy shale

Mineralogical Composition: Feldspathic Shale, Quartzose Shale, Micaceous Shale

Minerals: Clay minerals, Quartz

Cementing Materials. Calcareous shale . Ferruginous shale. Siliceous shale

Depositional Environment Flood Plain, Lake (away from shore), Mid-continental Shelf, Delta, Tidal Flat, Lagoon, or Deep Marine

Shale Classification

Shales are fissile clastic sedimentary rocks formed from transportation, deposition and compaction of detrital materials of silt and clay. Fissility of the clay is its main distinguishing characteristic from other sedimentary rocks. Fissility is defined as the property of a rock to split easily along thin closely spaced (< 10mm approximately) parallel layers. This fissility factor is highlighted in that shows classification of sediments and sedimentary rocks based on sizes of fragments.

Classification based on texture

Shales characteristically contain fine-grained silt and clay particles (< 0.063mm). They are therefore classified as silty shale or clay shale, depending on whether silts or clays dominate in the constituents of the rock. Silty shale and clay shale may collectively be called argillaceous shales. Occasionally, shales may also contain appreciable amounts of sands, in which case they may be called sandy shale or arenaceous shale.

 Classification based on mineralogical composition

Shales may be classified as quartzose, feldspathic or micaceous shale depending on the predominance of the minerals quartz, feldspar or mica, respectively, in the rock after appropriate XRD analysis (Pettijohn, 1957).

 Classification based on type of cementation/cementing materials.

Shales like other sedimentary rocks are cemented by some minerals or elements after deposition and compaction. The dominant type of cementing material may be used in the classification of the shale since this may affect the properties or performance of the shale when used as an engineering material. The common cementing materials are silica, iron oxide and calcite or lime. Accordingly, shales may be classified as siliceous, ferruginous or calcareous (sometimes also called limy), respectively.

Classification based on depositional environment

 The sedimentary environment of any sedimentary rock (including shale) is a natural geographical entity in which sediments are accumulated and later changed to rock (Reineck and Singh, 1980). Three depositional sedimentary environments are recognized, namely, continental, transitional or marginal and marine. Each depositional environment has various subdivisions. Shales are generally deposited in lacustrine (continental), deltaic (transitional) and marine depositional environments and may correspondingly be classified as such; that is, lacustrine, deltaic and marine shales (Compton, 1977; Boggs, 1995). Lacustrine deposits are characterized by mixture of clay, silt and sands; inorganic carbonate precipitates; and various fresh water invertebrate organisms including bivalves, ostracods, gastropods, diatoms and various plant deposits. Most lake deposits are less than 10m thick. Deltaic deposits are generally paralic (consisting of orderly sequences of shales and sandstones formed as a result of alternating marine transgressions and regressions). They are also characterized by shallow depth and concentration of kaolinite/illite/montmorillonite clay minerals. Deposits of marine environment are characterized by homogenous rock sequences (nonparalic), great depth, oxygen deficiency, and concentration of illite/montmorillonite clay minerals. Shales of marine depositional environment are generally darker in colour and richer in marine planktonic fossils than shales deposited in lacustrine and deltaic environments.

Classification based on organic matter content

Shales may be classified as carbonaceous or bituminous on the basis of their organic matter content (Krumbein and Sloss, 1963). The organic matter content of carbonaceous and bituminous shales are generally above 10%. The organic matter induces black or grey colour to the shales. The black colour of some shales may also be due to presence of iron sulphide. When the dominant organic matter content is from plant fragments such as pollen grains, stems and leaves, the shale is classified as carbonaceous, and the depositional environment is usually continental (lacustrine) or transitional (deltaic or lagoon). When the dominant organic matter content in the shale is from animal fragments such as fossils, the shale is classified as bituminous and its depositional environment is usually deltaic or marine. Both carbonaceous and bituminous shales are important source rocks for generation of petroleum oil and gas depending on their amount / type of kerogen content. Kerogen is that Mud Shale when laminated

Shale Composition

Shales are composed of silt, clay minerals and quartz grains. Generally typically crey color. In some cases the color of the rock is different. A minor constituents alters the color of the rock. Black shale result presenced of greater than one percent carbonaceous material and indicates a reducing environment.Red, brown and green colors are indicative of ferric oxide (hematite – reds), iron hydroxide (goethite – browns and limonite – yellow), or micaceous minerals (chlorite, biotite and illite – greens).

