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Autunite

Autunite is a phosphate mineral that formula is calcium uranium phosphate (Ca (UO2)2(PO4)2·10–12H2O) and It is harness of 2 – 2, 5.A popular collector’s mineral. Greenish or lemon yellow in color, autunite specimens fluoresce green under ultraviolet light. Autunite crystallizes in the orthorhombic system and often occurs as tabular square crystals, commonly in small crusts or in fan-like masses. Due to the moderate uranium content of 48.27% it is radioactive and also used as uranium ore. Coarse groups are found, but scaly coatings are more common. It is also found as crusts with crystals standing on edge, giving a serrated appearance. Named after Autun, France, where this mineral was discovered. It is formed in the oxidation zones of uranium ore bodies as an alteration product of uraniniteand other uranium-bearing minerals. It also occurs in hydrothermal veins and in pegmatites. Since autunite contains uranium and is radioactive, it must be stored carefully and handled as little as possible. When mildly heated, tetragonal autunite dehydrates into orthorhombic meta-autunite. Most museum and collector specimens of autunite have been converted to meta-autunite. A moist atmosphere helps prevent dehydration.

Name: For Autun, France, near to which the first specimens to be analyzed were collected.

Association: Meta-autunite, torbernite, phosphuranylite, saleeite, uranophane, uranophane-beta, sabugalite.

Mineral Group: Autunite group.

Morphology: Crystals thin to thick tabular {001}, and with a rectangular or octagonal outline. Subparallel growths common; foliated or scaly aggregates, crusts.

Type Material: Natural History Museum, Paris, France, H6307.

Chemical Properties

Chemical Classification Phosphate minerals
Formula Ca(UO2)2(PO4)2 · 11H2O

Autunite Physical Properties

Color Yellow, greenish-yellow, pale green; dark green, greenish black.
Streak Pale yellow
Luster Sub-Vitreous, Resinous, Waxy, Pearly
Cleavage Perfect Perfect on {001}, indistinct on {100}
Diaphaneity Transparent, Translucent
Mohs Hardness 2 – 2,5
Crystal System Orthorhombic
Fracture Micaceous
Density 3.05 – 3.2 g/cm3 (Measured)    3.14 g/cm3 (Calculated)
Tenacity Sectile

Autunite Optical Properties

Optical Extinction Z=c, Y={110}
Color / Pleochroism Visible
2V: Measured: 10° to 53°
RI values: nα = 1.553 – 1.555 nβ = 1.575 nγ = 1.577 – 1.578 nω = 1.575 nε = 1.572
Twinning Rare interpenetrant twinning on {110}.
Optic Sign Biaxial (-)
Birefringence δ = 0.003
Relief Low
Dispersion: r > v strong

Occurrence of Autunite

A secondary mineral derived from primary uranium-bearing minerals under oxidizing conditions, in hydrothermal veins, granite pegmatites, etc

Uses Area

This radioactive mineral is a very rich source of uranium containing about 48.27% uranium. Therefore, it is used as uranium ore in various industries. It is also used as a mineral sample.

Autunite Distribution

Widespread, many minor localities, but few for outstanding specimens.

  • In France, at LOuche dJau, Saint-Symphorien-de-Marmagne, and the Les Oudots mine, Autun district, Saone-et-Loire; from the Margnac mine, Compreignac, Haute-Vienne; large crystals from the Gagnol mine, Lachaux, Puy-de-Dome.
  • From Sabugal, Urgeirica, and elsewhere in Portugal.
  • At Peveragno, near Cuneo, Piedmont, Italy.
  • Large crystals from Bergen, Vogtland, Germany.
  • From a number of localities in Cornwall, England.
  • Fine groups from the Dahl (Daybreak) mine, near Mt. Spokane, east of Elk, Spokane Co., Washington, USA.
  • At Malacacheta, Minas Gerais, Brazil.
  • Large crystals from Mt. Painter, Flinders Ranges, South Australia.

References

  • Bonewitz, R. (2012). Rocks and minerals. 2nd ed. London: DK Publishing.
  • Handbookofmineralogy.org. (2019). Handbook of Mineralogy. [online] Available at: http://www.handbookofmineralogy.org [Accessed 4 Mar. 2019].
  • Mindat.org. (2019): Mineral information, data and localities.. [online] Available at: https://www.mindat.org/ [Accessed. 2019].

Wollastonite

Wollastonite is a group of innosilicate mineral, formula is CaSiO3 that may inlude small amount of magnesium, manganese and iron substituting for calcium. A valuable industrial mineral, wollastonite is white, gray, or pale green in color. It occurs as rare, tabular crystals or massive, coarse-bladed, foliated, or fibrous masses. Its crystals are usually triclinic, although its structure has seven variants, one of which is monoclinic. These variations are however, indistinguishable in hand specimens. Wollastonite forms as a result of the contact metamorphism of limestones and in igneous rocks that are contaminated by carbon-rich inclusions. It can be accompanied by other calcium containing silicates, such as diopside, tremolite, epidote, and grossular garnet. Wollastonite also appears in regionally metamorphosed rocks in schists, slates, and phyllites. It forms when impure limestone or dolomite is subjected to high temperature and pressure, which sometimes occurs in the presence of silica-bearing fluids as in skarns or in contact with metamorphic rocks.

Name: For William Hyde Wollaston (1766{1828), English chemist and mineralogist.

Association: Calcite, grossular, diopside, vesuvianite, akermanite, merwinite, larnite, spurrite

Polymorphism & Series: 1A, 2M, 3A, 4A, 5A, 7A polytypes

Mineral Group: Wollastonite Group

Chemical Properties

Chemical Classification Inosilicate mineral
Formula CaSiO3

Wollastonite Physical Properties

Color White, gray-white, light green, pinkish, brown, red, yellow
Crystal habit Rare as tabular crystals—commonly massive in lamellar, radiating, compact and fibrous aggregates.
Streak White
Luster Vitreous, Pearly
Cleavage Perfect Perfect on {001} Good on {001} and {102}
Diaphaneity Transparent, Translucent
Mohs Hardness 4,5 – 5
Crystal System Triclinic
Tenacity Brittle
Density 2.86 – 3.09 g/cm3 (Measured)    2.9 g/cm3 (Calculated)
Fracture Irregular/Uneven
Other characteristics Heat of Formation (@298): -89.61kJ Gibbs Free Energy: 41.78kJ
Melting point 1540 °C

Wollastonite Optical Properties

2V: Measured: 36° to 60°
RI values: nα = 1.616 – 1.640 nβ = 1.628 – 1.650 nγ = 1.631 – 1.653
Optic Sign Biaxial (-)
Birefringence δ = 0.015
Relief Moderate
Dispersion: weak r>v
Twinning Common

Occurrence of Wollastonite

Common in thermally metamorphosed siliceous carbonates, the intruding igneous rock, and skarn deposits along their contact; also in some alkalic igneous rocks and and carbonatites.

Wollastonite Uses Area

  • Wollastonite has industrial importance worldwide. In many sectors, it is often used involved in the manufacture of ceramics to improve many performance parameters, and this is due to yield properties, release from volatile components, whiteness and acicular particle form.
  • In ceramics, wollastonite reduces shrinkage and gas formation during firing, increases green and firepower, maintains brightness during firing, allows rapid firing and reduces crazing, cracking and glaze defects.
  • In metallurgical applications, wollastonite is used to protect the surface of the molten metal during a flux for welding, a source of calcium oxide.
  • As an additive to the paint, it increases the durability of the paint film, acts as a pH buffer, increases weather resistance, reduces gloss, reduces pigment consumption and acts as a smoothing and suspending agent.
  • In plastics, wollastonite increases tensile and bending strength, reduces resin consumption and increases thermal and dimensional stability at high temperatures. Surface treatments are used to improve adhesion between wollastonite and the polymers to which it is added.
  • Instead of asbestos in floor tiles, friction products, insulation boards and panels, paint, plastic and roofing products, wollastonite is resistant to chemical attack, is stable at high temperatures and increases bending and tensile strength.
  • In some industries, it is used at different impurity rates, such as being used as a manufacturer of mineral wool insulation or as an ornamental building material.

The price of raw wollastonite varied in 2008 between US$80 and US$500 per tonne depending on the country and size and shape of the powder particles.

Composition

In a pure CaSiO3, each component constitutes almost half of the mineral: 48.3% CaO and 51.7% SiO2. In some cases, a small amount of iron (Fe) and manganese (Mn) and a smaller amount of magnesium (Mg) are used instead of calcium (Ca) in the mineral formula (eg, Rhodonite). [9] Wollastonite may form a series of solid solutions in the hydrothermal synthesis of phases in the CaSiO3-FeSiO3 system or in the MnSiO3-CaSiO3 system.

Production

World production data for Wollastonite are not available in most countries and are often available from 2 to 3 years of age. Estimated production of crude wollastonite ore in the world in 2016 ranged from 700,000 to 720,000 tons. The world’s wollastonite reserve is estimated to exceed 100 million tons. However, many large deposits have not yet been explored.

Large amounts of wollastonite have been found in China, Finland, India, Mexico and the United States. In Canada, Chile, Kenya, Namibia, South Africa, Spain, Sudan, Tajikistan, Turkey, and Uzbekistan smaller but significant amount of deposits have been identified.

In 2016, major producers were China (425,000 tons), India (185,000 tons), the United States (for commercial reasons third place), Mexico (67,000 tons) and Finland (16,000).

The price of raw wollastonite varied in 2008 between US$80 and US$500 per tonne depending on the country and size and shape of the powder particles.

Distribution of Wollastonite

A widely distributed mineral; some prominent localities are:

  • in Romania, at Dognecea (Dognaczka) and Csiklova, Banat.
  • In Italy, at Sarrabus, Sardinia, and from Monte Somma and Vesuvius, Campania. In Ireland, at Dunmorehead, Mourne Mountains, and Scawt Hill, near Larne, Co. Antrim.
  • From Kongsberg, Norway.
  • At GÄockum, Sweden.
  • In Germany, at Harzburg, Harz Mountains, and Auerbach, Odenwald, Hesse.
  • In the USA, at Natural Bridge and Diana, Lewis Co., New York; from Crestmore, Riverside Co., and Darwin, Inyo Co., California; in a large deposit two miles southeast of Gilbert, Esmeralda Co., Nevada.
  • In Canada, at Oka and Asbestos, Quebec; at Outlet Post, Leeds Co., Ontario.
  • From Pichucalo, Chiapas, and in the Pilares deposit, 55 km north of Hermosillo, Sonora, Mexico.
  • At Hiiagiyama, Ibaragi Prefecture; Ishiyamadera, Shiga Prefecture; and Kushiro, Hiroshima Prefecture, Japan.
  • Large crystals from Belafa, Madagascar.

References

  • Bonewitz, R. (2012). Rocks and minerals. 2nd ed. London: DK Publishing.
  • Handbookofmineralogy.org. (2019). Handbook of Mineralogy. [online] Available at: http://www.handbookofmineralogy.org [Accessed 4 Mar. 2019].
  • Mindat.org. (2019): Mineral information, data and localities.. [online] Available at: https://www.mindat.org/ [Accessed. 2019].

Opal

Opals are a unique and mesmerizing gemstone known for their distinctive play of color, making them one of the most sought-after and mysterious gemstones in the world. In this introduction, we will provide a definition and a brief overview of opals.

Definition: Opals are a type of mineraloid, which means they lack the crystalline structure of typical minerals. Instead, opals are composed of tiny spheres of silica, often arranged in a closely packed and orderly manner. What sets opals apart from other gemstones is their remarkable play of color, which is a phenomenon known as “opalescence.” This play of color occurs due to the interaction of light with the silica spheres within the opal, causing the gemstone to exhibit a stunning array of iridescent colors, often resembling a vibrant spectrum of hues.

Name: Known since antiquity, derives its name from the Roman word opalus, which means “precious stone.”

Association: Chalcedony, quartz, calcite, topaz, goethite, cinnabar, phillipsite, magnesite, fluorite, ikaite

Polymorphism & Series: The structure of low-pressure polymorphs of anhydrous silica consist of frameworks of fully corner bonded tetrahedra of SiO4. The higher temperature polymorphs of silica cristobalite and tridymite are frequently the first to crystallize from amorphous anhydrous silica, and the local structures of microcrystalline also appear to be closer to that of cristobalite and tridymite than to quartz. The structures of tridymite and cristobalite are closely related and can be described as hexagonal and cubic close-packed layers. It is therefore possible to have intermediate structures in which the layers are not regularly stacked.

Historical Significance

Opals have a rich historical significance and cultural importance in various societies throughout history. Their unique play of color and captivating appearance have led to a range of symbolic meanings and beliefs associated with these gemstones. Here’s a closer look at the cultural and symbolic importance of opals:

1. Ancient Roman and Greek Beliefs: In ancient Rome and Greece, opals were highly regarded and believed to be symbols of hope and purity. The Romans called opals “opalus,” meaning “precious stone,” and considered them a symbol of love and good fortune. They associated opals with the rainbow and believed that the gemstones possessed the colors of all other precious stones.

2. Middle Eastern Beliefs: In the Middle East, opals were believed to have fallen from the heavens in lightning storms, making them highly prized and revered. Arabic legends suggested that opals held lightning and had the power to protect against evil.

3. Australian Aboriginal Culture: Opals hold immense cultural significance to Australia’s Indigenous communities, particularly to the Australian Aboriginal people. They have various Dreamtime stories and legends associated with opals, which often involve the creator being associated with the gemstone. Opals are considered sacred, and their colors are believed to represent different spiritual elements.

4. Superstitions and Myths: Opals have been both celebrated and feared for their unique play of color. In some cultures, they were considered symbols of good luck and protection, while in others, they were associated with bad luck and superstitions. Some believed that opals carried curses or misfortune, possibly due to their fragile nature.

5. Birthstone and Zodiac Significance: Opal is the birthstone for October, and it is associated with the zodiac sign Libra. Many people believe that wearing opal jewelry during their birth month can bring them good luck and positive energy.

6. Modern Symbolism: Today, opals are often associated with creativity, inspiration, and emotional healing. They are believed to enhance one’s intuition and imagination. Opal jewelry is frequently given as a gift to symbolize love, loyalty, and hope.

7. Opals in Art and Literature: Opals have been featured prominently in art and literature, often as symbols of mystery and transformation. They have inspired countless poets, writers, and artists with their mesmerizing colors and unique beauty.

8. Royal and Historical Significance: Opals have been used in the crowns, jewelry, and regalia of royals and aristocrats throughout history. Their allure and rarity made them valuable possessions for monarchs and nobility.

In summary, opals have held diverse and evolving cultural and symbolic significance throughout history. While they have been revered for their captivating beauty and positive attributes in many cultures, they have also faced superstitions and myths in others. Today, opals continue to be cherished for their unique play of color and are celebrated as symbols of creativity, love, and hope in the modern world.

Opal Chemical, Physical and Optical Properties

Opals are unique gemstones with distinct chemical, physical, and optical properties that contribute to their characteristic play of color and overall appearance. Here’s an overview of these properties:

Chemical Properties:

  1. Composition: Opals are primarily composed of hydrated silicon dioxide (SiO2·nH2O), commonly known as silica. The water content in opals can vary, and it plays a crucial role in the gemstone’s optical properties.
  2. Amorphous Structure: Unlike many other gemstones, which have a crystalline structure, opals have an amorphous, non-crystalline structure. This lack of crystallinity is responsible for their unique optical properties.

Physical Properties:

  1. Hardness: Opals are relatively soft gemstones, with a hardness of about 5.5 to 6.5 on the Mohs scale. This means they are more susceptible to scratching and abrasion compared to harder gemstones like diamonds or sapphires.
  2. Specific Gravity: The specific gravity of opals typically ranges from 1.98 to 2.25. This value indicates the gemstone’s density relative to the density of water.
  3. Transparency: Opals can be translucent to semi-translucent, with varying degrees of transparency depending on their type and quality.
  4. Cleavage and Fracture: Opals do not have a distinct cleavage like some other minerals. They exhibit conchoidal fracture, which means they break with smooth, curved surfaces similar to the way glass shatters.

Optical Properties:

  1. Play of Color: The most distinctive optical property of opals is their play of color, also known as “opalescence.” This phenomenon results from the interaction of light with microscopic silica spheres or voids within the opal. The varying sizes and arrangement of these spheres cause diffraction and interference of light, producing a spectrum of vibrant colors that change as the viewing angle shifts.
  2. Body Color: Opals can have a range of body colors, including white, black, gray, and various shades of brown. The play of color is superimposed on this body color, creating the opal’s overall appearance.
  3. Luster: Opals typically exhibit a vitreous to resinous luster, but this can vary depending on the type and quality of the opal.
  4. Refractive Index: Opals have a refractive index that falls in the range of 1.37 to 1.47. This index affects the way light is bent or refracted as it passes through the gemstone, contributing to the play of color.
  5. Birefringence: Opals do not exhibit birefringence, unlike some other gemstones that split light into two distinct rays.
  6. Dispersion: While opals do not have the high dispersion seen in diamonds or other gemstones like sapphires, their play of color is a form of dispersion, where different colors are separated and displayed due to the varying wavelengths of light.

In summary, opals are characterized by their unique play of color, which is a result of their amorphous structure and the interaction of light with microscopic structures within the gemstone. These properties make opals one of the most intriguing and captivating gemstones in the world, prized for their iridescent and ever-changing beauty.

Occurrence and Formation of Opal

Opals are formed through intricate geological processes and are found in various parts of the world. Their occurrence and formation involve a combination of specific geological conditions and the deposition of silica-rich solutions. Here’s an overview of how opals occur and are formed:

1. Geological Conditions:

  • Silica-Rich Environments: Opals are primarily composed of hydrated silica (SiO2·nH2O). They form in geological environments where silica-rich solutions are present. These solutions can come from a variety of sources, including groundwater, volcanic activity, and weathering of pre-existing rocks.
  • Porosity: The host rocks or sediments where opals form often have a high degree of porosity. This allows for the infiltration and circulation of silica-rich fluids.

2. Formation Process:

  • Hydration of Silica: Opal formation begins when water, often carrying dissolved silica, seeps into the host rock or sediment. The silica can come from the dissolution of surrounding minerals like quartz.
  • Deposition: As the silica-rich water infiltrates the porous rock or sediment, it encounters various conditions that trigger the precipitation of opal. These conditions can include changes in temperature, pressure, or pH levels.
  • Colloidal Silica: In some cases, opal formation involves the aggregation of tiny silica particles, creating a gel-like substance known as colloidal silica. This colloidal silica can accumulate in cracks, voids, or other openings within the host material.
  • Drying and Hardening: Over time, as the water carrying silica infiltrates deeper into the host rock or sediment and begins to evaporate or lose water content, the silica solidifies and hardens. The precise conditions during this drying process, including the rate of evaporation and temperature, can influence the type of opal formed and its play of color.

3. Types of Opals:

  • Precious Opals: These are opals that display the well-known play of color or opalescence. The play of color is a result of the unique arrangement of silica spheres within the opal, which diffract and scatter light, creating vibrant hues.
  • Common Opals: Common opals do not exhibit a play of color. They are typically opaque to translucent and may have a single, uniform body color. While they lack the iridescence of precious opals, they can still be attractive and valuable.

4. Locations of Occurrence:

  • Australia: Australia is renowned for producing some of the world’s most famous and valuable opals, including Black Opals, White Opals, and Boulder Opals. The Australian outback, particularly regions like Lightning Ridge, Coober Pedy, and Queensland, is known for its opal mines.
  • Ethiopia: Ethiopia has become a significant source of opals in recent years, particularly Welo and Mezezo opals, which can exhibit vibrant play of color.
  • Mexico, Brazil, and the United States: These countries also have opal deposits, with Mexico known for its Fire Opals and Brazil for its colorful Opalinas. In the United States, Nevada is a notable source of precious opals.

In conclusion, opals are formed through the deposition of silica-rich solutions in geological environments with specific conditions, resulting in the unique and mesmerizing gemstones known for their play of color. The occurrence of opals can vary widely, with different types and qualities found in different regions around the world.

Types of Opals

Opals come in various types, each with its own distinctive characteristics and appearance. The primary types of opals include:

  1. Precious Opals:
    • White Opals: White opals are characterized by their white to light gray body color, and they often display a play of color with vibrant hues. These opals are usually found in South Australia and are valued for their subtle yet beautiful play of color.
    • Black Opals: Black opals are the most highly prized and sought-after opals. They have a dark body color, typically black or very dark gray, which serves as a striking backdrop for their intense and vivid play of color. The town of Lightning Ridge in New South Wales, Australia, is renowned for producing some of the world’s finest black opals.
    • Boulder Opals: Boulder opals form within ironstone matrix or host rock, and they often display a play of color against a natural brown or ironstone background. These opals are mainly found in Queensland, Australia. Boulder opals are unique because they retain some of the host rock, creating intriguing patterns and designs.
    • Crystal Opals: Crystal opals have a transparent to translucent body, allowing for an excellent play of color to be visible. They can display vibrant colors against a clear or slightly milky background. Crystal opals are found in various opal-producing regions, including Australia and Brazil.
    • Jelly Opals: Jelly opals are a subtype of crystal opals characterized by their transparent, jelly-like appearance. They often have a water-clear body that enhances the visibility of the play of color.
  2. Common Opals:
    • White Common Opals: White common opals, as the name suggests, have a white or light-colored body without a significant play of color. They are known for their opalescence, which gives them a milky, semi-translucent appearance.
    • Mexican Fire Opals: These opals are valued for their vibrant orange, red, or yellow body colors. They do not typically display a play of color but are prized for their intense, fiery hues. Mexico is a primary source of fire opals.
    • Peruvian Opals: Found mainly in Peru, these opals come in various colors, including blue-green, pink, and purple. They are known for their smooth, cabochon-cut appearance and are often used in jewelry.
    • Hydrophane Opals: Hydrophane opals have the unique property of becoming temporarily transparent or translucent when immersed in water. This property makes them popular for carving and cabochon cutting.
  3. Matrix Opals:
    • Matrix opals are opals that are naturally embedded within their host rock, forming interesting patterns and designs. Boulder opals are a type of matrix opal, but there are other varieties as well, such as Koroit opal and Yowah opal, which are also found in Queensland, Australia.
  4. Synthetic Opals:
    • Synthetic or lab-created opals are manufactured in laboratories to replicate the appearance of natural opals. While they may not have the geological origin of natural opals, they can exhibit a play of color and are used in jewelry.

Each type of opal has its unique beauty and appeal, making opals one of the most diverse and captivating gemstones in the world of jewelry and gem collecting.

Uses and Application of Opal

Opals are prized gemstones with a wide range of uses and applications, primarily in the realm of jewelry and ornamental items. Their unique play of color and enchanting appearance make them a popular choice for various purposes:

1. Jewelry:

  • Rings: Opal rings are a popular choice for both engagement and fashion jewelry. They can feature different opal types and settings to suit various styles and preferences.
  • Necklaces: Opal pendants and necklaces showcase the gemstone’s beauty and are often worn as statement pieces.
  • Earrings: Opal earrings come in various designs, from simple studs to more intricate dangle and drop earrings.
  • Bracelets: Opal bracelets incorporate opals into their designs, either as a focal point or as accent stones.
  • Brooches: Opals are used in brooches and pins to add a touch of elegance and color to clothing.

2. Gemstone Collecting:

  • Opals, especially precious opals with exceptional play of color, are sought after by gemstone collectors. Collectors appreciate the rarity and individuality of opals, and some may focus on acquiring opals from specific regions or with unique characteristics.

3. Art and Decorative Items:

  • Opals are used in the creation of decorative items, sculptures, and art pieces. Their vibrant colors and iridescence can enhance the visual appeal of these items.

4. Religious and Spiritual Significance:

  • In some cultures, opals are associated with spiritual and healing properties. They may be used as talismans, amulets, or prayer beads.

5. Birthstone Jewelry:

  • Opals are the traditional birthstone for the month of October. Jewelry featuring opals is often given as birthday gifts to individuals born in this month, as it is believed to bring good luck and positive energy.

6. Custom and Artisan Jewelry:

  • Many jewelry designers and artisans incorporate opals into their unique, handcrafted creations. This allows for custom and one-of-a-kind pieces that cater to specific tastes and preferences.

7. Opal Inlays and Mosaics:

  • Opals are sometimes used in the creation of intricate inlay work and mosaics in decorative objects, including furniture, tiles, and musical instruments.

8. Ethical and Sustainable Jewelry:

  • With growing awareness of ethical and sustainable sourcing, some jewelers offer opals from responsible mining practices and fair trade sources, appealing to consumers who prioritize ethical gemstone choices.

9. Engagement and Wedding Rings:

  • Opals are chosen for engagement and wedding rings by couples who appreciate their unique and romantic appearance. However, it’s important to note that opals are relatively soft compared to traditional engagement stones like diamonds, so they require special care to prevent damage.

10. Carvings and Cameos: – Opals are sometimes carved into intricate designs and cameos, showcasing the artisan’s skill and creativity.

It’s important to note that while opals are undoubtedly stunning gemstones, they are relatively soft and require careful handling to avoid scratching or damage. Opal jewelry should be stored and worn with care to ensure its longevity and continued beauty.

Famous Opals

Aurora Australis

Famous opals, notable discoveries, and opal-adorned jewelry pieces have captured the fascination of people around the world for their exquisite beauty and unique play of color. Here are some notable examples:

Famous Opals:

  1. Aurora Australis: The Aurora Australis is one of the world’s most famous black opals. Discovered in Lightning Ridge, New South Wales, Australia, in 1938, it is renowned for its intense play of color, including vivid reds and blues. It weighs approximately 180 carats and is considered one of the most valuable opals in existence.
  2. Andamooka Opal: Found in South Australia in 1932, the Andamooka Opal is another legendary black opal. It displayed remarkable play of color and weighed over 200 carats in its rough state. It was later cut into several smaller stones, with the largest known as the “Queen’s Opal.”
  3. The Olympic Australis: Discovered in 1956, the Olympic Australis is one of the largest and most valuable opals ever found. It weighs around 17,000 carats and was named in honor of the 1956 Olympic Games held in Melbourne, Australia. Its play of color is exceptional, featuring a wide spectrum of hues.

Notable Opal Discoveries:

  1. Lightning Ridge, Australia: Lightning Ridge, located in New South Wales, is renowned for its black opals. The town’s opal fields have yielded many exceptional gems, including the world-famous Aurora Australis and Andamooka Opal.
  2. Coober Pedy, Australia: Coober Pedy is another major opal mining area in South Australia. It is known for producing white opals and crystal opals, often used in high-quality jewelry.
  3. Welo, Ethiopia: In recent years, Ethiopia has emerged as a significant opal-producing region. The Welo opal fields have yielded vibrant and colorful opals, including precious and crystal opals.
  4. Virgin Valley, Nevada, USA: Nevada is known for producing valuable black and fire opals. Virgin Valley, in particular, has been a source of stunning opals, including the Rainbow Ridge Opal and the Bonanza Opal.

Famous Opal Jewelry Pieces:

  1. The Burning of Troy Tiara: This exquisite tiara, made by Castellani in the 19th century, features opals among other gemstones. It is a part of the British royal collection and is known for its intricate design and historical significance.
  2. The Empress Eugénie Tiara: Commissioned by Emperor Napoleon III of France for his wife, Empress Eugénie, this tiara features opals and diamonds in a delicate floral motif. It remains one of the most famous opal tiaras in history.
  3. The Grand Opal Tiara: Created by Boucheron for Queen Isabella II of Spain, this tiara features several opals surrounded by diamonds. It is now part of the Spanish royal jewelry collection.
  4. The Queen’s Opal Brooch: The largest stone cut from the Andamooka Opal, known as the “Queen’s Opal,” was set into a brooch and presented to Queen Elizabeth II of the United Kingdom during her visit to Australia in 1954.

These famous opals and opal-adorned jewelry pieces showcase the allure and beauty of these gemstones, which have captivated the hearts of collectors, royalty, and jewelry enthusiasts throughout history. Opals continue to be treasured for their enchanting play of color and timeless appeal.

Conclusion

In summary, opals are captivating gemstones known for their unique play of color, formed through the interaction of silica-rich solutions with specific geological conditions. They have significant historical, cultural, and symbolic importance and are used in various applications, primarily in jewelry and ornamental items. Notable opals, such as the Aurora Australis and the Olympic Australis, have achieved worldwide fame, and opal discoveries in places like Lightning Ridge and Coober Pedy, Australia, have shaped the opal industry.