Clay Minerals are major component of shale and other similar rocks. The clay minerals represented are mostly kaolinite, montmorillonite and illite. Clay minerals of Late Tertiary mudstones are expandable smectites whereas in older rocks especially in mid- to early Paleozoic shales illites predominate. The transformation of smectite to illite produces silica, sodium, calcium, magnesium, iron and water. These released elements form authigenic quartz, chert, calcite, dolomite, ankerite, hematite and albite, all trace to minor (except quartz) minerals found in shales and other mudrocks

Organic matter

Very important component carbonaceous material in the shale rocks. This is the organic material that usually occurring in the rocks as kerogen  (a mixture of organic compounds with high molecular weight). Although kerogen does not form more than about 1% of all the shales, the vast majority of kerogen is in mudstones. Shales that are rich in organic matter (>5%) are known as black shales. Black color is given to these rocks by organic matter. Organic matter should be decomposed in normal conditions by bacteria, but high productivity, rapid deposition and burial or lack of oxygen may preserve it. Pyrite is a common sulfide mineral in black shales. Organic matter and pyrite occur together in the same rock because both need oxygen-free conditions for their formation.

Some shales especially rich in organic matter.  This type rock name is Oil Shale. Oil shale may be used as a fossil fuel, although it is relatively “dirty” fuel because it usually contains lots of unwanted (not burning) minerals.

Shales and mudrocks contain roughly 95 percent of the organic matter in all sedimentary rocks. However, this amounts to less than one percent by mass in an average shale. Black shales, which form in anoxic conditions, contain reduced free carbon along with ferrous iron (Fe2+) and sulfur (S2−). Pyrite and amorphous iron sulfide along with carbon produce the black coloration.

Shale Formation

Shale formation is fine partiles that can remain suspended in water long afrer the larger particles of sand have deposited. Shales are typically deposited in very slow moving water and are often found in lakes and lagoonal deposits, in river deltas, on floodplains and offshore from beach sands. They can also be deposited in sedimentary basins and on the continental shelf, in relatively deep, quiet water.

‘Black shales’ are dark, as a result of being especially rich in unoxidized carbon. Common in some Paleozoic and Mesozoic strata, black shales were deposited in anoxic, reducing environments, such as in stagnant water columns. Some black shales contain abundant heavy metals such as molybdenum, uranium, vanadium, and zinc.

Fossils, animal tracks/burrows and even raindrop impact craters are sometimes preserved on shale bedding surfaces. Shales may also contain concretions consisting of pyrite, apatite, or various carbonate minerals.

Shales that are subject to heat and pressure of metamorphism alter into a hard, fissile, metamorphic rock known as slate. With continued increase in metamorphic grade the sequence is phyllite, then schist and finally gneiss.

Diagenesis and hydrocarbons

The process of illitization (smectite is transformed to illite) is a major change that takes place in mudstones during the diagenesis. Illitization consumes potassium (provided usually by detrital K-feldspar) and liberates iron, magnesium and calcium, which can be used by the other forming minerals like chlorite and calcite. The temperature range of illitization is about 50-100°C3. Kaolinite content also decreases with increased burial depth. Kaolinite forms in hot and humid climate. The drier temperate climate tends to favor smectite. The reason is that lots of precipitation washes soluble ions out of the rock, while drier climate does not accomplish this task so effectively. Kaolinite is favored in humid climate because it contains only aluminum in addition to silica and water. Aluminum is highly residual while the constituents of smectite (magnesium and calcium, in addition to aluminum and iron) get carried away more easily.