Key Points:

  • Opals are composed of hydrated silica and have an amorphous structure.
  • They exhibit a play of color or opalescence due to the diffraction and interference of light with microscopic silica spheres.
  • Opals come in various types, including precious opals (e.g., white, black, crystal, boulder) and common opals (e.g., white common, Mexican fire).
  • Opals are used in jewelry, art, collectibles, religious items, and more.
  • Famous opals like the Aurora Australis and the Olympic Australis are highly valuable and renowned for their beauty.
  • Notable opal discoveries have been made in Lightning Ridge and Coober Pedy, Australia, as well as in Ethiopia and the United States.
  • Opals have adorned famous jewelry pieces, including tiaras and brooches, and have historical and royal significance.

Future of Opals:

The future of opals is promising but also faces challenges:

  1. Sustainability: Ethical and sustainable sourcing of opals will likely become increasingly important as consumers prioritize responsible practices in the gemstone industry.
  2. Technology: Advancements in gemstone treatment and enhancement techniques may impact the opal market. Disclosure and transparency in gemstone treatment will be critical.
  3. Fashion Trends: Opals are likely to continue to be sought after for their unique play of color and artistic appeal, especially in custom and artisan jewelry pieces.
  4. Scientific Research: Ongoing research into the geological processes and formation of opals can provide valuable insights and may lead to new discoveries.

In conclusion, opals will remain a beloved gemstone for their enchanting beauty and symbolic significance. Their future will be shaped by evolving consumer preferences, sustainable practices, and ongoing scientific exploration.

References

  • Bonewitz, R. (2012). Rocks and minerals. 2nd ed. London: DK Publishing.
  • Mindat.org. (2019). Opal: Mineral information, data and localities.. [online] Available at: https://www.mindat.org/ [Accessed. 2019].
  • Wikipedia contributors. (2019, June 13). Opal. In Wikipedia, The Free Encyclopedia. Retrieved 00:37, June 20, 2019, from https://en.wikipedia.org/w/index.php?title=Opal&oldid=901668208

Weathering Types

Weathering is the combination of processes that breaking down of rocks, soil and minerals, eventually transforming into sediment. On the other hand, disintegration or alteration of the rock surface in its natural or original position through physical, chemical and biological processes induced or modified by wind, water and climate.

Spheroidal Weathering
Spheroidal Weathering (Spheroidal weathering is most common among coarse-grained igneous rocks, especially granite and similar rock types. It is more likely to be found in warm climates, where mechanical weathering by freezing ice is less likely.) Source: https://sciencing.com/definition-spheroidal-weathering-23142.html

Weathering involves physical, chemical, and biological processes that act separately or more often together to cause fragmentation and decay of rock material. Physical decomposition causes mechanical disintegration of the rock and therefore depends on the application of force. Weathering involves breaking up the rock into the forming minerals or particles without disturbing the forming minerals. The main sources of physical Weathering are the expansion and contraction of heat, the erosion of overlapping materials, the release of pressure on the rock, alternatively the freezing and thawing of water, the dissolution of water between the cracks and cracks in the rock, the growth of plants and organisms in the rock. Organisms in the rock. Rock exchange usually involves chemical deterioration in which the mineral composition in the rock is altered, rearranged or redistributed. Rock minerals are subjected to solution, carbonation, hydration and oxidation with circulating water. These effects on the Weathering of minerals are added to the effects of living organisms and plants as nutrient extraction to rocks.

After the rock breaks, the remaining materials cause soil with organic materials. The mineral content of the soil is determined by the parent material; therefore, a soil derived from a single rock type may often be lacking in one or more minerals required for good fertility, whereas a ventilated soil from a mixture of rock types (such as glacial, aeolian or alluvial deposits) generally makes more fertile soils. In addition, most of the Earth’s landforms and landscapes are the result of decomposition processes associated with erosion and re-accumulation.

Explain the disintegration or dissolution of rocks and minerals on the Earth’s surface. Water, ice, acids, salts, plants, animals and changes in temperature are all weather conditions.

After a rock is shredded, a process called erosion removes rock and mineral fragments. No rock on earth can resist erosion.

Weathering and erosion constantly changes the rocky landscape of the Earth. Wear abrades exposed surfaces over time. Exposure time generally contributes to how vulnerable a rock is to weather conditions. Rocks buried under other rocks, such as lava, are less susceptible to wear and erosion than rocks exposed to wind and water.

It is the first step in soil production in weather conditions as it smooths hard, sharp rock surfaces. Small pieces of worn minerals mix with plants, animal remains, fungi, bacteria and other organisms. A single type of weathered rock generally produces infertile soil, the weathered materials from the rock collection are richer in mineral diversity and contribute to more fertile soil. Soil types associated with the weathered rock mixture include untouched and alluvial deposits until icing.

Picture from Stephen Marshak (Essentials of Geology)

Physical weathering or Mechanical weathering

Physical weathering, also called mechanical weathering or disaggregation, is a class of processes that cause rocks to break up without chemical change. The primary process in physical weathering is abrasion (the process by which clips and other particles are reduced in size).  Temperature, pressure, freezing and so on. Physical weathering may occur for reasons. For example, cracks resulting from physical weathering will increase the surface area exposed to the chemical effect, thereby increasing the rate of disintegration.

Frost wedging: Freezing water blows pipes and breaks bottles; because water expands when the walls of the container freeze and push. The same phenomenon occurs on the rock. When stuck water in a joint freezes, it forces the joint to open and may cause the joint to grow. These freezing wedges allow the blocks to be freed from solid bedrock.

Salt wedging: In arid climates, dissolved salt in groundwater precipitates and grows as crystals in open pore spaces in rocks. This process, called salt wedging, pushes apart the surrounding grains and weakens the rock so that when exposed to wind and rain, the rock disintegrates into separate grains. The same phenomenon happens along the coast, where salt spray percolates into rock and then dries.

Root wedging: Have you ever noticed how the roots of an old tree can break up a sidewalk? As roots grow, they apply pressure to their surroundings, and can push joints open in a process known as root wedging

Thermal expansion: When the heat of an intense forest fire bakes a rock, the outer layer of the rock expands. On cooling, the layer contracts. This change creates forces in the rock sufficient to make the outer part of the rock break off in sheet-like pieces. Recent research suggests that the intense heat of the Sun’s rays sweeping across dark rocks in a desert may cause the rocks to fracture into thin slices.

Animal attack: Animal life also contributes to physical weathering: burrowing creatures, from earthworms to gophers, push open cracks and move rock fragments. And in the past century, humans have become perhaps the most energetic agent of physical weathering on the planet. When we excavate quarries, foundations, mines, or roadbeds by digging and blasting, we shatter and displace rock that might otherwise have remained intact for millions of years more.

Bryce Canyon National Park

Chemical weathering

Chemical weathering changes the composition of rocks, often transforming them when water interacts with minerals to create various chemical reactions. Chemical weathering is a gradual and ongoing process as the mineralogy of the rock adjusts to the near surface environment. New or secondary minerals develop from the original minerals of the rock. In this the processes of oxidation and hydrolysis are most important. Chemical weathering is enhanced by such geological agents as the presence of water and oxygen, as well as by such biological agents as the acids produced by microbial and plant-root metabolism.

The process of mountain block uplift is important in exposing new rock strata to the atmosphere and moisture, enabling important chemical weathering to occur; significant release occurs of Ca2+ and other ions into surface waters.

Dissolution: Chemical weathering during which minerals dissolve into water is called dissolution. Dissolution primarily affects salts and carbonate minerals (Fig. B.6a, b), but even quartz dissolves slightly.

Hydrolysis: During hydrolysis, water chemically reacts with minerals and breaks them down (lysis means loosen in Greek) to form other minerals. For example, hydrolysis reactions in feldspar produce clay.

Oxidation: Oxidation reactions in rocks transform ironbearing minerals (such as biotite and pyrite) into a rustybrown mixture of various iron-oxide and iron-hydroxide minerals. In effect, iron-bearing rocks can “rust.”

Hydration: the absorption of water into the crystal structure of minerals, causes some minerals, such as certain types of clay, to expand. Such expansion weakens rock.

Organic or Biological Weathering

A number of plants and animals may create chemical weathering through release of acidic compounds, i.e. the effect of moss growing on roofs is classed as weathering. Mineral weathering can also be initiated or accelerated by soil microorganisms. Lichens on rocks are thought to increase chemical weathering rates.

Some plants and animals can cause chemical weathering through the release of acidic compounds, ie, classification of algae grown on the roof as degradation. Mineral weathering can also be initiated or accelerated by soil microorganisms. It is thought that lichens on the rocks increase the chemical weathering rates.

The most common forms of biological weathering are the release of chelating compounds (ie, organic acids, siderophores) and acidifying molecules (ie, protons, organic acids) to break down aluminum and iron-containing compounds in soils beneath plants. The decomposition of the remains of dead plants in the soil can form organic acids which, when dissolved in water, cause chemical weather conditions. Excessive release of chelating compounds can easily affect the surrounding rocks and soils and lead to soils podsolization.

Factors affecting weathering

Weathering is affected by several factors, including climate, rock type, and natural agents. Here’s a brief discussion of each of these factors:

  1. Climate: The climate of a particular area can greatly influence the type and rate of weathering that occurs. In regions with high rainfall and high humidity, chemical weathering is more common, as water reacts with minerals in rocks to create new compounds. In contrast, areas with extreme temperature changes, such as those that experience freeze-thaw cycles, experience mechanical weathering due to the expansion and contraction of water in rocks. Additionally, areas with strong winds can cause abrasion and wear on exposed rock surfaces.
  2. Rock type: The type of rock being weathered is also an important factor. Some rocks, such as granite and basalt, are more resistant to weathering due to their dense and hard composition. In contrast, sedimentary rocks, such as sandstone and limestone, are often more susceptible to weathering due to their porous nature and the presence of minerals that can dissolve in water. Additionally, rocks that contain iron and other minerals that are prone to oxidation are more susceptible to chemical weathering.
  3. Natural agents: Natural agents such as water, wind, and living organisms can greatly influence the rate and type of weathering that occurs. Water can cause both mechanical and chemical weathering, as it can freeze and thaw in rocks, and it can also dissolve minerals over time. Wind can cause abrasion and wear on exposed rock surfaces, while living organisms such as plant roots and burrowing animals can physically break down rocks and minerals.

Effects of weathering on the landscape

Weathering has a significant impact on the landscape over time. Here are some effects of weathering on the landscape:

  1. Formation of soil: Weathering plays a major role in the formation of soil. As rocks and minerals are broken down by natural agents and chemical reactions, they form smaller particles that mix with organic matter to create soil. Over time, the accumulation of soil can support the growth of vegetation, leading to the development of complex ecosystems.
  2. Erosion: Weathering can contribute to erosion, which is the process of removing soil and rock from one location to another through natural agents such as water and wind. As rocks and minerals are weathered, they can become loose and easily transported by these agents, leading to the formation of features such as canyons, valleys, and riverbeds.
  3. Sedimentation: Weathering can also contribute to sedimentation, which is the process of depositing sediment in a new location. As weathered material is transported by natural agents, it can settle and accumulate in a new area. This can lead to the formation of sedimentary rocks over time.
  4. Formation of caves: Chemical weathering can dissolve rocks and minerals over time, leading to the formation of caves and other underground features. In limestone areas, for example, the dissolution of calcium carbonate by acidic water can lead to the formation of complex cave systems.
  5. Formation of mountains: Weathering can contribute to the formation of mountains over long periods of time. As rocks are weathered and eroded, the resulting sediments can accumulate and be compressed, leading to the formation of new rock formations and the uplift of land masses.

Overall, weathering is an important natural process that contributes to the shaping and evolution of the Earth’s landscape over time.

Human impact on weathering

Human activities can have a significant impact on weathering processes. Here are some ways in which human activities can affect weathering:

  1. Land use changes: Human activities such as deforestation, urbanization, and agriculture can alter the natural landscape and affect the rate and type of weathering that occurs. For example, deforestation can lead to increased soil erosion and decreased plant cover, leading to increased chemical weathering of rocks and soil.
  2. Mining and excavation: Mining and excavation activities can remove large quantities of rocks and minerals, leading to significant changes in the local geology and weathering patterns. These activities can also increase the exposure of rocks and minerals to natural agents such as water and air, leading to accelerated weathering.
  3. Industrial activities: Industrial activities such as fossil fuel combustion and manufacturing can release pollutants into the air and water, which can react with rocks and minerals and contribute to chemical weathering. Additionally, the construction of buildings and infrastructure can alter the local landscape and affect the natural processes of weathering and erosion.
  4. Climate change: Human activities such as the burning of fossil fuels and deforestation can contribute to global climate change, which can alter the temperature and precipitation patterns in a given area. These changes can affect the type and rate of weathering that occurs, as well as other natural processes such as erosion and sedimentation.

In summary, human activities can have both direct and indirect impacts on weathering processes, and can alter the natural landscape and ecosystem dynamics over time. Understanding and minimizing these impacts is important for preserving natural resources and maintaining healthy ecosystems.

Practical applications of weathering

Weathering processes have several practical applications across a range of fields. Here are some examples:

  1. Agriculture: Weathering plays a critical role in the formation of soil, which is essential for agriculture. Understanding weathering processes can help farmers optimize their soil management practices, such as selecting the appropriate fertilizers and irrigation methods based on the type of soil and weather conditions.
  2. Geology and mining: Weathering patterns and rates can be used to identify the types and locations of valuable minerals and ores. By understanding the weathering characteristics of different rock formations, geologists and miners can optimize their exploration and extraction efforts.
  3. Civil engineering and construction: Understanding the weathering characteristics of different types of rock and soil is important for construction projects such as building foundations, tunnels, and bridges. Engineers need to consider the potential impacts of weathering processes such as erosion and subsidence on the long-term stability and safety of these structures.
  4. Environmental science: Weathering processes play an important role in the natural carbon cycle and can affect climate change. Understanding the processes and rates of weathering can help researchers better model and predict the impacts of climate change on the Earth’s systems and inform strategies for mitigating these impacts.
  5. Cultural heritage preservation: Weathering processes can cause damage to cultural heritage sites such as monuments and sculptures. Understanding the weathering characteristics of different materials and environmental conditions can help conservators develop effective preservation and restoration strategies.

Overall, understanding weathering processes is important for a range of practical applications across fields such as agriculture, geology, construction, environmental science, and cultural heritage preservation.

Weathering research: Methods and current trends

Weathering research is a broad and interdisciplinary field that involves the study of physical, chemical, and biological processes that transform rocks and minerals over time. Here are some methods and current trends in weathering research:

  1. Laboratory experiments: Researchers use laboratory experiments to study the chemical and physical weathering processes that occur under controlled conditions. These experiments can help identify the mechanisms and rates of weathering reactions and provide insights into the factors that influence these processes.
  2. Field observations: Field observations involve the direct measurement and monitoring of weathering processes in natural environments. Researchers use field observations to study the effects of climate, geology, and vegetation on weathering patterns and rates over time.
  3. Modeling: Modeling involves the use of mathematical and computer-based models to simulate weathering processes and predict their impacts under different scenarios. Modeling can help researchers better understand the complex interactions between different environmental factors and inform management and conservation strategies.
  4. Emerging techniques: Advances in analytical techniques such as X-ray diffraction, scanning electron microscopy, and laser ablation inductively coupled plasma mass spectrometry have enabled researchers to study weathering processes at the micro- and nanoscale. These techniques allow researchers to identify and characterize the mineralogy and chemistry of rocks and minerals and provide insights into the mechanisms and rates of weathering reactions.
  5. Interdisciplinary approaches: Weathering research is increasingly becoming more interdisciplinary, with researchers from different fields such as geology, chemistry, biology, and environmental science collaborating to study weathering processes and their impacts on the Earth’s systems. This approach allows for a more holistic understanding of weathering processes and their interactions with other environmental factors.

Overall, weathering research involves a range of methods and approaches aimed at understanding the complex and dynamic processes that transform rocks and minerals over time. Ongoing research in this field is critical for understanding and managing the impacts of weathering on the Earth’s systems and developing strategies for mitigating these impacts.

Summary of key points and future directions in weathering research.

Key points in weathering research include:

  1. Weathering processes are complex and dynamic and involve physical, chemical, and biological processes that transform rocks and minerals over time.
  2. Factors such as climate, rock type, and natural agents influence the rates and patterns of weathering.
  3. Weathering can have significant impacts on the landscape, including the formation of soil, the release of nutrients, and the erosion of rock formations.
  4. Human activities such as pollution, deforestation, and mining can accelerate or modify weathering processes.

Future directions in weathering research may include:

  1. Developing a better understanding of the microscale and nanoscale processes that drive weathering reactions.
  2. Studying the impacts of climate change on weathering processes and the carbon cycle.
  3. Investigating the interactions between different environmental factors, such as climate, vegetation, and soil properties, on weathering rates and patterns.
  4. Developing more effective strategies for managing and mitigating the impacts of weathering on natural and cultural systems.
  5. Improving our understanding of the role of weathering in the formation and evolution of planets, including the early Earth and Mars.

Overall, weathering research is an interdisciplinary field with significant implications for a range of scientific and practical applications. Ongoing research in this field is critical for understanding and managing the impacts of weathering on the Earth’s systems and developing strategies for mitigating these impacts.

Weathering FAQ

Q: What is weathering?

A: Weathering is the process by which rocks and minerals are broken down into smaller particles due to exposure to the atmosphere, water, and other natural agents.

Q: What are the three types of weathering?

A: The three types of weathering are mechanical weathering, chemical weathering, and biological weathering.

Q: What is mechanical weathering?

A: Mechanical weathering occurs when rocks and minerals are broken down into smaller pieces through physical processes.

Q: What is chemical weathering?

A: Chemical weathering occurs when rocks and minerals are broken down through chemical reactions.

Q: What is biological weathering?

A: Biological weathering occurs when rocks and minerals are broken down through the action of living organisms.

Q: How do these types of weathering work together?

A: All three types of weathering can work together to break down rocks and minerals into smaller particles, which can then be transported and deposited by natural agents such as wind and water.

Q: Why is weathering important?

A: The process of weathering is an important part of the natural rock cycle, and it plays a crucial role in shaping the Earth’s landscape over time.

Q: What are some examples of mechanical weathering?

A: Examples of mechanical weathering include freeze-thaw cycles, exfoliation due to pressure release, abrasion due to wind or water, and the formation of talus slopes.

Q: What are some examples of chemical weathering?

A: Examples of chemical weathering include the dissolution of limestone by carbonic acid, the oxidation of iron in rocks to form rust, and the leaching of minerals by acid rain.

Q: What are some examples of biological weathering?

A: Examples of biological weathering include the breakdown of rocks and minerals by plant roots, the burrowing of animals into rocks, and the action of microorganisms in soil.

Q: How long does weathering take?

A: The amount of time it takes for weathering to occur depends on factors such as the type of rock or mineral, the climate and environment, and the strength and duration of the natural agents causing weathering. Some rocks may weather quickly in certain conditions, while others may take thousands or even millions of years to weather.

Q: What are the effects of weathering on the Earth’s landscape?

A: Weathering plays a major role in shaping the Earth’s landscape over time. It can create features such as canyons, caves, and mountains, and it can also break down rocks and minerals into smaller particles that contribute to the formation of soil and the cycling of nutrients in ecosystems. Weathering can also contribute to erosion and sedimentation, which can have both positive and negative effects on the environment.

References

  1. White, A. F., & Brantley, S. L. (2016). The effect of time on the weathering of silicate minerals: why do weathering rates differ in the laboratory and field?. Chemical Geology, 420, 1-16.
  2. Lalonde, K., Konhauser, K. O., & Reimer, C. W. (2012). The last billion years of Earth history: A bio-inorganic sedimentary record of coupled climate, sedimentation, and evolution. Earth-Science Reviews, 108(1-2), 47-75.
  3. Brantley, S. L., & Lebedeva, M. I. (2011). Learning to read the chemistry of silicate rocks: Weathering geothermometers and geospeedometers. Earth-Science Reviews, 106(1-2), 92-111.
  4. Navarrete-López, M., & Martínez-Montoya, J. F. (2017). The role of weathering in the formation and evolution of planets. Planetary and Space Science, 138, 1-10.
  5. Gabet, E. J., & Mudd, S. M. (2010). Bedrock and soil controls on alpine treeline ecotone position. Journal of Geophysical Research: Earth Surface, 115(F4).
  6. Foster, C., & Rosenzweig, C. (2003). Assessing the vulnerability of human settlements to extreme weather events: a conceptual framework. Environment and Urbanization, 15(2), 123-135.

Bowen’s Reaction Series

Bowen’s Reaction Series is a fundamental concept in the field of geology, specifically in the study of igneous rocks. It was developed by Canadian geologist N.L. Bowen in the early 20th century and provides critical insights into the formation of igneous rocks, their mineral composition, and the sequence in which minerals crystallize as molten rock (magma) cools and solidifies. This concept is crucial for understanding the Earth’s geology, the processes that shape its crust, and even the development of mineral resources.

Bowen's Reaction Series
Bowen’s Reaction Series

Definition and Significance:

Bowen’s Reaction Series is a graphical representation of the sequence in which minerals crystallize from a cooling magma. It helps geologists understand the relationship between temperature and the mineral composition of igneous rocks. The key points to note are:

  1. Mineral Crystallization Sequence: Bowen’s Reaction Series outlines two main branches – the discontinuous branch and the continuous branch. The discontinuous branch represents the minerals that crystallize at distinct temperature intervals. The continuous branch represents minerals that form continuously as temperature decreases.
  2. Temperature Gradient: The series illustrates that different minerals have different crystallization temperatures. Minerals that form at higher temperatures are found at the top of the series, while those forming at lower temperatures are at the bottom. This temperature gradient helps geologists understand the cooling history of a particular igneous rock.
  3. Composition Changes: As a magma cools and minerals crystallize, the composition of the remaining magma changes. This can lead to the development of different types of igneous rocks, including those rich in felsic (light-colored) minerals like quartz and feldspar or mafic (dark-colored) minerals like pyroxene and olivine.
  4. Practical Applications: Understanding Bowen’s Reaction Series is crucial in fields such as mineral exploration, petrology, and volcanology. It helps geologists predict the mineral composition of igneous rocks, which is valuable information for resource exploration and understanding volcanic processes.

Formation of Igneous Rocks:

Formation of Igneous Rocks

Igneous rocks are formed from the solidification and crystallization of molten rock material, either beneath the Earth’s surface (intrusive or plutonic) or on the surface (extrusive or volcanic). The process can be summarized as follows:

  1. Magma Formation: Magma is generated deep within the Earth’s crust or upper mantle through processes like partial melting of rocks due to increased temperature, pressure changes, or the addition of volatiles (such as water). The composition of the magma depends on the source rocks and the degree of partial melting.
  2. Intrusion or Extrusion: Depending on whether the magma remains underground or reaches the Earth’s surface, it can form intrusive or extrusive igneous rocks, respectively.
    • Intrusive Igneous Rocks: When magma cools and solidifies beneath the Earth’s surface, it forms intrusive igneous rocks. This process is typically slower, allowing for the growth of larger mineral crystals. Common intrusive rocks include granite, diorite, and gabbro.
    • Extrusive Igneous Rocks: Magma that erupts onto the Earth’s surface as lava cools rapidly due to exposure to lower temperatures and air or water. This rapid cooling results in the formation of smaller mineral crystals or even glassy textures. Common extrusive rocks include basalt, andesite, and rhyolite.
  3. Mineral Crystallization: As the magma cools, the minerals within it begin to crystallize according to Bowen’s Reaction Series. The specific minerals that form depend on the magma’s composition and cooling rate.
  4. Texture and Composition: The texture and composition of the resulting igneous rocks are determined by the cooling rate and the minerals that crystallize. For example, rocks with large crystals are termed “phaneitic,” while those with fine-grained textures are “aphanitic.”

In summary, Bowen’s Reaction Series is essential for understanding the sequence of mineral crystallization during the formation of igneous rocks. It provides valuable insights into the cooling history and composition of these rocks, which, in turn, helps geologists interpret geological processes and make practical applications in various fields.

Phases of Bowen’s Reaction Series

Bowen’s Reaction Series outlines the sequence in which minerals crystallize from a cooling magma. It is divided into two main branches: the discontinuous branch and the continuous branch. Here, I’ll explain the phases of Bowen’s Reaction Series within each of these branches:

Discontinuous Branch (Series of Discontinuous Reactions):

This branch of the reaction series describes the crystallization sequence of specific minerals as temperature decreases. It consists of two phases:

  1. Olivine Phase: Olivine is the first mineral to crystallize from a cooling magma. It forms at the highest temperatures within the discontinuous branch. Olivine is a greenish to yellowish mineral composed mainly of iron and magnesium silicate.
  2. Pyroxene Amphibole Biotite Phase: This phase is characterized by the successive crystallization of pyroxene, amphibole, and biotite mica as the magma continues to cool. Pyroxenes and amphiboles are typically dark-colored minerals, while biotite is a dark mica mineral. The order of crystallization within this phase may vary depending on the specific composition of the magma.

Continuous Branch (Series of Continuous Reactions):

The continuous branch describes the sequence of minerals that form as temperature decreases in a more gradual and continuous manner. It doesn’t involve discrete phases like the discontinuous branch but represents a gradual transition. The key minerals in this branch include:

  1. Feldspar Phase: The continuous branch begins with the crystallization of calcium-rich plagioclase feldspar (anorthite) at higher temperatures. As the temperature decreases, plagioclase feldspar compositions change to more sodium-rich varieties (bytownite, labradorite, andesine, and oligoclase).
  2. Feldspar-Alkali Feldspar Phase: As the temperature continues to decrease, sodium-rich plagioclase feldspars transition into potassium feldspar (orthoclase and microcline), which has a higher temperature of crystallization compared to plagioclase.
  3. Quartz Phase: At the lowest temperatures within the continuous branch, quartz begins to crystallize. Quartz is composed of silicon and oxygen and is typically a clear or milky-white mineral.

It’s important to note that the order of crystallization within the continuous branch is based on idealized conditions and can vary depending on factors such as magma composition, pressure, and cooling rate. Additionally, not all minerals in Bowen’s Reaction Series are present in every igneous rock; their presence depends on the specific conditions of magma crystallization.

In summary, Bowen’s Reaction Series consists of two main branches: the discontinuous branch, with phases including olivine, pyroxene, amphibole, and biotite; and the continuous branch, with a gradual transition from plagioclase feldspar to alkali feldspar to quartz. These phases represent the sequence in which minerals crystallize from a cooling magma, providing valuable insights into the formation and composition of igneous rocks.

How Crystallization Occurs

Crystallization within Bowen’s Reaction Series occurs as a result of the cooling of molten rock (magma). Bowen’s Reaction Series describes the order in which minerals crystallize from magma as it cools. Here’s how crystallization occurs within this context:

  1. Magma Formation: The process begins when molten rock, known as magma, is generated beneath the Earth’s surface. Magma forms through various geological processes such as partial melting of rocks within the Earth’s mantle or crust. The composition of the initial magma depends on the source rocks and the specific geological conditions.
  2. Temperature Decrease: As the magma rises towards the Earth’s surface or cools due to changes in its surroundings, its temperature gradually decreases. The rate of cooling can vary, and this cooling process is central to the crystallization of minerals.
  3. Mineral Nucleation: The first step in crystallization involves the nucleation of tiny crystal nuclei. These nuclei can form spontaneously within the magma (homogeneous nucleation) or on pre-existing solid surfaces or foreign particles (heterogeneous nucleation).
  4. Crystal Growth: Once nuclei form, they serve as the starting points for the growth of crystals. Atoms, ions, or molecules from the magma attach themselves to the crystal nuclei, gradually building the crystal lattice structure.
  5. Crystallization Sequence: Bowen’s Reaction Series outlines the specific order in which minerals crystallize as the magma cools. In the discontinuous branch of the series, minerals such as olivine, pyroxene, amphibole, and biotite crystallize at distinct temperature intervals. In the continuous branch, minerals like plagioclase feldspar, alkali feldspar, and quartz form gradually as temperature decreases. The sequence depends on the composition of the magma.
  6. Mineral Attachment: Each mineral has a specific crystallization temperature, and minerals attach to the growing crystals in a particular sequence dictated by Bowen’s Reaction Series. For example, olivine typically forms at the highest temperatures, followed by pyroxene and so on in the discontinuous branch.
  7. Crystal Size and Texture: The size and texture of the resulting crystals depend on factors such as cooling rate, pressure, and the specific mineral composition of the magma. Slow cooling typically allows for the formation of larger crystals, while rapid cooling results in smaller crystals or even a glassy texture.
  8. Rock Formation: As minerals continue to crystallize and grow, they eventually form an igneous rock. The mineral composition of this rock reflects the sequence in which minerals crystallized from the original magma. For example, if the magma is rich in feldspar and quartz, it may lead to the formation of a granite rock, whereas a mafic magma rich in pyroxene and olivine may produce basalt.