Another major and economically very important process that takes place during diagenesis (sometimes this stage is referred to as catagenesis) is the maturation of kerogen into hydrocarbons. Kerogen is a waxy substance trapped in the rock, but it will mature into lighter hydrocarbons that are able to move out of the shale and migrate upwards. This process can take place at temperatures between about 50-150°C4 (oil window). This corresponds usually to 2-4 kilometers of burial depth. Lighter hydrocarbons liberated during the processes (known as catalytic and thermal cracking) are now free to migrate upwards. They can form exploitable oil and gas reservoirs if stopped by some sort of structural trap which may be an anticline or a fault boundary. The rock layer that stops the upward movement is in many cases another layer of shale because compacted shale is a tough barrier for liquids and gas. Shale can also form an aquiclude between water-bearing layers for the same reason — it does not allow water to flow easily through the rock (has low permeability).

This is also the reason why some of the formed hydrocarbons are not able to migrate out of the source rocks. This resource is still at least partly available to us if we drill holes and inject pressurized water into the rock which will cause it to fracture. This method is known as hydraulic fracturing (fracking). Cracks formed will be kept open by the sand-grains injected with the water and hydrocarbons trapped in the rocks will become recoverable. Fracturing actually is a common process in the crust. Mineral veins and dikes are cracks in the crust opened and sealed by a highly pressurized fluid or magma.

Importance Of Shales To The Petroleum Industry

According to Okeke (2003), the petroleum industry encompasses exploration, production, transportation, processing and marketing of petroleum oil and gas. The generation and accumulation of petroleum involve three stages, namely, generation in the source rocks, migration through geologic formations and storage in rock reservoirs. Petroleum source rocks are geologic formations that are capable of generating petroleum Coal, mudstone and shale are the recognized source rocks because of their organic carbon contents. These organic contents, depending on their nature, depositional environment, temperature, pressure, and depth of burial are capable of generating petroleum. Generally, petroleum gas is produced in high temperature/pressure, humic and plant dominant organic sediments such as coal while oil is produced from less humic, fossil dominant and moderate temperature/pressure marine shales. The source rocks have very low porosity and permeability, and thus the petroleum once formed is trapped in the rock but may move out due to hydrodynamic pressure conditions into a nearby porous rock from where it continues moving or migrating until it is trapped or stored in a suitable geologic reservoir formation. The petroleum oil or gas trapped in the reservoirs can then be exploited by drilling wells into the reservoirs. Such reservoirs include sandstones, limestones as well as fractured shales. Shales as impermeable rocks are also important seals in stratigraphic and structural traps. Shales are therefore important as source rocks, reservoir, as well as seal rocks. According to Roegiers (1993), about 90% of all formations drilled in the petroleum industry is shales and limestones. It is also known that shales can be problematic in the petroleum industry. Roegiers (1993) has it that about 75% of well drilling/completion problems are related to shale formations. Details of the positive as well as the negative aspects of shale to the petroleum industry are now reviewed.

Shale Characteristics and Properties

Here are different levels of definitions.

  • soft, finely stratified sedimentary rock that formed from consolidated mud or clay and can be split easily into fragile slabs.
  • a fissile rock that is formed by the consolidation of clay, mud, or silt, has a finely stratified or laminated structure, and is composed of minerals essentially unaltered since deposition.
  • a rock of fissile or laminated structure formed by the consolidation of clay or argillaceous material.

None of these have anything to do with so-called “shale” oil & gas production. True shales, as above, are majorly clay minerals which are also defined as a size class (clay sized) and are commonly called gray shales. The hydrocarbon producing reservoirs are less than 50% clay minerals (sometimes much less), do meet the particle size definition and are organic rich. One of the most prolific “shales” in the US is the Woodford formation. It carries a very high level of organics and is typically about 30% clay minerals. The remainder is sand/clastic in most area. Other ‘shales’ are stronger in carbonates than clays.