In summary, crystallization within Bowen’s Reaction Series is a fundamental process in the formation of igneous rocks. It involves the cooling and solidification of magma, with minerals crystallizing in a specific sequence determined by their respective crystallization temperatures. This sequence provides valuable insights into the mineral composition and cooling history of igneous rocks.

The Role of Mineral Composition

The mineral composition is a central concept in Bowen’s Reaction Series, as it helps us understand how and why different minerals form in igneous rocks as they cool from molten magma. The mineral composition plays several key roles in this context:

  1. Sequence of Mineral Crystallization: Bowen’s Reaction Series is essentially a sequence that shows the order in which minerals crystallize from a cooling magma. The specific minerals that crystallize depend on the composition of the magma and its temperature. The series helps geologists predict which minerals are likely to form first and last as the magma cools. This sequence is crucial for understanding the formation of igneous rocks.
  2. Identification of Rock Types: By examining the mineral composition of an igneous rock, geologists can determine its likely position in Bowen’s Reaction Series. For example, rocks rich in feldspar and quartz are typically classified as felsic, while those with more mafic minerals like pyroxene and olivine are categorized as mafic. This classification provides insight into the rock’s cooling history, source magma, and geological context.
  3. Temperature History: The mineral composition of an igneous rock can be used to estimate the temperature at which it formed. This is because the minerals that crystallize at higher temperatures are found at the top of the series, while those forming at lower temperatures are at the bottom. By examining the minerals present and their arrangement, geologists can infer the cooling history of the rock.
  4. Insights into Geological Processes: Bowen’s Reaction Series provides insights into the geological processes that shape the Earth’s crust. For example, understanding the sequence of mineral crystallization can help geologists interpret the tectonic and volcanic history of an area. It can also shed light on the differentiation of magmas and the formation of various rock types.
  5. Resource Exploration: The knowledge of mineral composition is valuable for resource exploration. Certain minerals are associated with specific geological environments and may indicate the presence of valuable resources like ores. Geologists use mineral composition to identify and assess the economic potential of mineral deposits.
  6. Volcanic Behavior: The mineral composition of volcanic rocks influences their behavior during eruptions. Felsic rocks, with their higher silica content, tend to produce more explosive eruptions, while mafic rocks, with lower silica content, lead to more effusive eruptions. Understanding the mineral composition helps in predicting volcanic hazards.

In summary, the mineral composition is fundamental in Bowen’s Reaction Series as it guides our understanding of how and why different minerals crystallize in igneous rocks during cooling. This knowledge is essential for classifying rocks, interpreting geological processes, estimating temperature histories, and making practical applications in fields like resource exploration and volcanic hazard assessment.

Practical Applications

Bowen’s Reaction Series and an understanding of mineral composition have several practical applications in the fields of petrology and rock classification, geothermal energy exploration, and economic geology and mineral resources:

1. Petrology and Rock Classification:

  • Identification of Rock Types: Geologists use knowledge of Bowen’s Reaction Series and mineral composition to identify and classify rocks. This classification is critical for interpreting the geological history of an area and understanding the conditions under which rocks formed.
  • Crystallization History: Analyzing the mineral composition of rocks helps reconstruct their crystallization history. This information aids in deciphering geological processes, such as magma cooling rates and differentiation.
  • Geological Mapping: When mapping geological formations, the recognition of specific minerals and their arrangement can assist geologists in delineating different rock units and understanding the relationships between them.

2. Geothermal Energy Exploration:

  • Temperature Estimation: Geothermal energy exploration relies on understanding subsurface temperatures. Knowledge of the sequence of mineral crystallization in Bowen’s Reaction Series helps estimate the temperature gradient in the Earth’s crust. This, in turn, helps identify areas with the potential for geothermal energy extraction.
  • Reservoir Characterization: Geothermal reservoirs often consist of fractured rocks with specific mineral compositions. By analyzing the mineralogy of rocks in potential geothermal areas, geologists can better characterize the reservoir’s properties and potential productivity.

3. Economic Geology and Mineral Resources:

  • Ore Deposit Identification: Understanding the sequence of mineral crystallization is crucial for identifying ore deposits. Specific minerals are associated with valuable resources like metals (e.g., copper, gold, and silver) and industrial minerals (e.g., talc and kaolin). Economic geologists use this knowledge to locate and assess the economic potential of mineral deposits.
  • Exploration and Mining: When exploring for mineral resources, geologists examine rock and mineral compositions to pinpoint areas with elevated concentrations of valuable minerals. This information guides the development of mining operations and mineral extraction techniques.
  • Resource Management: Knowledge of mineral composition is essential for sustainable resource management. It helps ensure efficient extraction, minimize environmental impact, and assess the economic viability of mining projects.

In summary, Bowen’s Reaction Series and an understanding of mineral composition have a broad range of practical applications in geology and related fields. They aid in rock classification, geological mapping, geothermal energy exploration, the identification of valuable mineral resources, and the responsible management of Earth’s geological assets. These applications contribute to our understanding of the Earth’s subsurface and its utilization for energy, mineral resources, and scientific research.

Summary of Key Points

Bowen’s Reaction Series is a critical concept in geology that describes the sequence in which minerals crystallize from a cooling magma. It is divided into two main branches: the discontinuous branch and the continuous branch.

Discontinuous Branch:

  • Involves the crystallization of specific minerals at distinct temperature intervals.
  • Begins with olivine and proceeds through pyroxene, amphibole, and biotite.
  • The order of crystallization depends on the composition of the magma.

Continuous Branch:

  • Represents minerals that form continuously as temperature decreases.
  • Begins with calcium-rich plagioclase feldspar and transitions to sodium-rich plagioclase feldspar, alkali feldspar, and quartz.
  • The sequence is influenced by the composition of the magma.

Importance of Bowen’s Reaction Series in Geology:

  1. Rock Classification: It helps geologists identify and classify igneous rocks based on their mineral composition. This classification provides insights into the rocks’ cooling history, geological context, and tectonic processes.
  2. Temperature Estimation: Bowen’s Reaction Series allows geologists to estimate the temperature at which a particular rock or mineral crystallized. This information aids in reconstructing the geological history of an area.
  3. Geological Processes: Understanding the sequence of mineral crystallization provides insights into geological processes such as magma cooling, differentiation, and the formation of various rock types. It contributes to our understanding of plate tectonics and volcanic behavior.
  4. Resource Exploration: Knowledge of mineral composition is crucial in economic geology for identifying and assessing the economic potential of mineral deposits. It guides exploration efforts and mining operations.
  5. Geothermal Energy: Bowen’s Reaction Series helps estimate subsurface temperatures, aiding in the exploration and development of geothermal energy resources.
  6. Environmental Geology: It has applications in environmental geology by providing insights into groundwater and soil chemistry, helping assess water quality, and understanding environmental impacts related to mineral composition.
  7. Education and Research: Bowen’s Reaction Series is a fundamental concept in geology education and research. It forms the basis for understanding the formation of igneous rocks and their mineralogical characteristics.

In conclusion, Bowen’s Reaction Series is a foundational concept in geology with far-reaching implications. It enhances our understanding of Earth’s geological history, processes, and the formation of igneous rocks. Its applications span various fields, from rock classification and resource exploration to environmental and energy-related studies, making it an indispensable tool for geologists and Earth scientists.

Who is Norman L. Bowen ?

Norman Levi Bowen (1887-1956) was a Canadian geologist renowned for his significant contributions to the field of petrology and the study of igneous rocks. He is best known for developing Bowen’s Reaction Series, a fundamental concept in geology that describes the sequence in which minerals crystallize from a cooling magma. This concept revolutionized the understanding of the formation of igneous rocks and the processes occurring within the Earth’s crust.

Bowen conducted his groundbreaking research during the early 20th century, primarily while working at the Geophysical Laboratory of the Carnegie Institution for Science in Washington, D.C. His work, published in various scientific papers and his book “The Evolution of the Igneous Rocks,” laid the foundation for modern petrology and greatly influenced the study of rock formation, mineralogy, and geological processes.

Bowen’s Reaction Series, named in his honor, remains a fundamental framework in geology and is used extensively to classify and interpret igneous rocks, understand their cooling histories, and gain insights into geological processes, such as plate tectonics and volcanism.

Norman L. Bowen’s contributions to the field of geology have had a lasting impact on the way geologists and scientists understand the Earth’s crust, igneous rock formation, and the mineralogical processes that shape our planet.

The Rock Cycle

The rock cycle is a natural process that describes how rocks are formed, broken down, and transformed into different types of rocks over time. It involves various geological processes such as weathering, erosion, deposition, compaction, cementation, melting, crystallization, and uplift. The rock cycle is a continuous process that occurs over millions of years and is driven by the Earth’s internal heat, tectonic activity, and external factors such as weather and climate.

Diagram describing the rock cycle

Rock Cycle Processes

Igneous Rock Cycle Process

When rocks are pushed deep under the surface, they can melt into magma. If the conditions for the magma to remain liquid are no longer present, they are cooled and incorporated into an igneous rock. A rock that cools in the earth is called intrusive or plutonic, and it cools very slowly to produce a coarse-grained texture, such as rock granite. As a result of volcanic activity, the magma (called lava when it reaches the Earth’s surface), which is called extruded or volcanic rocks, can cool down very quickly while on the surface where the Earth is exposed to the atmosphere. These rocks are fine grained and sometimes so fast that no crystals form and do not result in a natural glass like obsidian, but the most common fine grained rock is known as basalt. Any of the three main rock types (igneous, sedimentary and metamorphic rocks) can melt into magma and cool down to igneous rocks.

Crystallization: The magma cools underground or on the surface and cures to a rickety rock. As the magma cools, different crystals form at different temperatures that undergo crystallization. For example, mineral olivine crystallizes at temperatures much higher than quartz than magma. The cooling rate determines how much time the crystals must form. Slow cooling produces larger crystals.

Rock Cycle
the rock cycle diagram

Metamorphic Rock Cycle Process

Metamorphic rocks can be changed physically or chemically to form a different rock under the high pressures and temperatures. Regional metamorphism refers to effects on large rock masses over a large area, usually associated with mountain formation events in orogenic belts. These rocks exhibit different bands of different mineralogy and colors, often called foliation. Another main type of metamorphism occurs when a rock mass comes into contact with an igneous intrusion that heats up this surrounding country rock. This contact metamorphism results in an over temperature of the magma and / or a rock which is altered and recrystallized by the addition of liquids that add chemical material (metasomatism) to the surrounding rock. Any pre-existing rock species can be replaced by metamorphism processes.

Metamorphism: When a rock is exposed to extreme heat and pressure within the Earth but does not melt, the rock becomes metamorphosed. Metamorphism can change the mineral composition and the texture of the rock. Thus, a metamorphic rock can be a new mineral composition and / or texture.

the rock cycle diagram

Sedimentary Rock Cycle Process

Rocks exposed to the atmosphere are variably unstable and subject to weathering and erosion. Abrasion and erosion break down the original rock into smaller pieces and remove dissolved materials. This shredded material accumulates and is embedded by additional material. While an individual sandstone is still a member of the rock class from which it is formed, it is a rock sediment composed of mixed grains. Sedimentary rocks may consist of collection of these small fragments (plastic clastic rock), accumulation and lithification of living organisms, or removal of mineral sediment from biologically deposited material. evaporation (sedimentary sedimentary rock). Due to processes such as plant residues, such as elastic or organic material, frangible fractions may form from fragments separated from larger rocks of any species. Biogenic and sedimentary rocks consist of accumulation of minerals from dissolved chemicals from all other rock types.

Erosion and Sedimentation: Attrition, rock glides into smaller pieces on the surface of the Earth. Small pieces are called sediments. Flowing water, ice and gravity transport these deposits from one place to another by erosion. During sedimentation, sediments are laid or deposited. In order to form a sedimentary rock, the accumulated sediment must be compacted and cemented together.

The Rock Cycle Chart
The Rock Cycle Chart

Several processes can turn one type of rock into another type of rock. The key processes of the rock cycle are crystallization, erosion and sedimentation, and metamorphism.

Where does the energy that drives Earth’s rock cycle come from? Processes driven by heat from Earth’s interior are responsible for creating igneous and metamorphic rocks. Weathering and erosion, external processes powered by energy from the Sun, produce the sediment from which sedimentary rocks form.

Graphite

Graphite is like diamond, It is a form of native carbon crystalline with its atoms arranged in a hexagonal structure that is opaque and dark gray to black. It occurs as hexagonal crystals, flexible sheets, scales, or large masses. It may be earthy, granular, or compact. Graphite forms from the metamorphism of carbonaceous sediments and the reaction of carbon compounds with hydrothermal solutions. It occurs naturally in this form and is the most stable form of carbon under standard conditions. Under high pressures and temperatures it converts to diamond. It looks dramatically different from diamond and is at the other end of the hardness scale. It’s softness is due to the way carbon atoms are bonded to each other rings of six carbon atoms are arranged in widely spaced horizontal sheets. The atoms are strongly bonded within the rings but very weakly bonded between the sheets. It is used in pencils and lubricants. Its high conductivity makes it useful in electronic products such as electrodes, batteries, and solar panels.

Name: From the Greek to write, in allusion to its use as a crayon.

Association: A wide variety of minerals stable in the metamorphic conditions under which graphite forms. In meteorites, in nodules with troilite, silicates

Polymorphism & Series: Polymorphous with chaoite, diamond, and lonsdaleite.

Chemical Properties

Chemical Classification Native element
Formula C

Graphite Physical Properties

Color Steel gray to black
Streak Black
Luster Metallic, sometimes earthy
Cleavage Perfect in one direction
Diaphaneity Opaque
Mohs Hardness 1 to 2
Crystal System Hexagonal
Tenacity Flexible
Density 2.09 – 2.23 g/cm3 (Measured)    2.26 g/cm3 (Calculated)
Fracture Micaceous

Graphite Optical Properties

Anisotropism Extreme
Color / Pleochroism Strong
Optic Sign Uniaxial (-)
Birefringence extreme birefringence

Graphite Occurrence

It is formed by metamorphism of sedimentary carbonaceous material by reduction of carbon compounds; primary component in igneous rocks. It occurs in metamorphic rocks as a result of the reduction of sedimentary carbon compounds during metamorphic rocks. It is also seen in magmatic rocks and meteorites. It-related minerals are quartz, calcite, mica and tourmaline. China, Mexico, Canada, Brazil and Madagascar are the main export sources of mined.

Synthetic Graphite

Synthetic graphite is a material consisting of graphitic carbon which has been obtained by graphitizing of non-graphitic carbon, by CVD from hydrocarbons at temperatures above 2500 K, by decomposition of thermally unstable carbides or by crystallizing from metal melts supersaturated with carbon.

The term artificial it is often used synonymously with synthetic graphite. However, the term synthetic graphite is preferred since their crystals are thought to be composed of carbon macromolecules. The term synthetic graphite is used predominantly for graphitized carbon, although the term CVD includes pyrolytic graphite as well as carbide decomposition residues. Such common uses are the same as the definition above. Synonyms for this most important type of synthetic graphite are Acheson graphite and electrograph.

Uses Area

  • Natural graphite is mostly used for refractories, batteries, steelmaking, expanded graphite, brake linings, foundry facings and lubricants.
  • Crucibles began using very large flake graphite, and carbon-magnesite brick requiring not quite so large flake graphite; for these and others there is now much more flexibility in the size of flake required, and amorphous graphite is no longer restricted to low-end refractories.
  • The use of graphite in batteries has increased in the last 30 years. Natural and synthetic are used to construct electrodes in major battery technologies.
  • The demand for batteries, As an example, a lithium-ion battery in a fully electric Nissan Leaf contains nearly 40 kg of graphite.
  • Natural graphite in steelmaking mostly goes into raising the carbon content in molten steel, and can also be used to lubricate the dies used to extrude hot steel.
  • Natural amorphous and fine flake graphite are used in brake linings or brake shoes for heavier (nonautomotive) vehicles, and became important with the need to substitute for asbestos.
  • A foundry facing mold wash is a water-based paint of amorphous or fine flake. Painting the inside of a mold with it and letting it dry leaves a fine graphite coat that will ease separation of the object cast after the hot metal has cooled.

Use of synthetic graphite

  • High-focal pyrolytic graphite (HOPG) is the highest quality synthetic form of graphite. In scientific research, it is used as the length standard for scanner calibration, especially on a scanning probe microscope.
  • It electrodes carry electricity that melts scrap iron and steel in electric arc furnaces, the majority of steel furnaces, and sometimes melts directly reduced iron (DRI). They are made from petroleum coke after being mixed with coal tar tar.
  • Electrolytic aluminum smelting also uses graphite carbon electrodes. On a much smaller scale, synthetic discharge electrodes are used to make injection molds for plastics in the electrical discharge process (EDM).
  • Special grades of synthetic graphite, such as gilsocarbon, find utility as a matrix and neutron moderator in nuclear reactors. The low neutron cross section also recommends the use in recommended fusion reactors.
  • It (carbon) fiber and carbon nanotubes are also used in carbon fiber reinforced plastics and heat-resistant composites such as reinforced carbon-carbon (RCC). Commercial structures made of carbon fiber graphite composites include fishing rods, golf club shafts, bicycle frames, sports car body panels, the body of the Boeing 787 Dreamliner and the body of the pool marker bars.
  • Modern smokeless powder is coated with graphite to prevent the accumulation of static charge.
  • It was used in at least three radar absorbing materials. Sumpf and Schornsteinfeger used in U-boat snorkels to reduce radar cross-sections were mixed with rubber. F-117 Nighthawk was also used on the tiles on the secret strike fighters.
  • Graphite composites are used as absorbers for high energy particles (eg, in the LHC beam dump).

Graphite recycling

The most common way of graphite recycling occurs when synthetic graphite electrodes are produced and cut into pieces or discard lathes, or when the electrode (or other) is used up to the electrode holder. A new electrode replaces the old one, but most of the old one remains. This is crushed and sized and the resulting graphite powder is mostly used to increase the carbon content of the molten steel. It-containing refractories are sometimes recycled, but often not because of graphite: the largest bulk materials such as carbon-magnesite bricks containing only 15-25% graphite often contain very little graphite. However, some recycled carbon-magnesite bricks are used as the basis for furnace repair materials, while broken carbon-magnesite bricks are used in slag air conditioners. The crucibles have a high graphite content, while the crucibles used and then recycled have a small volume.

A high quality flake graphite product very similar to natural leaf graphite can be made from steelmaking. Kish is a large volume of molten waste filtered from the molten iron feed into a basic oxygen furnace and consists of a mixture of graphite (precipitated from supersaturated iron), lime-rich slag and some iron. The iron is recycled in place and a mixture of graphite and slag is left. The best recovery process uses hydraulic grading (using water flow to separate minerals by specific gravity: graphite is light and almost precipitates) to obtain a 70% graphite concentrate. Leaching of this concentrate with hydrochloric acid yields a 95% graphite product with a flake size down to 10 sieves.

Distribution

Numerous localities, but only a few afford well-crystallized examples.

  • In the USA, at Monroe and Ticonderoga, Essex Co., New York; at Franklin and Sterling Hill, Ogdensburg, Sussex Co., New Jersey.
  • In Canada, commercially significant occurrences in Quebec, at Buckingham and Grenville, and in adjacent parts of Ontario.
  • In Russia, from Nizhni Tunguski, east of Turukhansk, near the Yenisei River, Siberia; at Shunga, Karelia.
  • Around Ratnapura, Matara, and Kurunegale, Sri Lanka, large deposits of pure material.
  • At Passau, Bavaria, Germany.
  • From Pargas, Finland.
  • In England, at Barrowdale, near Keswick, Cumbria.
  • In Mexico, at Santa Maria, Sonora, formed by metamorphism of coal beds.

References

  • Bonewitz, R. (2012). Rocks and minerals. 2nd ed. London: DK Publishing.
  • Handbookofmineralogy.org. (2019). Handbook of Mineralogy. [online] Available at: http://www.handbookofmineralogy.org [Accessed 4 Mar. 2019].
  • Mindat.org. (2019). Graphite: Mineral information, data and localities.. [online] Available at: https://www.mindat.org/ [Accessed. 2019].
  • Smith.edu. (2019). Geosciences | Smith College. [online] Available at: https://www.smith.edu/academics/geosciences [Accessed 15 Mar. 2019].

Hornblende

Hornblende is a inosilicate amphibole minerals, which are two type hornblende minerals. They are ferrohornblende and magnesiohornblende. They are an isomorphous mixture of three molecules; a calcium-iron-magnesium silicate, an aluminium-iron-magnesium silicate, and an iron-magnesium silicate.The name hornblende is applied to a group of minerals that can be distinguished from each other only by detailed chemical analysis. The two end-member hornblendes—iron-rich ferrohornblende and magnesiumrich magnesiohornblende—are both calcium-rich and monoclinic in crystal structure. Other elements, such as chromium, titanium, and nickel, can also appear in the crystal structures of the group. The concentrations of these elements are an indicator of the metamorphic grade of the mineral. Specimens are green, dark green, or brownish green to black in color. Crystals are usually bladed and unterminated, and they often show a pseudohexagonal cross section. Well-formed crystals are short to long prisms. They also occurs as cleavable masses and radiating groups. The mineral forms in metamorphic rocks, especially gneisses, hornblende schists, amphibolites, and magnesium- and iron-rich igneous rocks.

Name: The word it is derived from the German horn and blenden, to ‘deceive’ in allusion to its similarity in appearance to metal-bearing ore minerals.

Ferro-hornblende Association: Hedenbergite (granite); biotite, epidote, albite, quartz (amphibolite)

Magnesio-hornblende: Quartz, orthoclase, plagioclase, biotite, magnetite, apatite (granite).

Polymorphism & Series: Forms a series with magnesiohornblende (Magnesio-hornblende). Forms a series with ferrohornblende (Ferro-hornblende)

Mineral Group: Amphibole supergroup

Chemical Properties

Chemical Classification Silicate mineral
General Formula (Ca,Na)2–3(Mg,Fe,Al)5(Al,Si)8O22(OH,F)2.
Ferro-hornblende {Ca2}{Fe2+4Al}(AlSi7O22)(OH)2
Magnesio-hornblende {Ca2}{Mg4Al}(AlSi7O22)(OH)2
Common Impurities Ti,Mn,Na,K

Hornblende Physical Properties

Color Usually black, dark green, dark brown
Streak White, colorless – (brittle, often leaves cleavage debris behind instead of a streak)
Luster Vitreous
Cleavage Two directions intersecting at 124 and 56 degrees
Diaphaneity Translucent to nearly opaque
Mohs Hardness 5 to 6
Crystal System Monoclinic

Ferro-hornblende Optical Properties

Color / Pleochroism Pleochroic in various shades of green and brown.  In PPL a thin section of Hornblende ranges from yellow -green to dark brown. Green varieties usually have X= light yellow green, Y=green or grey-green and Z=dark green. Brownish varieties have X=greenish-yelow/brown, Y=yellowish to reddish brown and Z=grey to dark brown.
2V: Measured: 12° to 76°, Calculated: 30° to 62°
RI values: nα = 1.687 – 1.694 nβ = 1.700 – 1.707 nγ = 1.701 – 1.712
Optic Sign Biaxial (-)
Birefringence δ = 0.014 – 0.018
Relief High
Dispersion: r > v or r < v
Extinction Symmetrical to cleavages
Distinguishing Features          Cleavages at 56 and 124 degrees which form a distinctive diamond shape in cross section.  Hornblende is easly confused with biotite.  Distiguishing factors are the lack of birds eye extinction and the two distinct cleavages.  Simple twinning is relatively common. Crystal habit and cleavage distinguish hornblende from dark-colored pyroxenes.

Magnesio-hornblende Optical Properties

Color / Pleochroism Pleochroic in various shades of green and brown.  In PPL a thin section of Hornblende ranges from yellow -green to dark brown. Green varieties usually have X= light yellow green, Y=green or grey-green and Z=dark green. Brownish varieties have X=greenish-yelow/brown, Y=yellowish to reddish brown and Z=grey to dark brown.
2V: Measured: 66° to 85°, Calculated: 58° to 88°
RI values: nα = 1.616 – 1.680 nβ = 1.626 – 1.695 nγ = 1.636 – 1.700
Optic Sign Biaxial (-)
Birefringence δ = 0.020
Relief Moderate
Dispersion: r > v or r < v
Extinction Symmetrical to cleavages
Distinguishing Features          Cleavages at 56 and 124 degrees which form a distinctive diamond shape in cross section.  Hornblende is easly confused with biotite.  Distiguishing factors are the lack of birds eye extinction and the two distinct cleavages.  Simple twinning is relatively common. Crystal habit and cleavage distinguish hornblende from dark-colored pyroxenes.

Occurrence of Hornblende

It is a common component of many magmatic and metamorphic rocks such as granite, syenite, diorite, gabbro, basalt, andesite, gneiss and schist.

It is the main mineral of amphibolites. Very dark brown to black hornblendes containing titanium are normally called basaltic hornblendes, as they are usually a component of basalt and related rocks. Hornblende easily replaces chlorite and epidote.

A rare kind of hornblende contains less than 5% of iron oxide, is gray to white in color and Edenite is named Edenite from Orange County, New York.

Magnesio-hornblende Occurrence: Common in amphibolites, schists, and pegmatitic alkalic gabbro. Also from welded tu®s, granodiorites, granites, and tonalites.

Ferro-hornblende Occurrence: From granites, granodiorites, and metabasalts; common in amphibolites and schists. As reaction rims on ferroan hedenbergite.

Uses Area

It is the most abundant mineral in a rock known as amphibolite, which has numerous uses.

  • Crushed and used as road construction and railway ballast.
  • It was cut to be used as a dimension stone.
  • The highest quality pieces are cut, polished and sold under the name “black granite” for use as building facades, floor tiles, countertops and other architectural uses.
  • It was used to estimate the depth of crystallization of plutonic rocks. Those with low aluminum content are associated with crystallization at shallow depth, while those with high aluminum content are associated with greater crystallization depths. This information is also useful for understanding the crystallization of magma and for mineral research.

Distribution

Magnesio-hornblende

Very widespread. A few conrmed localities include:

  • at Vesuvius and Monte Somma, Campania, Italy.
  • In the granitic batholiths of the Scottish Highlands; Swiss and Italian Alps; Harz Mountains, Germany; Finland and Sweden.
  • In the Southern California and Sierra Nevada batholiths, California, USA.
  • Widespread in Japan.

Ferro-hornblende

Very widespread, but many locality references lack qualifying chemical analyses. A few historic localities for well-crystallized material include:

  • at Monte Somma and Vesuvius, Campania, Italy.
  • From Pargas, Finland.
  • At KragerÄo, Arendal, and around the Langesundsfjord, Norway.
  • From Blina and Schima, Czech Republic.
  • In the USA, from Franklin and Sterling Hill, Ogdensburg, Sussex Co., New Jersey; from Edwards, Pierrepont, and Gouverneur, St. Lawrence Co., New York.
  • From Bancroft, Pakenham, and Eganville, Ontario, Canada.
  • From Broken Hill, New South Wales, Australia.

References

  • Bonewitz, R. (2012). Rocks and minerals. 2nd ed. London: DK Publishing.
  • Handbookofmineralogy.org. (2019). Handbook of Mineralogy. [online] Available at: http://www.handbookofmineralogy.org [Accessed 4 Mar. 2019].
  • Mindat.org. (2019). Orpiment: Mineral information, data and localities.. [online] Available at: https://www.mindat.org/ [Accessed. 2019].
  • Smith.edu. (2019). Geosciences | Smith College. [online] Available at: https://www.smith.edu/academics/geosciences [Accessed 15 Mar. 2019].

10 Most Powerful Earthquakes in Earth History

Earthquakes are one of the most powerful and destructive natural phenomena that occur on our planet. They can cause widespread devastation, loss of life, and economic damage, making them a significant threat to human societies. Throughout history, the earth has experienced many powerful earthquakes that have left a lasting impact on the affected regions. These seismic events can vary in magnitude, with the most severe earthquakes reaching levels that are hard to comprehend. In this article, we will explore the ten most powerful earthquakes ever recorded in Earth’s history, examining their causes, impacts, and the lessons learned from these catastrophic events. Understanding the power and impact of these earthquakes can help us prepare for and mitigate the damage caused by future seismic events.