Shale Uses

  • Shale has many commercial uses. It is a source material in the ceramics industry to make brick, tile, and pottery. Shale used to make pottery and building materials requires little processing besides crushing and mixing with water.
  • Shale is crushed and heated with limestone to make cement for the construction industry. Heating drives off water and breaks limestone into calcium oxide and carbon dioxide. Carbon dioxide is lost as a gas, leaving calcium oxide and clay, which hardens when mixed with water and allowed to dry.
  • The petroleum industry uses fracking to extract oil and natural gas from oil shale. Fracking involves injection of liquid at high pressure into the rock to force out the organic molecules. Typically high temperatures and special solvents are needed to extract the hydrocarbons, leading to waste products that raise concerns about environmental impact.

Key Point

  • Shale is the most common sedimentary rock, which accounts for about 70 percent of the Earth’s crust.
  • Shale is a fine-grained rock made of compressed mud and clay.
  • The defining characteristic of the shales is its fragility. In other words, shale is easily divided into thin layers.
  • Black and gray shales are common, but the rock can appear in any color.
  • Shale is commercially important. It is used in the construction of bricks, ceramics, tiles and Portland cement. Natural devil and oil can be removed from the oil shale.
  • Rock can occur in the playas, rivers, basins and oceans.
  • It is common to find limestone and sandstone lying near shale.
  • Shale usually occurs on the leaves.
  • Roughly 55% of all sedimentary rocks are shale.
  • Some shales are probably high in calcium due to the fossils they contain.
  • Shale with high alumina content is used in cement production.
  • The shale with a high natural gas content has recently been used as an energy source.
  • Quartz and other minerals are typically found in shale.
  • Although the shale is normally gray, it may be black if it contains too much carbon material.
  • Approximately 95% of the organic matter in the sedimentary rock is found in shale or mud.
  • Shale is created by a process called compression.
  • The shale exposed to extreme heat and pressure may vary in slate form.
  • Once formed, the shale is usually released into lakes and rivers with slow-moving water.
  • Clay is an important component in shale rocks.

A brief overview of rock names used to describe mudstones or rocks derived from them:

Muddy rock Description
Shale A laminated and compacted rock. Clay should dominate over silt.
Claystone Like shale but lacks its fine lamination or fissility. Clay should dominate over silt.
Clay rock A synonym of claystone.
Argillite A rather weakly defined rock type. It is a compact and indurated rock buried deeper than most mudrocks and can be considered to be a weakly metamorphosed mudstone. Argillite lacks the slaty cleavage and is not laminated as well as typical shale is.
Mudstone An indurated mud lacking the fine lamination characteristic of shales. Mudstone has roughly equal proportions of clay and silt. “Mudstone” can be treated as a general term that includes all varieties of rocks that are mostly composed of compacted mud.
Siltstone A mudstone in which the silt predominates over clay.
Mudrock A synonym of mudstone.
Lutite A synonym of mudstone although rarely used independently. Usually in combination with some modifier (calcilutite is a very fine-grained limestone).
Pelite Another synonym of mudstone. May be used to describe unconsolidated fine-grained sediments. Is also used to decribe fine-grained carbonates just as lutite.
Marl A calcareous mud. It is a mixture of clay, silt and carbonate grains in various proportions. May be consolidated but in this case it is often named marlstone.
Sarl Similar to marl but contains siliceous biogenic grains instead of carbonate mud.
Smarl A mixture of sarl and smarl.
Black shale Black carbonaceous shale which owes its color to organic matter (>5%). It is rich in sulfide minerals and contains elevated concentrations of several metals (V, U, Ni, Cu).
Oil shale A variety of shale rich in organic matter. It will yield hydrocarbons on distillation.
Alum shale Similar to black shale but pyrite has partly decomposed forming sulfuric acid which reacted with the constituent minerals of the rock to form alum (hydrous potassium-aluminum sulfate). It is rich in several metals just as black shale and has been mined as a source of uranium.
Olistostrome A chaotic mass of mud and larger clasts formed underwater as a gravity-driven mudslide. It lacks bedding.
Turbidite A sediment or a rock deposited by a turbidity current. These deposits form underwater as a mixture of clay, silt and water sliding down the continental slope (in most cases). Turbidite is often composed of alternating silty and clayey layers.
Flysch An old term nowadays largely replaced by turbidite.
Diamictite Purely descriptive term used to describe any sedimentary rock containing larger clasts in a fine-grained matrix. Diamictite may be formed in many ways, but it seems to be a lithified glacial till in the majority of cases.
Tillite A lithified poorly sorted (larger clasts in a muddy matrix) sediment deposited by a glacier. Tillite is a lithified till.
Slate A fine-grained metamorphic rock that can be split into thin sheets (has slaty cleavage). Slate in the vast majority of cases is a metamorphosed shale/mudstone.
Metapelite Any metamorphosed mudstone. Slate, phyllite, and various schists are common metapelites.
Phyllite A metamorphic rock higher in grade than slate and lower than schist. It has a characteristic sheen on the cleavage surfaces given to it by platy mica and/or graphite crystals.