10. The 2012 Indian Ocean earthquakes

Sumatra earthquake from pics(http://www.abc.net.au/news/2007-09-14/sumatra-earthquake/292416)
Sumatra earthquake (2012)

11 April ,2012 at 15.38 local time, Indian Ocean earthquakes were magnitude 8.6 undersea that near of Indonesian city of Aceh. Authorities were at tsunami call but subsequently cancelled .These were unusually strong intraplate earthquakes and the largest strike-slip earthquake ever recorded.

it occurred very remote from an inhabited place and produced no destructive tsunami (10 cm to 0.8 meter / 3.9 inches to 31.4 inches tsunamis were reported). 10 deaths and 12 injuries were reported – most of them caused by panic and/or heart attack.


9. Assam-Tibet Earthquake (1950) – 8.6

Assam-Tibet Earthquake
Assam-Tibet Earthquake(1950)

On August 15, 1950, Earthquake occured at Xizang-India border region and epicenter of earthquake located near Rima,Tibet, Result of earthquakes many buildings were destroyed and between 1.500 and 3.000 peaple were killed.

After the earthquake, large landslides blocked the Subansiri River. This natural dam broke 8 days later, creating a wave of 7 m (23 ft) high which inundated several villages and killed 536 people.

The earthquake also created around 5,000,000 homeless.


8. Rat Islands Earthquake(1965) – 8.7

1965 Rat Islands earthquake is located in Alaska

The Rat Islands earthquake of 1965 was a powerful earthquake that occurred on February 4, 1965, in the Rat Islands region of Alaska. The earthquake had a magnitude of 8.7, making it one of the most powerful earthquakes ever recorded.

The earthquake was caused by the subduction of the Pacific Plate beneath the North American Plate, which resulted in significant movement along the boundary between the two plates. The earthquake triggered a large tsunami that caused significant damage in several communities in Alaska, Hawaii, and California. However, due to the remote location of the epicenter and the low population density in the affected areas, the number of casualties was limited.

The Rat Islands earthquake was significant because it demonstrated the potential for large earthquakes to occur in remote areas, where they may not be detected immediately. It also highlighted the importance of early warning systems and the need for preparedness measures in coastal areas vulnerable to tsunamis.


7. Ecuador-Colombia Earthquake(1906)– 8.8

The Ecuador-Colombia earthquake of 1906 was a powerful earthquake that occurred on January 31, 1906, along the border between Ecuador and Colombia. The earthquake had a magnitude of 8.8, making it one of the most powerful earthquakes ever recorded.

The earthquake caused significant damage and destruction in the affected areas, with many buildings being destroyed and landslides blocking roads and transportation routes. The death toll from the earthquake is estimated to be around 1,000 people, with many more injured or displaced.

The Ecuador-Colombia earthquake was caused by the movement of the South American Plate as it collided with the Nazca Plate, which resulted in significant movement along the boundary between the two plates. The earthquake triggered several aftershocks, and the effects were felt throughout the region.


6. Maule (Chile) Earthquake (2010)– 8.8

pics from http://www.scmp.com/news/world/article/1571468/massive-chilean-earthquake-2010-shook-antarctic-ice-sheet

2010 Maule Earthquake, also known as the 2010 Chile earthquake has occurred off the coast of central Chile on Saturday, 27 February at 03:34 local time (06:34 UTC) about 3 km (1.9 miles) off the coast of Pelluhue commune in the Maule Region, Chile. The intense shaking lasted for about three minutes. Several coastal towns in south-central Chile were devastated by the tsunami triggered by the earthquake. The tsunami also damaged the port at Talcahuano.

Buildings collapsed in many cities, including the capital, Santiago, causing many deaths. The authorities announced the final death toll of 525 victims and 25 people missing in January 2011.


5. Kamchatka, Russia Earthquake (1952) – 9.0

1952 Kamchatka Tsunami

On November 4, 1952, at 16:58 GMT (04:58 local time) a huge earthquake struck off the coast of Kamchatka Peninsula, in the far east of Russia. It produced a great destructive Pacific-wide tsunami with waves up to 15 meters (50 feet) which caused extensive damage to the Kamchatka Peninsula and the Kuril Islands, left an estimated 10,000 to 15,000 people dead. It was also very damaging in the Hawaiian Islands, but there were no human deaths attributed to the tsunami. The waves traveled as far as Peru, Chile and New Zealand. In Alaska, the Aleutian Islands and California, tsunami waves of up to 1.4 meters (4.6 feet) were observed.


4. Tōhoku Earthquake (2011) – 9.1

Tōhoku Earthquake
Japan’s devastating 8.9 magnitude earthquake in 2011 is continuing to cause problems, with seismologists calling the county’s most recent quake an ‘aftershock’. (Reuters)

On 11 March 2011 Friday, at 14:46 with the local time (05:46 UTC), a massive undersea megathrust earthquake off the coast of Japan occurred. The earthquake triggered a massive tsunami with waves up to 40.5 meters (133 feet) high. It was one of the deadliest in human history, the waves traveled inland as far as 6 miles (10 km) and caused extensive and severe structural damage in north-eastern Japan. Airports, roads and railroads destroyed, 127,290 buildings totally collapsed, 272,788 buildings half collapsed, and another 747,989 buildings partially damaged. A dam collapsed. The tsunami also caused nuclear accidents, primarily the level 7 meltdowns (means a Major accident, highest level, see notes 2) at three reactors in the Fukushima Daiichi Nuclear Power Plant complex.

On 10 March 2015, it was announced that the confirmed casualties were 15,894 deaths, 6,152 injured, and 2,562 people missing.


3. Sumatra Earthquake (2004)– 9.1

One of the deadliest natural disasters in recent history, the 2004 Sumatra Earthquake, also known as the 2004 Indian Ocean earthquake, occurred at 00:58:53 UTC on 26 December with the epicenter off the west coast of Sumatra, Indonesia. It ruptured the greatest fault length of any recorded earthquake, spanning a distance of 1500 km (900 miles). The resulting tsunami, with waves up to 30 meters (100 ft) high, caused up to a quarter of a million deaths.

2004 Indian Ocean earthquake and tsunami

The earthquake had also the longest duration of faulting ever observed, between 8.3 and 10 minutes. It caused the entire planet to vibrate as much as 1 centimeter (0.4 inches). Total energy released by the quake was 4.0×1022 joules (4.0×1029 ergs), or 9,600 gigatons of TNT, 550 million times that of Hiroshima atomic bomb. The vast majority of this energy was underground. The energy released on the Earth’s surface was estimated at 1.1×1017 joules or 26 megatons of TNT. This energy is equivalent to over 1,500 times that of the Hiroshima atomic bomb, but less than that of Tsar Bomba, the largest nuclear weapon ever detonated.

The resulting tsunami was given various names, including the 2004 Indian Ocean tsunami, South Asian tsunami, Indonesian tsunami, the Christmas tsunami (there were also hundreds of thousands of Christian tourists in the areas affected by the tsunami), and the Boxing Day tsunami.


2. Great Alaska Earthquake (1964)– 9.2

The 1964 Great Alaska earthquake (also known as Good Friday earthquake) occurred at 5:36 PM (local time, 3:36 UTC) on Good Friday, March 27 in the Prince William Sound region of Alaska. It lasted approximately 4.5 minutes and is the most powerful recorded earthquake in U.S. history.

Great Alaska Earthquake (1964)– 9.2

The earthquake triggered 27-foot (8.2 meters) tsunami which destroyed the village of Chenega, killing 23 of the 68 people who lived there. Survivors out-ran the wave, climbing to high ground. It also caused a massive underwater landslide. Port Valdez city harbor and docks were collapsed, 30 people perished.

A total of 139 people are believed to have died: 15 as a result of the earthquake itself, 106 from the subsequent tsunami in Alaska, 5 from the tsunami in Oregon, and 13 from the tsunami in California


1.  Valdivia Earthquake (1960)– 9.5

Valdivia Earthquake
Valdivia Earthquake from pics(http://santiagotimes.cl/en/wp-content/uploads/2018/05/sanfrancisco-earthquake-1906.png)

Also known as the Great Chilean earthquake (Spanish: Gran terremoto de Chile), it was the most powerful earthquake ever recorded. The earthquake hit on May 22 in the afternoon (19:11 GMT, 15:11 local time), approximately 100 miles (160 km) off the coast of Chile, parallel to the city of Valdivia. It lasted approximately 10 minutes and triggered a massive tsunami with waves up to 25 meters (82 feet). The main tsunami severely battered the Chilean coast, and raced across the Pacific Ocean and devastated Hilo, Hawaii. Waves as high as 10.7 meters (35 feet) were recorded even 10,000 kilometers (6,200 mi) from the epicenter, and as far away as Japan and the Philippines.

The death toll of 1960 Valdivia Earthquake is not certain – the total number of fatalities from the earthquake and tsunamis have been estimated between 1,000 and 6,000. About 3,000 people were injured.

Arsenic

Arsenic is a native element with the formula As and atomic number 33. Known since antiquity, arsenic is widely distributed in nature, although it is unusual in native form. It is classified as a semimetal, because it possesses some properties of metals and some of nonmetals. Crystals are rare, but when found they are rhombohedral. It usually occurs in massive, botryoidal to reniform, or stalactitic habits, often with concentric layers. On fresh surfaces, arsenic is tin-white, but it quickly tarnishes to dark gray. Native arsenic is found in hydrothermal veins, often associated with antimony, silver, cobalt, and nickel-bearing minerals. It is highly poisonous, although it is used in some medicines to treat infections. Arsenic-based compounds can be used in alloys to increase high-temperature strength and as a herbicide and pesticide.

The United States’ Environmental Protection Agency states that all forms of arsenic are a serious risk to human health. The United States’ Agency for Toxic Substances and Disease Registry ranked arsenic as number 1 in its 2001 Priority List of Hazardous Substances at Superfund sites. Arsenic is classified as a Group-A carcinogen. (Wikipedia, 2019)

Name: From the Latin arsenicum, earlier Greek arrenikos, or arsenikos, masculine, an allusion to its potent properties.

Association: Arsenolite, cinnabar, realgar, orpiment, stibnite, galena, sphalerite, pyrite, barite

Polymorphism & Series: Dimorphous with arsenolamprite.

Mineral Group: Arsenic group.

Cell Data: Space Group: R3m (synthetic). a = 3.7598(1) c = 10.5475(2) Z = 6

Morphology: Granular, massive, concentric layered. Reticulated, reniform, stalagtitic, columnar, acicular. small rhombohedra.

Chemical Properties

Chemical Classification Native Element
Formula As
Common Impurities Bi,Sb,Fe,Ni,Ag,S,Se

Arsenic Physical Properties

Color Tin-white, tarnishing to dark grey or black.
Streak Grey
Luster Metallic, Dull
Cleavage Perfect Perfect basal on {0001}, fair on {0114}
Diaphaneity Opaque
Mohs Hardness 3,5
Crystal System Trigonal
Tenacity Brittle
Density 5.63 – 5.78 g/cm3 (Measured)    5.778 g/cm3 (Calculated)
Fracture Irregular/Uneven

Arsenic Optical Properties

Type Anisotropic
Anisotropism Distinct – yellowish brown and light grey to yellowish grey
Color / Pleochroism Weak
Twinning Rare on {1014}, Pressure twinning on {0112}

Occurrence

In hydrothermal veins and deposits that contain other arsenic minerals; may be in Co–Ag sulfide veins.

Arsenic comprises about 1.5 ppm (0.00015%) of the Earth’s crust, and is the 53rd most abundant element. Typical background concentrations do not exceed 3 ng/m3 in the atmosphere; 100 mg/kg in soil; and 10 μg/L in freshwater.

Arsenic Uses Area

  • The toxicity of arsenic to insects, bacteria, and fungi led to its use as a wood preservative
  • It was also used in various agricultural insecticides and poisons. For example, lead hydrogen arsenate was a common insecticide on fruit trees.
  • It is used as a feed additive in poultry and swine production, in particular in the U.S. to increase weight gain, improve feed efficiency, and to prevent disease
  • It is intentionally added to the feed of chickens raised for human consumption. Organic compounds are less toxic than pure arsenic, and promote the growth of chickens. Under some conditions, the arsenic in chicken feed is converted to the toxic inorganic form.
  • Medical use
  • During the 18th, 19th, and 20th centuries, a number of arsenic compounds were used as medicines, including arsphenamine (by Paul Ehrlich) and arsenic trioxide (by Thomas Fowler).
  • Arsenic trioxide has been used in a variety of ways over the past 500 years, most commonly in the treatment of cancer, but in medications as diverse as Fowler’s solution in psoriasis.
  • The main use is in alloying with lead. Lead components in car batteries are strengthened by the presence of a very small percentage of arsenic.
  • Gallium arsenide is an important semiconductor material, used in integrated circuits. Circuits made from GaAs are much faster (but also much more expensive) than those made from silicon.

Distribution

Numerous localities are known, most of only minor interest.

  • In Germany, from Freiberg, Schneeberg, Johanngeorgenstadt, Marienberg, and Annaberg, Saxony; Wolfsberg and St. Andreasberg, Harz Mountains; and Wieden, Black Forest.
  • In the Gabe-Gottes mine, Rauenthal, near Sainte-Marie-aux-Mines, Haut-Rhin, France. At Jachymov (Joachimsthal), Prıbram, and Cınovec (Zinnwald), Czech Republic.
  • In Romania, from Sacarımb (Nagyag), Hunyad, and Cavnic (Kapnikbanya).
  • At Sterling Hill, Ogdensburg, Sussex Co., New Jersey and Washington Camp, Santa Cruz Co., Arizona, USA.
  • In the Huallapon mine, Pasto Bueno, Ancash Province, Peru. At Bidi, Sarawak Province, Borneo.
  • In the Akatani mine, Fukui Prefecture, Japan. From the Dajishan tungsten deposits, Jianxi Province, China.

References

  • Bonewitz, R. (2012). Rocks and minerals. 2nd ed. London: DK Publishing.
  • Handbookofmineralogy.org. (2019). Handbook of Mineralogy. [online] Available at: http://www.handbookofmineralogy.org [Accessed 4 Mar. 2019].
  • Mindat.org. (2019). Orpiment: Mineral information, data and localities.. [online] Available at: https://www.mindat.org/ [Accessed. 2019].
  • Wikipedia contributors. (2019, June 8). Arsenic. In Wikipedia, The Free Encyclopedia. Retrieved 12:08, June 11, 2019, from https://en.wikipedia.org/w/index.php?title=Arsenic&oldid=900851916

Sulfur

Sulfur is the tenth most common element by mass in the universe, and the fifth most common on Earth. It (also spelled sulphur) is a chemical element with the symbol S and atomic number 16. It is abundant, multivalent, and nonmetallic. Under normal conditions, atoms form cyclic octatomic molecules with a chemical formula S8. Elemental sulfur is a bright yellow, crystalline solid at room temperature. It occurs in the form of sulfides, sulfates, and elemental sulfur. The bright yellow or orangish color of this mineral makes the mineral easy to identify. Sulfur forms pyramidal or tabular crystals, encrustations, powdery coatings, and granular or massive aggregates. Crystalline sulfur may exhibit as many as 56 different habits. Most sulfur forms in volcanic fumaroles, but it can also result from the breakdown of sulfide ore deposits. Massive form found in thick beds in sedimentary rocks, particularly those associated with salt domes. Sulfur is a poor conductor of heat, which means that specimens are warm to the touch.

Name: derived from the Latin word sulpur, which was Hellenized to sulphur. The spelling sulfur appears toward the end of the Classical period. (The true Greek word for sulfur, θεῖον, is the source of the international chemical prefix thio-.)

Association: Aragonite, Celestine, Calcite, Stibnite, Gypsum, Baryte, Galena, Anglesite, Quartz, Stibiconite

Member of: Sulphur Group

Morphology: Over 50 forms have been noted, blocky dipyramidal ones most common, also tabular and sphenoidal; also found as powdery coatings, massive material, and in reniform and stalactic forms.

Cell Parameters: a = 10.468 Å, b = 12.870 Å, c = 24.49 Å

Chemical Properties

Chemical Classification Native
Chemical Composition S
Common Impurities Se,Te

Sulfur Physical Properties

Color Yellow, sulphur-yellow, brownish or greenish yellow, orange, white
Streak Colourless
Luster Resinous, Greasy
Cleavage Imperfect/Fair Imperfect on {001}, {110} and {111}.
Diaphaneity Transparent, Translucent
Mohs Hardness 1,5 – 2,5
Crystal System Orthorhombic
Tenacity Brittle
Density 2.07 g/cm3 (Measured)    2.076 g/cm3 (Calculated)
Fracture Irregular/Uneven, Conchoidal
Parting Parting on {111}

Sulfur Optical Properties

Type Anisotropic
Color / Pleochroism Visible
2V: Measured: 68° , Calculated: 70°
RI values: nα = 1.958 nβ = 2.038 nγ = 2.245
Twinning On {101}{011}{110} rare
Optic Sign Biaxial (+)
Birefringence δ = 0.287
Relief Very High
Dispersion: relatively weak r< v

Occurrence

Sulfur is widely distributed in nature. It is found in many minerals and ores, e.g., iron pyrites, galena, cinnabar, zinc blende, gypsum, barite, and epsom salts and in mineral springs and other waters. It is found uncombined in some volcanic regions and in large underground deposits in Sicily and in Texas and Louisiana. Its often occurs with coal, petroleum, and natural gas. It is found in meteorities, and deposits of it may be present near the lunar crater Aristarchus. The distinctive colors of Jupiter’s moon Io are believed to result from forms of molten, solid, and gaseous sulfur. It is a component of all living cells. The amino acids cysteine, methionine, homocysteine, and taurine contain sulfur as do some common enzymes; it is a component of most proteins. Some forms of bacteria use hydrogen sulfide (H 2S) in place of water in a rudimentary photosynthesislike process. It is absorbed by plants from soil as sulfate ions.

Uses Area

  • Elemental sulfur is used mainly as a precursor to other chemicals. Approximately 85% (1989) is converted to sulfuric acid (H2SO4):
  • Large quantities of sulfites are used to bleach paper and to preserve dried fruit. Many surfactants and detergents (e.g. sodium lauryl sulfate) are sulfate derivatives.
  • When silver-based photography was widespread, sodium and ammonium thiosulfate were widely used as “fixing agents”. Sulfur is a component of gunpowder (“black powder”).
  • It is increasingly used as a component of fertilizers. The most important form of sulfur for fertilizer is the mineral calcium sulfate.
  •  It improves the efficiency of other essential plant nutrients, particularly nitrogen and phosphorus.
  • Organosulfur compounds are used in pharmaceuticals, dyestuffs, and agrochemicals. Many drugs contain sulfur; early examples being antibacterial sulfonamides, known as sulfa drugs. It is a part of many bacterial defense molecules.
  • Elemental sulfur is one of the oldest fungicides and pesticides. “Dusting sulfur”, elemental sulfur in powdered form, is a common fungicide for grapes, strawberry, many vegetables and several other crops.
  • Small amounts of sulfur dioxide gas addition (or equivalent potassium metabisulfite addition) to fermented wine to produce traces of sulfurous acid (produced when SO2 reacts with water) and its sulfite salts in the mixture, has been called “the most powerful tool in winemaking”.
  • It (specifically octasulfur, S8) is used in pharmaceutical skin preparations for the treatment of acne and other conditions. It acts as a keratolytic agent and also kills bacteria, fungi, scabies mites, and other parasites.
  • It can be used to create decorative inlays in wooden furniture. After a design has been cut into the wood, molten sulfur is poured in and then scraped away so it is flush.

References

  • Bonewitz, R. (2012). Rocks and minerals. 2nd ed. London: DK Publishing.
  • Handbookofmineralogy.org. (2019). Handbook of Mineralogy. [online] Available at: http://www.handbookofmineralogy.org [Accessed 4 Mar. 2019].
  • Mindat.org. (2019). Orpiment: Mineral information, data and localities.. [online] Available at: https://www.mindat.org/ [Accessed. 2019].
  • Smith.edu. (2019). Geosciences | Smith College. [online] Available at: https://www.smith.edu/academics/geosciences [Accessed 15 Mar. 2019].

Silver

Silver is an element with the chemical symbol Ag and atomic number 47. Opaque and bright silvery white with a slightly pink tint, it readily tarnishes to either gray or black. Natural crystals of silver are uncommon, but when found they are cubic, octahedral, or dodecahedral. It is usually found in granular habit and as wiry, branching, lamellar, or scaly masses. Widely distributed in nature, it is a primary hydrothermal mineral. It also forms by alteration of other silver-bearing minerals. Much of the world’s silver production is a by-product of refining lead, copper, and zinc. It is the second most malleable and ductile metal, and it is important in the photographic and electronic industries. Most silver is produced as a byproduct of copper, gold, lead, and zinc refining. It has long been valued as a precious metal. Silver metal is used in many bullion coins, sometimes alongside gold: while it is more abundant than gold, it is much less abundant as a native metal.

Name: From an Old English word for the metal soelfer, related to the German silber and the Dutch zilver; the chemical symbol from the Latin argentum

Association: Acanthite, chlorargyrite, embolite, silver sulfosalts, gold, copper

Polymorphism & Series: Forms a series with gold; the cubic form is 3C; hexagonal stacking polytypes 2H and 4H are known

Mineral Group: Copper Group

Cell Data: Space Group: Fm3m. a = 4.0862 Z = 4

Morphology: Crystals are cubic, octahedral, dodecahedral to a cm. Often elongated to many cms in herringbone twins and wires (crystals elongated along the [111] axis).

Chemical Properties

Chemical Classification Native – members of Copper Group
Formula Ag
Common Impurities Au,Hg,Cu,Sb,Bi

Silver’s Physical Properties

Color Silver-white, tarnishes dark gray to black
Streak Silver white
Luster Metallic
Cleavage None Observed
Diaphaneity Opaque
Mohs Hardness 2.5-3 on Mohs scale
Crystal System Isometric
Tenacity Malleable
Density 10.1 – 11.1 g/cm3 (Measured)    10.497 g/cm3 (Calculated)
Fracture None observed

It is an extremely soft, ductile and malleable transition metal, though it is slightly less malleable than gold. Crystallizes in a face-centered cubic lattice with bulk coordination number 12, where only the single 5s electron is delocalized, similarly to copper and gold.

It has a brilliant white metallic luster that can take a high polish, and which is so characteristic that the name of the metal itself has become a color name.

Very high electrical and thermal conductivity is common to the elements in group 11, because their single s electron is free and does not interact with the filled d subshell, as such interactions (which occur in the preceding transition metals) lower electron mobility. The electrical conductivity of it is the greatest of all metals, greater even than copper, but it is not widely used for this property because of the higher cost. An exception is in radio-frequency engineering, particularly at VHF and higher frequencies where silver plating improves electrical conductivity because those currents tend to flow on the surface of conductors rather than through the interior.

Silver Optical Properties

Type Isotropic
Color / Pleochroism Non-pleochroic
Color in reflected light Brilliant silver white
Internal Reflections None
Twinning Penetration twins on (111) with cubes from Kongsberg and tetrahexahedrons from Michigan (bearpaws). Arborescent growths twinned on (100) and on (111).

Silver Occurrence

A primary hydrothermal mineral, also formed by secondary processes, especially in the oxidized portions of mineral deposits.

The abundance of silver in the Earth’s crust is 0.08 parts per million, almost exactly the same as that of mercury. It mostly occurs in sulfide ores, especially acanthite and argentite, Ag2S. Argentite deposits sometimes also contain native when they occur in reducing environments, and when in contact with salt water they are converted to chlorargyrite (including horn silver), AgCl, which is prevalent in Chile and New South Wales. Most other this minerals are pnictides or chalcogenides; they are generally lustrous semiconductors. Most true silver deposits, as opposed to argentiferous deposits of other metals, came from Tertiary period vulcanism.

It is usually found in nature combined with other metals, or in minerals that contain silver compounds, generally in the form of sulfides such as galena (lead sulfide) or cerussite (lead carbonate). So the primary production of requires the smelting and then cupellation of argentiferous lead ores, a historically important process. Lead melts at 327 °C, lead oxide at 888 °C and silver melts at 960 °C. To separate the silver, the alloy is melted again at the high temperature of 960 °C to 1000 °C in an oxidizing environment. The lead oxidises to lead monoxide, then known as litharge, which captures the oxygen from the other metals present. The liquid lead oxide is removed or absorbed by capillary action into the hearth linings.

Silver Uses Area

The earliest known coins were minted in the kingdom of Lydia in Asia Minor around 600 BC. The coins of Lydia were made of electrum, which is a naturally occurring alloy of gold and silver, which available within the territory of Lydia. Since that time, standards, in which the standard economic unit of account is a fixed weight of silver, have been widespread throughout the world until the 20th century.

Today, silver bullion has the ISO 4217 currency code XAG, one of only four precious metals to have one (the others being palladium, platinum, and gold).

Applications

The major use of silver besides coinage throughout most of history was in the manufacture of jewellery and other general-use items, and this continues to be a major use today.

Electrolytically refined pure silver plating is effective at increasing resistance to tarnishing.

Wound dressings containing silver sulfadiazine or silver nanomaterials are used to treat external infections. It is also used in some medical applications, such as urinary catheters (where tentative evidence indicates it reduces catheter-related urinary tract infections) and in endotracheal breathing tubes (where evidence suggests it reduces ventilator-associated pneumonia).

It and its nanoparticles are used as an antimicrobial in a variety of industrial, healthcare, and domestic application: for example, infusing clothing with nanosilver particles thus allows them to stay odourless for longer

Silver and its alloys are used in cranial surgery to replace bone, and silver–tin–mercury amalgams are used in dentistry.

Silver diammine fluoride, the fluoride salt of a coordination complex with the formula [Ag(NH3)2]F, is a topical medicament (drug) used to treat and prevent dental caries (cavities) and relieve dentinal hypersensitivity.

It is very important in electronics for conductors and electrodes on account of its high electrical conductivity even when tarnished. Bulk silver and silver foils were used to make vacuum tubes, and continue to be used today in the manufacture of semiconductor devices, circuits, and their components.

Containing brazing alloys are used for brazing metallic materials, mostly cobalt, nickel, and copper-based alloys, tool steels, and precious metals.

Equipment made to work at high temperatures is often silver-plated. It and its alloys with gold are used as wire or ring seals for oxygen compressors and vacuum equipment.

The photosensitivity of the silver halides allowed for their use in traditional photography, although digital photography, which does not use silver, is now dominant.

Pure silver metal is used as a food colouring. It has the E174 designation and is approved in the European Union.

Distribution

Numerous localities even for fine specimens. Well-crystallized examples from:

  • in Germany, near Freiberg and Marienberg, Saxony, and at St. Andreasberg, Harz Mountains.
  • Exceptionally developed at Kongsberg, Norway.
  • From Prıbram and Jachymov (Joachimsthal), Czech Republic.
  • In Italy, from Monte Narba, Sarrabus, Sardinia.
  • In the USA, on the Keweenaw Peninsula, Houghton and Keweenaw Cos., Michigan; at Aspen, Pitkin Co., and from Creede, Mineral Co., Colorado; and in Arizona, in the Silver King mine, Pinal Co. In Canada, in large amounts from Cobalt; and in the Thunder Bay district, at Silver Islet, on the north shore of Lake Superior, Ontario. Important production from Mexico, in many states; finely crystallized from Batopilas, Chihuahua; masses over 1500 kg from Arizonac, Sonora.
  • At Chanarcillo, south of Copiapo, Atacama, Chile.
  • In Australia, at Broken Hill, New South Wales.

References

  • Bonewitz, R. (2012). Rocks and minerals. 2nd ed. London: DK Publishing.
  • Handbookofmineralogy.org. (2019). Handbook of Mineralogy. [online] Available at: http://www.handbookofmineralogy.org [Accessed 4 Mar. 2019].
  • Mindat.org. (2019). Orpiment: Mineral information, data and localities.. [online] Available at: https://www.mindat.org/ [Accessed. 2019].
  • Smith.edu. (2019). Geosciences | Smith College. [online] Available at: https://www.smith.edu/academics/geosciences [Accessed 15 Mar. 2019].
  • Wikipedia contributors. (2019, June 7). Silver. In Wikipedia, The Free Encyclopedia. Retrieved 14:35, June 10, 2019, from https://en.wikipedia.org/w/index.php?title=Silver&oldid=900845751
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