References

  • Bonewitz, R. (2012). Rocks and minerals. 2nd ed. London: DK Publishing.
  • Okeke, O. C., & Okogbue, C. O. (2011). Shales: A review of their classifications, properties and importance to the petroleum industry. Global Journal of Geological Sciences, 9(1), 75-83.
  • Helmenstine, Anne Marie, Ph.D. (2018, October 22). Shale Rock: Geology, Composition, Uses. Retrieved from https://www.thoughtco.com/shale-rock-4165848
  • Wikipedia contributors. (2019, April 26). Shale. In Wikipedia, The Free Encyclopedia. Retrieved 02:01, May 9, 2019, from https://en.wikipedia.org/w/index.php?title=Shale&oldid=894256126

Skarn

Skarn is coarse-grained metamorphic rocks that forms by a metasomatism. Also called tactites. Skarn tend to be rich in calcium-magnesium-iron-manganese-aluminium silicate minerals that also regerred to calc-silicate minerals. Skarn, in geology, metamorphic zone developed in the contact area around igneous rock intrusions when carbonate sedimentary rocks are invaded by large amounts of silicon, aluminum, iron, and magnesium. Many skarns also include ore minerals; several productive deposits of copper or other base metals have been found in and adjacent to skarns. Granitic and dioritic magmas are most commonly associated with skarns. Skarns can form by regional, or contact metamorphism and therefore form in relatively high temperature environments. The hydrothermal fluids associated with the metasomatic processes can originate from either magmatic, metamorphic, meteoric, marine, or even a mix of these.The resulting skarn may consist of a variety of different minerals which are highly dependent on the original composition of both the hydrothermal fluid and the original composition of the protolith.

Name origin: Skarn names came from old Swedish mining term is silicate gangue, or waste rock, associated with iron-ore bearing sulfide deposits

Colour: Black, Brown, Colourless, Green, Grey, White

Grain size: fine or course grains rock

Group: Metamorphic rock

Texture: They are fine, medium or coarse grained.

Alterations: Hydrothermal alteration

Minerals: Mostly garnets and pyroxene with a wide variety of calc-silicate and associated minerals. Skarn minerals is include pyroxene, garnet, idocrase, wollastonite, actinolite, magnetite or hematite,

Economically Important Minerals: Tungsten, manganese, gold, copper, zinc, nickel, lead, molybdenum and iron

Classification of Skarn

Skarns can be divided into sub-sections according to certain criteria:

Skarn can be classified according to its Protolith. If sakarn protolith is sedimentary origin, it can be reffered to as an exoskarn. If the protolith is ignouse rock, it can be called an endoskarn.

Skarn also classification can be made based on the protolith by observing the skarns dominant composition and the resulting alteration assemblage. If the skarn has a Olivine, Serpentine, Phlogopite, magnesium Clinopyroxene, Orthopyroxene, Spinel, Pargasite, and minerals s from the Humite group, are characteristic of a dolomitic protolith and can be classed as a magnesian skarn.

Calcic skarns are  replacement products of a limestone protolith with dominant mineral assemblages containing Garnet, Clinopyroxene, and Wollastonite.

Skarn deposits have typical skarn Gangue minerals but also contain ore minerals in abundance which are of economic importance. Skarn deposits are therefore classified by their dominant economic element, such as copper (Cu) skarn deposit, or molybdenum (Mo) skarn deposit to name a few.

Fe (Cu, Ag, Au) skarn deposits

The tectonic setting for calcic Fe skarns tends to be the oceanic island arcs. The host rocks tend to be gabbros to syenite associated with intruding limestone. The tectonic setting for magnesium Fe skarns tends to be the continental margin. The host rocks tend to be granodiorite to granite associated with intruding dolomite and dolomitic sedimentary rocks. Magnetite is the principal ore in these types of skarn deposits which its grade yields from 40 to 60 %. Chalcopyrite, bornite and pyrite are the minor ores.

Cu (Au, Ag, Mo, W) skarn deposits

The tectonic setting for Cu deposits tends to be the Andean-type plutons intruding older continental-margin carbonate layers. The host rocks tend to be quartz diorite and granodiorite. Pyrite, chalcopyrite and magnetite are typically found in higher abundances.

Types of Skarn Deposits

A descriptive skarn classification can be based on the dominant economic minerals.

1.   Iron Skarns

The largest skarn deposits, with many over 500 milliion tonnes. They are mined for their magnetite. Minor amounts of Ni, Cu, Co and Au may be present, but typically only Fe is recovered. They are dominantly magnetite, with only minor silicate gangue.

2.   Gold Skarns

Most gold skarns are associated with relatively mafic diorite – granodiorite plutons and dyke/sill complexes. Some large Fe or Cu skarns have Au in the distal zones. There is the potential that other skarn types have undiscovered precious metals if the entire system has not been explored.

3.   Tungsten Skarns

These are found in association with calc-alkaline plutons in major orogenic belts. They are associated with coarse grained, equigranular batholiths (with pegmatite and aplite dykes), surrounded by high temperature metamorphic aureoles. This is indicative of a deep environment.

4.   Copper Skarns

These are the world’s most abundant type and are particularly common in orogenic zones related to subduction both in continental and oceanic settings. Most are associated with porphyritic plutons with co-genetic volcanic rocks, stockwork veining, brittle fracturing, brecciation and intense hydrothermal aleteration. These features are all indicative of a relatively shallow environment. The largest copper skarns can exceed 1 billion tonnes and are associated with porphyry copper deposits.

5.   Zinc Skarns

Most occur in continental settings associated either with subduction or rifting. They are also mined for lead and silver, and are high grade. They form in the distal zone to associated igneous rocks.

6.   Molybdenum Skarns

Most are associated with leucocratic (lacking ferromagnesian minerals) granites and form high graade, small deposits. other metals are also commonly associated, the most common being Mo-W-Cu skarns.

7.   Tin Skarns

These are almost exclusively associated with high silica granites generated by partial melting of continental crust. Greisen alteration by fluorine produces a characteristic yellowish mica.

Composition of Skarn

Skarn is composed of of calcium-iron-magnesium-manganese-aluminum silicate minerals. Skarn deposits are economically important valuable sources, which metals such as tungsten, manganese, gold, copper, zinc, nickel, lead, molybdenum and iron.

A skarn is formed by consists of various metasomatic processes during the metamorphism between two adjacent lithological units. Skarn can form in almost any lithology type such as shale, granite and basalt but the majority of skarns are found in lithology containing a limestone or a dolomite. It is common to find skarns near plutons, along faults and major shear zones, in shallow geothermal systems, and on the bottom of the sea floor. The mineralogy of skarn rock usually highly related to the protolith.

Skarn minerals are mostly garnets and pyroxene with a wide variety of calc-silicate and associated minerals. Skarn minerals is include pyroxene, garnet, idocrase, wollastonite, actinolite, magnetite or hematite, epidote and scapolite. Because skarns are formed from incompatible-element rich, siliceous aqueous fluids a variety of uncommon mineral types are found in the skarn environment, such as: tourmaline, topaz, beryl, corundum, fluorite, apatite, barite, strontianite, tantalite, anglesite, and others.

Skarn Formation

In general, there are two main tyoes of skarns that are exoskarns and endoskarns.

Exoskarns are more common than endoskarns. Exoskarns form  on the except intrusive body than comes into contact with carbonate units.They are formed when fluids left over from the crystallisation of the intrusion are ejected from the mass at the waning stages of emplacement. When these fluids come into contact with reactice rocks, generally carbonates rock such as limestone or dolomite, the fluids reacting them, so producing alteration. Also other name of this production infiltration metasomatism

Endoskarns forming within the intursive body where fracturing, cooling joints, and stockworks have been produced, which results in a permeable area. The permeable area can incorporate from the carbonate layer. The magmatic hydrothermal fluids that  were transported or created by the intrusion interacts with the carbonate material and forms the endoskarn. Endoskarns are considered to be rare. Both the composition and the textures of protolith strongly play a role in the formation of the resulting skarn

On the other hand reaction skarn is formed from isochemşcak metamorphism occuring on thinly interlayered sedimentary lithology units that involves a small scale (perhaps centimetres) metasomatic transfer of components between adjacent units.

Skarnoid is a calc-silicate rock than is fine-grained rock but iron poor. It founded lies between a hornfels and a coarse-grained skarns. Generally the skarnoid tends to reflect the composition of the protolithic rock.

Skarn deposit mostly experience a transition from  early metamorphism which forms hornfels, reaction skarns, and skarnoids to late metamorphism which forms relatively coarser grained, ore-bearing skarns. The magma intrusion triggers contact metamorphism in the region where sedimentary rocks are present and form as a result.The recrystallization and phase change of a hornfel reflect the composition of the protolith. After the formation of a hornfel, a process called metasomatism occurs which involves hydrothermal fluids associated with magmatic, metamorphic, marine, meteoric or even a mix of these. This process is called isochemical metamorphism and can result in the production of a wide range of calc-silicate minerals that form in impure lithology units and along fluid boundaries where small-scale metasomatism occurs (argillite and limestone, and banded iron formation).

An antiskarn is a calc-silicate rock that formed by direct metasomatism of silicate rocks by a carbonatite magma.These rocks are characterised by a high-temperature assemblage of diopsidic clinopyroxene, olivine and wollastonite, and an apparent lack of igneous calcite.

Skarn Uses

A variety gemstones have been founded skarn deposits, with garnet, ruby, and sapphire being common occurrences in skarn.

Creating Artwork, Gemstone, Jewelry, Metallurgical Flux, Source of Magnesia (MgO)

As a Flux in the Production of Steel and Pig Iron, As a Sintering Agent in Steel Industry to process Iron Ore, As Dimension Stone, Gold and Silver production, Manufacture of Magnesium and Dolomite Refractories

As Building Stone, As Facing Stone, Garden Decoration, Paving Stone

Other Important Information About Skarn

Rocks that contain garnet or pyroxene as major phases, are fine-grained, lack iron, and have skarn-like appearances, are generally given the term skarnoid. Skarnoid therefore is the intermediate stage of a fine-grained Hornfel and a coarse-grained skarn.

Uncommon types of skarns are formed in contact with sulfidic or carbonaceous rocks such as black shales, graphite shales, banded iron formations and, occasionally, salt or evaporites. Here, fluids react less via chemical exchange of ions, but because of the redox-oxidation potential of the wall rocks

References

  • Bonewitz, R. (2012). Rocks and minerals. 2nd ed. London: DK Publishing.
  • Wikipedia contributors. (2019, April 29). Skarn. In Wikipedia, The Free Encyclopedia. Retrieved 22:48, May 7, 2019, from https://en.wikipedia.org/w/index.php?title=Skarn&oldid=894634204
3,425FansLike
23,108FollowersFollow
2,270SubscribersSubscribe